研究生: |
劉□睿 |
---|---|
論文名稱: |
利用磁控濺鍍法在鎳酸鑭底電極上沈積鋯鈦酸鋇薄膜作為微波變容器之研究 The Study of Ba(Zr,Ti)O3 Thin Films Deposited on LaNiO3 electrode by RF Magnetron Sputtering for microwave varactors |
指導教授: |
吳泰伯
|
口試委員: | |
學位類別: |
碩士 Master |
系所名稱: |
工學院 - 材料科學工程學系 Materials Science and Engineering |
論文出版年: | 2003 |
畢業學年度: | 91 |
語文別: | 中文 |
論文頁數: | 91 |
中文關鍵詞: | 鋯鈦酸鋇 、微波 、變容器 、調諧元件 |
外文關鍵詞: | BZT, microwave, varactor, tunable device |
相關次數: | 點閱:2 下載:0 |
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本實驗的目的乃是發展較為新型之鐵電材料,觀測其在鐵電微波調諧元件上的應用,其內容為微波元件中最基本的變容器。由於鐵電調諧元件首重電容隨電壓而變的調變力,以及高頻下的介電損失,所以在材料的選擇上,取用與現今被廣泛討論的鈦酸鍶鋇(BST)同系列之鋯鈦酸鋇(BZT)做為材料研發的重點,BZT材料的特性在於比起BST有較小的介電損失,以及不弱的調變力,並且藉由鋯含量的增加,使居里溫度可以降至室溫以下,得到完全之順電相。本實驗配製三種不同鋯含量之Ba-rich靶材,採用射頻磁控濺鍍法濺鍍所需之薄膜。
多篇論文曾提及,利用LNO底電極有助於使同樣為鈣鈦礦結構的鐵電材料在低溫結晶,且具有優選指向,本實驗係利用LNO底電極薄膜來幫助成長較好結晶品質之BZT薄膜。此外,影響調變力與介電損失的因素通常決定於薄膜的品質,其與製程參數的選擇有很大的關係,由實驗中發現,濺鍍功率、鍍膜溫度、以及鍍膜時的氣氛,皆會影響薄膜的物理以及電氣性質,太大或太小的濺鍍功率、太高或太低的鍍膜溫度,太多或太少的氧含量分壓,皆會造成薄膜性質的下降。本實驗最好的參數選擇為當濺鍍功率50W(2-inch靶材)、鍍膜溫度550℃、以及濺鍍氣氛為Ar/O2=75/25時會得到較好的薄膜品質。
不同鋯含量的薄膜,展現出來的性質也不一樣,本實驗亦發現,隨著鋯含量的增加,薄膜展現出之調變力雖有下降之趨勢,但介電損失亦會降低,而材料對於鐵電調諧元件的實用性可由一項優異值來決定,從實驗的結果中,以鋯含量最多者之薄膜得到的優異值最大。
此外,在高頻量測上,本實驗採用的量測模型乃選自Zhengxiang Ma、Andrew J.[40]等人所發展的一套模型,量測此材料在高頻上所展現出的電氣特性,從結果得知,此模型量測的量測的準確範圍約在1GHz以下。
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