研究生: |
王柏森 |
---|---|
論文名稱: |
二價銅、二價鎳巨環錯合物配位化學之研究與化學教育 Coordination Chemistry of Copper(II) and Nickel(II) Macorcyclic Compelexes and Chemical Education |
指導教授: | 鍾崇燊 |
口試委員: | |
學位類別: |
碩士 Master |
系所名稱: |
理學院 - 化學系 Department of Chemistry |
論文出版年: | 2004 |
畢業學年度: | 92 |
語文別: | 中文 |
論文頁數: | 140 |
中文關鍵詞: | 四胺基大環配位子 、x光晶體繞射 、金屬錯合物 、晶體結構 、著作 、化學 |
外文關鍵詞: | macrocyclic ligand, X-ray diffraction, metal complexes, crystal structure, article, Chemistry |
相關次數: | 點閱:1 下載:0 |
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兩個四胺基大環配位子,1,4,7,11-Tetraazacyclotetradecane和3-[8-(2-Cyano-ethyl)-3,5,7,7,10,12,14,14-octamethyl-
1,4,8,11tetraaza-cyclotetradec-1-yl]-propionitrile與兩個金屬錯合物cis-Diaqua(1,4,7,11-Tetraazacyclotetradecane)
nickel(II) Choride和{3-[8-(2-Cyano-ethyl)-3,5,7,7,10,12,14
,14-octamethyl-1,4,8,11tetraaza-cyclotetradec-1-yl] -propi
onitrile-N,N,N,N,}corpper(II) Choride被合成出來,並且用x光晶體繞射,測定這兩個金屬錯合物之晶體結構。
在這兩年中,完成下列三篇著作:
1. 陳震豪 鄭美玲 王柏森 呂卓穎 李伊璿 蔣得明 鄭丞劭 陳孟筠 彭馨瑩 黃品倩 鍾崇燊 “以實驗教學法提昇高中生的化學創造力
。” 化學, 2003, 61, pp.551-560
2.張盛綱 王柏森 呂卓穎 李伊璿 蔣德明 陳孟筠 彭馨瑩 黃品蒨 鍾崇燊 “以岑賓與本斯的學習理論為基礎的科學教學法提昇高中生的化學創造力:米立肯油滴實驗。”
3. Yung-Jan Lin, Po-Son Wang, Tarun Kumar Misra, Chung-Sun Chung “Kinetic studies of the conversion of to the square planar complex。”
Abstract
Two macrocyclic ligands , 1,4,7,11-Tetraazacyclotetra
decane and 3-[8-(2-Cyano-ethyl)-3,5,7,7,10,12,14,14
-octamethyl-1,4,8,11tetraaza-cyclotetradec-1-yl]-propionitrile,two macrocyclic transition metal complexes , cis-Diaqua(1,4,7,11-Tetraazacyclotetradecane) nickel(II) Chorideand {3-[8-(2-Cyano-ethyl)-3,5,7,7,10,12,14,14-octamethyl-1,4,8,11tetraaza-cyclotetradec-1-yl] -propionitrile-N,N,N,N,}corpper(II) Choride , have been prepared. The crystal structures of these two complexes have been determined by X-ray diffraction.
Three articles were finished in these two years:
1. Chen Hao Chen Mei Ling Cheng Po Sen Wang Cho Ying Lu Yi Hsuan Li Cheng Shao Cheng Te Ming Chiang Meng Yun Chen Hsin Ying Peng Pin Chien Huang Chung-Sun Chung”Applying an Experimental Method of Instruction to Enhance Senior High School Student,Creativites in Chemistry.” Chemistry, 2003, 61, pp.551-560.
2. Sheng Kang Chang Po Sen Wang Cho Ying Lu Yi Hsuan Li
Te Ming Chiang Meng Yun Chen Hsin Ying Peng Pin Chien Huang
Chung-Sun Chung “Applying Champagne and Bunce,s Learning-theory Based Science Teaching Method To Enhance Senior High School Students, Creativities in Chemistry :Millikan oil-drop experiment.”
3. Yung-Jan Lin, Po-Son Wang, Tarun Kumar Misra, Chung-Sun Chung “Kinetic studies of the conversion of to the square planar complex。”
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