鄰苯二甲酸酯類(Phthalate esters)在日常及工業上被廣泛使用，已發現存在於空氣、土壤和水中，可經由各種暴露或接觸途徑進入環境和人體中，其環境荷爾蒙性質對人體易造成危害。
揮發性有機化合物（Volatile Organic Compounds, VOCs）由於其高揮發性及在環境中有較長的半生期，故在環境中比其他類型污染物更易於流佈，短期暴露易造成呼吸系統受損、頭暈與神經系統失調，若長期暴露則會有致突變性與致癌性。
故本研究主要以固相微萃取法結合GC/FID分析飲用水中鄰苯二甲酸酯類及揮發性有機化合物濃度，並用固相微萃取法結合GC/ECD分析飲用水中鄰苯二甲酸酯類化合物以和GC/FID分析結果做確認比較，了解目前飲用水遭受的污染程度。最佳化分析條件下鄰苯二甲酸酯類及揮發性有機化合物檢量線之相關係數均在0.995以上。
飲用水樣品實測結果顯示，經淨水器與開飲機加熱過之水樣雖可去除自來水中揮發性有機物，但水中所含鄰苯二甲酸酯類濃度增加，以DBP為主要污染物。而八種市售包裝飲用水中均未測到13種目標揮發性有機化合物，鄰苯二甲酸酯分析方面以GC/FID測得 DEP濃度在n.d.~1.20μg/L、DBP濃度在0.45μg/L ~1.23μg/L、BBP濃度在n.d.~0.65μg/L、DEHP濃度在0.44μg/L ~2.31μg/L；以GC/ECD測得DEP濃度在n.d.~1.08μg/L、DBP濃度在0.54μg/L ~1.13μg/L、BBP濃度在n.d.~0.78μg/L、DEHP濃度在n.d.~2.11μg/L。由實驗結果可發現ECD偵檢器對DEHP靈敏度不如FID偵檢器。

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