本研究內容，主要探討中孔洞二氧化矽、金屬與高分子之共嵌入化學。中孔洞二氧化矽（SBA-15）為一具有高表面積以及規則孔洞排列之奈米結構，可應用於觸媒以及其他許多方面上。
　　在第一部分，研究利用SBA-15作為模板與鐵及聚吡咯的複合系統中，聚吡咯高溫裂解的過程中鐵之化學環境之變化。而在第二部分之中，則研究白金釕雙金屬與聚吡咯及SBA-15三者的複合系統。在直接甲醇燃料電池上，對於一氧化碳的毒化問題，白金釕雙金屬系統是很重要的陽極觸媒。聚吡咯則是一具有導電性質的導電高分子。利用SBA-15提供空間的侷限下，藉由控制實驗條件以期能得到不同奈米結構金屬粒子與聚吡咯之複合材料。
　　在Ｘ光吸收光譜的分析下，隨著各個處理過程，鐵的化學環境變化被細部地觀察與探討。白金釕雙金屬之奈米結構可藉由不同實驗條件控制為個別金屬粒子或核殼結構等。電化學活性與金屬結構之關係則待更進一步的實驗量測。

In this thesis, the co-incorporation of metal and polypyrrole into mesoporous silica was studied. Mesoporous silica possesses high surface area and ordered pore structure that enables the applications in catalysis, separation and so on. The employment of vapor-phase oxidative polymerization of PPY as carbon precursor possesses the stoichiometric relationship enables the rational control of carbon loading. In part I, the evolution of the chemical environment of iron during the pyrolysis process was investigated by X-ray absorption spectroscopy. In part II, extending the work of part I, the corporation of electrocatalyst, i.e. PtRu, and PPY is investigated. PtRu is considered the best anode catalyst toward the poison of CO. Several PPY/PtRu/SBA-15 composites are designed and performed for the anode materials of DMFC. The preliminary result from XAS suggests that the alloy structure of PtRu particles could be controlled as core-shell or separate particles by tuning the experimental parameters. The further electrochemical analysis is in progress.

1. Kresge, C.T.; Leonowicz, M.E.; Roth, W.J.; Vartuli,
J.C.; Beck, J.S. Nature 1992, 252, 710.
2. Beck, J. S.; Vartuli, J. C.; Roth, W. J.; Leonowicz, M.
E.; Kresge,C. T.; Schmitt, K. D.; Chu, C. T. W.; Olson,
D. H.; Sheppard, E.W.; McCullen, S. B.; Higgins, J. B.;
Schlenker, J. L. J. Am. Chem. Soc. 1992, 114, 10834.
3. Zhao, D; Huo, Q.; Feng. J.; Chmelka B. F.; Stucky G. D.
Science 1998, 279, 548.
4. Zhao, D; Huo, Q.; Feng. J.; Chmelka B. F.; Stucky G. D.
J. Am. Chem. Soc. 1998, 120, 6024.
5. Soler-Illia, Galo J. de A.A.; Crepaldi, Eduardo L.;
Grosso, David; Sanchez, Clément CURRENT OPINION IN
COLLOID & INTERFACE SCIENCE 2003, 8, 109.
6. (1) Moller, K.; Bein, T. Chem. Mater. 1998, 10, 2950.
(2) Ying, J. Y.; Mehnert, C. P.; Wong, M. S. Angew.
Chem. Int. Ed. 1999, 38, 56.
(3) Davis, M. E. Nature 2002, 147, 813.
7. Han, Y. J.; Kim, J. M.; Stucky, G. D. Chem. Mater. 2000,
12, 2068.
8. Luan, Z. H.; Maes, E. M.; van der Heide, P. A. W.; Zhao,
D. Y.; Czernuszewicz, R. S.; Kevan, L. Chem. Mater.
1999, 11, 3680.
9. Kang, H.; Jun, Y.; Park, J. I.; Lee, K. B.; Cheon, J.
Chem. Mater. 2000, 12, 3530.
10.Jiang, Y. J.; Gao, Q. M. J. Am. Chem. Soc. 2006, 128,
726.
11.Luan, Z. H.; Hartmann, M. ; Zhao, D.Y. Chem. Mater.
1999, 11, 1621.
12.Frisch, H. L.; Mark, J. E. Chem. Mater. 1996, 8, 1735.
