Molecular Architecture Effect on the Self-Assembly of Comb-Coil Block Copolymers

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研究生：	蔣瑋珊 Wei-Shan Chiang
論文名稱：	Molecular Architecture Effect on the Self-Assembly of Comb-Coil Block Copolymers 分子架構效應於梳狀-柔軟團聯式共聚物自組裝之影響
指導教授：	陳信龍 Hsin-Lung Chen
口試委員:
學位類別：	碩士 Master
系所名稱：	工學院 - 化學工程學系 Department of Chemical Engineering
論文出版年：	2008
畢業學年度：	96
語文別：	英文
論文頁數：	94
中文關鍵詞：	梳狀雙團聯式共聚物
外文關鍵詞：	comb-coil
相關次數：	點閱：1 下載：0
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Self-assembly has drawn much attention of all fields because materials formed by self assembly can provide patterns with ordered array and identical size. The occurrence of self-assembly is usually the outcome of balance between enthalpy and entropy to some degree which causes molecules to self-organize and then induces plentiful phase behaviors and structures. Self-assembly is a spontaneous process, that is, the system can transfer from a disorder state to an order state without intervention of external force and also the system is thermal reversible.
The phenomenon of self-assembly often occurs in soft condense matters such as colloid, surfactant, lipid and block copolymer. Nowadays, utilizing these materials to make product with micrometer- or nanometer-scale ordered structure is a popular research field. In this study, we emphasize the self-assembly of star copolymers and then compare the result with their linear counterparts (diblock copolymers). According to the theories and experimental results from many researchers, we know that the common morphology formed through self-assemble of diblock copolymers are as follows: lamellae, hexagonally packed cylinder, gyroid, body-center-cubic packed sphere.
In our experiment, we use small angle X-ray scattering (SAXS) to investigate the morphology formed by comb-coil star copolymers from the viewpoint of reciprocal space. Then, we utilize transmission electron microscopy (TEM) to observe the real space morphology formed by the samples. In order to investigate the relative orientation of the structure-within-structure morphology, we also conduct large amplitude oscillatory shear (LAOS) experiment.

Index    1
Table Index    3
Figure Index    4
Chapter 1. Introduction    7
1-1 Preface    7
1-2 Self-Assembly    8
1-3 The development of supramolecular chemistry    11
1-4 Introduction to block copolymer    13
1-4-1 Amorphous-amorphous block copolymer    14
1-4-2 Star blocks and multiblocks    18
1-5 Introduction to supramolecular comb-shaped copolymer    26
1-6 Reference    36
Chapter 2. Molecular Architecture Effect on the Self-Assembly Behavior of Comb-Coil Block Copolymers Displaying Lamellae-within-Lamellae Morphology    42
2-1 Abstract    42
2-2 Introduction    43
2-3 Experimental Section    46
2-3-1 Synthesis of PS-P4VP Copolymers    46
2-3-2 Complex Preparation.    47
2-3-3 Small Angle X-Ray Scattering (SAXS) Measurements.    48
2-3-4 Transmission Electron Microscope (TEM) Observations.    48
2-3-5 Differential Scanning Calorimetry (DSC) Measurements.    49
2-4 Results    50
2-4-1 Comb-Coil Copolymers with Hydrogen-Bonding Complexation    50
2-4-2 Comb-Coil Copolymers with Ionic Complexation    53
2-5 Discussion    56
2-6 Conclusions    60
2-7 References    72
Chapter 3. Tetragonally Packed Cylinder Structure in Hetero-arm Star Comb-Coil Copolymer    75
3-1 Abstract    75
3-2 Introduction    76
3-3 Experiment Section    79
3-4 Result and Discussion    82
3-5 Conclusion    87
3-6 References    94

                                

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