二氧化鈦光電極結構對可撓式染料敏化太陽能電池元件效率之影響

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研究生：	楊斯閔 Yang, Sz-Min
論文名稱：	二氧化鈦光電極結構對可撓式染料敏化太陽能電池元件效率之影響 Effects of Microstructure of TiO2 Photoelectrodes on Efficiency of Flexible Dye-sensitized Solar Cells
指導教授：	開執中
口試委員:	李欣芳歐陽汎怡
學位類別：	碩士 Master
系所名稱：	原子科學院 - 工程與系統科學系 Department of Engineering and System Science
論文出版年：	2014
畢業學年度：	102
語文別：	中文
論文頁數：	106
中文關鍵詞：	染料敏化太陽能電池、可撓式基板、二氧化鈦
相關次數：	點閱：2 下載：0
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本研究以五種不同粒徑大小之二氧化鈦奈米顆粒(P25、A100、500 nm、800 nm與1000 nm)，製備低溫無黏著劑之二氧化鈦漿料，並以刮刀塗佈法與加壓製程，於ITO/PEN基板上製作出不同結構與組成之二氧化鈦光電極，應用於可撓式染料敏化太陽能電池，在單層結構中，100 nm顆粒的添加可以增加二氧化鈦光電極的入射光路徑，進而提升光捕獲率；在雙層結構中，使用粒徑800 nm的散射顆粒，配合P25的添加，可以形成同時具備染料吸附力與散射能力的散射層結構，提升元件整體的電子生成效率與光捕獲率；於三層結構之中，配合1000 nm二氧化鈦球的添加，可以進一步將穿透前兩層電極的穿透光反射回前兩層中，達到更佳的光捕獲率與利用效率。本研究並使用鈦金屬箔為對電極基板，以熱裂解法將鉑原子由氯鉑酸前驅物還原至鈦基板上，四氯化鈦之前處理影響亦在文中討論，最後加入化學還原法與電鍍法之低溫還原製程於鈦對電極作為比較。
二氧化鈦光電極之光學特性以紫外光-可見光光譜儀進行分析，元件之光電特性則由量子效率量測儀與太陽光模擬器進行量測，在經過混合不同比例之二氧化鈦顆粒的測試後，可以有效增加二氧化鈦光電極之光捕獲率，以優化過之ITO/PEN基板二氧化鈦光電極與熱裂解製程之鈦金屬對電極組成之可撓式染料敏化太陽能電池，可以在1 sun之光強度下達到7.56%之光電轉換效率，而優化過之二氧化鈦光電極與電鍍之鈦金屬對電極所組成之可撓式染料敏化太陽能電池，可以在1 sun之光強度下達到7.65%之光電轉換效率。

摘要    i
Abstract    ii
誌謝    iii
目錄    v
表目錄    vii
圖目錄    viii
第一章    緒論    1
1-1    染料敏化太陽能電池    1
1-2    研究動機    4
第二章    文獻回顧    9
2-1    染料敏化太陽能電池    9
2-1-1染料敏化太陽能電池之發展    9
2-1-2染料敏化太陽能電池之工作原理    9
2-2    染料敏化太陽能電池之組成    11
2-2-1染料    12
2-2-2工作電極    12
2-2-3電解液    14
2-2-4對電極    15
2-3    可撓式染料敏化太陽能電池    16
2-3-1導電塑膠基板    18
2-3-2可撓式金屬箔基板    18
2-4    影響染料敏化太陽能電池光電表現之因素    19
第三章    實驗流程與原理    29
3-1    實驗儀器與分析原理    29
3-1-1表面輪廓分析儀 (α-step)    29
3-1-2場發射掃描式電子顯微鏡 (Field Emission Scanning Electron Microscope)    29
3-1-3紫外光可見光光譜分析儀(UV-Vis. Spectrophotometer)    30
3-1-4入射光-電子轉換效率量測儀 (Incident Photon to electron Conversion Efficiency, IPCE)    31
3-1-5電化學交流阻抗分析儀 (Electrochemical Impedance Spectra, EIS)    32
3-1-6太陽光模擬器與光電轉換效率量測分析儀 (Solar Simulator)    33
3-2    實驗材料    34
3-3    實驗流程    34
3-3-1    二氧化鈦光電極之製備    34
3-3-2    膠態電解液之配製    36
3-3-3    光電極染料浸泡    36
3-3-4    可撓式對電極之製備    36
3-3-5    可撓式染料敏化太陽能電池之元件封裝    38
第四章    實驗結果與討論    52
4-1    單層二氧化鈦結構    53
4-1-1    二氧化鈦光電極厚度對光電效率之影響    53
4-1-2    摻雜不同粒徑之二氧化鈦光電極對光電轉換效率之影響    54
4-2    雙層二氧化鈦結構    56
4-2-1    二氧化鈦散射層粒徑對染料敏化太陽能電池效率之影響    57
4-2-2    散射層摻雜不同粒徑之二氧化鈦對電池效率產生之影響    58
4-3    三層二氧化鈦結構    60
4-4    可撓式染料敏化太陽能電池之對電極    62
4-4-1    前處理對高溫熱解鉑於鈦金屬箔之影響    63
4-4-2    低溫化學還原法應用於可撓式鈦金屬箔    64
4-4-3    電鍍法應用於可撓式鈦金屬箔    65
第五章    結論    95
第六章    未來展望    97
第七章    參考文獻    98

                                

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