13.Yang, C. M.; Weidenthaler, C.; Spliethoff, B.; Mayanna,
M.; Schuth, F. Chem. Mater. 2005, 17, 355.
14.Antonelli, D. M.; Ying, J. Y. Angew. Chem., Int. Ed.
Engl. 1996, 35, 426.
15.(1) Pei, Q.; Qian, R. Synthetic Metals 1991, 45, 35.
(2) Aeiyach, S.; Zaid, B.; Lacaze, P. C. Electrochimica
Acta 1999, 44, 2889.
16.(1) Matsumoto, A.; Kitajima, T.; Tsutsumi, K. Lagmuir
1999, 15, 7626.
(2) Ikegame, M.; Tajima, K.; Aida, T. Angew. Chem. Int.
Ed. 2003, 42, 2154.
(3) Choi, J. R.; Kim, Y.; Yoon, M. Bull. Korean Chem.
Soc 2001, 22, 1045.
(4) Xue, X. Appl. Surf. Sci. 2004, 221, 87.
(5) Chakarvati, S. K. Phys. Lett. A , 2004, 327, 198.
17.(1) Zhang, X; S. K. Manohar J. Am. Chem. Soc. 2004, 126,
12714.
(2) Zhang, X; S. K. Manohar J. Am. Chem. Soc. 2005, 127,
12456.
18.Brillas, E.; Alcaide, F.; Cabot, P.-L. Electrochim. Acta
2002, 48, 331.
19.Sammes, N.; Bove, R.; Stahl, K. Current Opinion in Solid
State and Materials Science 2004, 8, 372.
20.Minh, N. Q. J. Am. Ceram. Soc. 1993, 76, 563.
21.Dicks, A. L. Current Opinion in Solid State and
Materials Science 2004, 8, 379.
22.Zhou, W. J.; Zhou, Z. H.; Song, S. Q.; Li, W. Z.; Sun,
G. Q.; Tsiakaras, P.; Xin, Q. Applied Catalysis B:
Environmental 2003, 46, 273.
23.Troughton, G. L.; Hamnett, A. Bull. Electrochem. 1991,
7, 488.
24.Frelink, T.; Visscher, W.; van Veen, J. A. R. Surf. Sci.
1995, 335, 353.
25.Gotz, M.; Wendt, H. Electrochimica Acta. 1998, 43, 3637.
26.Moore, J. T.; Chu, D.; Jiang, R.; Deluga, G. A.;
Lukerhart, C. M. Chem. Mater. 2003, 15, 1119.
27.Gasteiger, H. A.; Markovic, N.; Ross, P. N.; Cairns, E.
J. J. Phys. Chem. 1994, 98, 617.
28.Watanabe, M.; Motoo, S. J. Electroanal. Chem. 1975, 60,
267.
29.Li, W. Z.; Liang, C. H.; Zhou; W. J.; Qiu, J. S.; Zhou,
Z. H.; Sun, G. Q.; Xin, Q. J. Phys. Chem. B 2003, 107,
6292.
30.Steigerwalt, E. S.; Deluga, G. A.; Cliffel, D. E.;
Lukehart, C. M. J. Phys. Chem. B 2001, 34, 8097.
31.Chai, G. S.; Yoon, S. B.; Yu, J. S.; Choi, J. H.; Sung,
Y. E. J. Phys. Chem. B 2004, 018, 7074.
32.Nam, J. H.; Jang, Y. Y.; Kwon, Y. U.; Nam, J. D.
Electrochemistry Communications 2004, 6, 737
33.Choi, Y. S.; Joo, S. H.; Lee, S. A.; You, D. J.; Kim,
H.; Pak, C.; Chang, H.; Seung, D. Macromolecules 2006,
39, 3275.
34.(1) Liu, H. S.; Song, C.J.; Zhang, L.; Zhang, J. J.;
Wang, H. J.; Wilkinson, D. P. Journal of Power Sources
2006, 155, 95.
(2) Wasmus, S.; Kuver, A. Journal of Electroanalytical
Chemistry 1999, 461, 14.
(3) Antolini, E Materials Chemistry and Physics 2003,
78, 563.
35.Choi, M.; Heo, W.; Kleitz, F.; Ryoo, R. Chem. Comm.
2003, 12, 1340.
36.(a) Yang, C. M.; Zibrowius, B.; Schmidt, W.; Schuth, F.
Chem. Mater. 2003, 15, 3739.
(b) Yang, C. M.; Zibrowius, B.; Schmidt, W.; Schuth, F.
Chem. Mater. 20034 16, 2918.
37.(1) Teo, B. K. (Ed.) EXAFS: Basic Principles and Data
analysis, Springer-Verlag, New York, 1986.
(2) Koningsberger D. C.; Prins, R. (Eds.) X-ray
Absorption, John Wiley & Sons, New York, 1988.
(3) Lee. P. A.; Pendry, J. B. Phys. Rev. B, 1975, 11,
2795.
(4) Guaman, S. J.; Pettifer, R. F. Phil. Mag. B, 1979,
40, 345.
(5) Sayers, D. A.; Stern, E. A.; Lytle, F. W. Phys. Rev.
B, 1971, 27, 1204.
(6) Sayers, D. A.; Stern, E. A.; Herriott, J. R. J.
Chem. Phys. 1976, 64, 427.
(7) Stern, E. A. Phys. Rev. B 1974, 10, 3027.
(8) Ashely, C. A.; Doniach, S. Phys. Rev. B 1975, 11,
1279.
(9) Lee, P. A.; Beni, G. Phys. Rev. B 1977, 15, 2862.
(10) Lee, P. A.; Pendry, J. B. Phys. Rev. B 1975, 11,
2795.
(11) Ankudinov, A. L.; Ravel, B.; Rehr, J. J.;
Conradson, S. D. Phys. Rev. B 1998, 7565.
(12) Ankudinov, A. L.; Rehr, J. J. Phys. Rev. B 1997,
R1712.
(13) Zabinsky, S. I.; Rehr, J. J.; Ankudinoe, A. L.;
Albers, R. C.; Eller, M. J. Phys. Rev. B, 1995, 52, 2995.
38.Porto, A.O.; Pernaut, J.M.; Daniel, H.; Schilling, P.J.;
Martins Alves, M.C Synthetic Metals 1999, 104, 89.
39.(1) Suri, K.; Annapoorni, S.; Tandon, R. P. Bull. Mater.
Sci. 2001, 24, 563.
(2) Suri, K.; Annapoorni, S.; Tandon, R. P. Mehra, N. C.
Synthetic Metals 2002, 126, 137.
40.(1)Roth,C.; Martz, N.; Morlang, A.; Theissmann, R.;
Fuess, H. Phys. Chem. Chem. Phys. 2004, 6, 3557.
(2) Liu, D. G.; Lee, J. F.; Tang, M. T. Journal of
Molecular Catalysis A: Chemical 2005, 240, 197.
(3) O'Grady W. E.; Hagans, P. L.; Pandya, K. I.;
Maricle, D. L. Langmuir 2001, 17, 3047.
(4) Roth, C.; Martz, N.; Morlang, A.; Theissmann, R.;
Fuess, H. Phys. Chem. Chem. Phys. 2004, 6, 3557.
(5) Viswanathan, R.; Hou, G. Y.; Liu, R. X.; Bare, S.
R.; Modica, F.; Mickelson, G.; Segre, C. U.; Leyarovska,
N.; Smotkin, E. S. J. Phys. Chem. B 2002, 106, 3458.
41.Jentys, A. Phys. Chem. Chem. Phys. 1999, 1, 4059.
42.McKeown, D.A.; Hagans, P. L.; Carette, L. P. L.;
Russell, A. E.; Swider, K.E.; Rolison, D. R. J. Phys.
Chem. B 1999, 103, 4825.
43.Hwang, B. J.; Sarma, L. S.; Chen, J. M.; Chen, C. H.;
Shih, S. C.;Wang, G. R.; Liu, D. G.; Lee, J. F.; Tang,
M. T. J. Am. Chem. Soc. 2005, 127, 11140.
44.Bock, C.; MacDougall, Y.; Lepege, Y. J. Electrochem.
Soc. 2004, 151, 1269.
45.Stein, A.; Melde, B. J.; Schroden. R. C. Adv. Mater.
2000, 12, 1403.
46.Dai, S.; Burleigh, M. C.; Shin, Y; Morrow, C. C.;
Barnes, C. E; Xue, Z Angew. Chem. Int. Ed. 1999, 38,
1235.
47.K. Manohar J. Am. Chem. Soc. 2004, 126, 12714.
48.Rodriguez, J. M. D.; Melian, J. A. H.; Pena, J. P.
Journal of Chemical Education 2000, 77, 1195.