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研究生: 吳旻駿
Wu, Min-Chun
論文名稱: 以碳纖維布捕獲二氧化碳
Capture CO2 by Carbon Fiber Cloth
指導教授: 談駿嵩
Tan, Chung-Sung
口試委員: 蔣孝澈
賴慶智
學位類別: 碩士
Master
系所名稱: 工學院 - 化學工程學系
Department of Chemical Engineering
論文出版年: 2011
畢業學年度: 99
語文別: 中文
論文頁數: 68
中文關鍵詞: CO2捕獲活性碳纖維布電力擺盪吸附法胺類嫁接CO2吸附能力再生
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  • 本研究以活性碳纖維布 (Activated Carbon Fiber Cloth, ACFC)為吸附材,電力擺盪吸附法 (Electric Swing Adsorption, ESA)為再生技術,探討不同操作變數,如吸附溫度、再生電流 (電壓)、再生溫度及再生時間,對CO2吸附能力之影響;此外亦藉由 (1) 3-Aminopropyltriethoxysilane (APTS)密閉迴流加熱法、 (2)高溫氨氣煅燒、(3) 胺類含浸改質及 (4)胺類嫁接改質等方法,將胺類官能基嫁接於ACFC上,期藉以提升ACFC對CO2之吸附量。
    實驗結果顯示,在吸附溫度35 oC以及再生溫度120 oC下,ACFC有較佳之CO2吸附能力,吸附量為13.8 mg/g;當再生溫度為120 oC時,以電流為1.53 A、電壓為5 V之條件下,再生所需能量為最低;當再生時間超過30 min以上,ACFC之吸附能力並無明顯提升,代表30 min之再生時間可將ACFC上之CO2幾乎完全脫附。
    將胺類官能基嫁接於ACFC之研究結果顯示:經APTS迴流嫁接改質後的ACFC,其對CO2之吸附量減少98%,可能改質後ACFC之孔洞會被阻塞導致CO2分子無法有效進入ACFC孔洞中,造成吸附量比未改質之ACFC還要低。
    ACFC經過400 oC氨氣煅燒後,在吸附溫度為35 oC下,對CO2之吸附能力相較於未改質之ACFC增加19%的吸附量;ACFC經過20 wt% MEA含浸後,在吸附溫度為45 oC下,有最大之吸附量,相較於未改質之ACFC增加28%的吸附量;再者,將MEA濃度提高,ACFC經過100 wt% MEA含浸後,在吸附溫度為45 oC下,對CO2之吸附能力相較於未改質之ACFC增加70%的吸附量。


    目錄 謝誌 I 摘要 II 目錄 III 表目錄 VI 圖目錄 VIII 壹、緒論 1 2-1吸附CO2之研究文獻 8 2-2 活性碳之吸附 12 2-3 各種碳材改質方法 13 2-3-1 碳材親水性改質 13 2-3-2 濕式胺前驅物嫁接 13 2-3-3 乾式嫁接方法-高溫氨氣煅燒 14 2-3-4 胺類含浸改質活性碳 15 2-3-5 微波 (Microwave Irradiation)改質活性碳 16 2-3-6 臭氧 (Ozone)改質活性碳 17 2-4 再生技術 17 2-5 利用活性碳纖維材料經電力擺盪吸附法捕獲CO2 18 參、實驗方法 31 3-1 實驗設備與藥品 31 3-1-1 實驗設備 31 3-1-2 實驗藥品 31 3-2 碳材改質之方法 32 3-2-1 碳纖維布表面改質呈親水性-利用H2SO4/HNO3作為氧化劑 32 3-2-2 利用密封迴流加熱法將胺類物質嫁接於碳纖維布上 32 3-2-3 高溫氨氣煅燒改質碳纖維布 33 3-2-4胺類含浸改質碳纖維布 33 3-2-5 胺類嫁接改質碳纖維布 33 3-3 CO2吸附實驗 34 3-3-1 碳纖維布之前處理 34 3-3-2 CO2分析儀校正步驟 34 3-3-3 脫附操作 35 3-3-4 吸附操作 35 3-3-5吸附量計算 36 3-4 碳材改質之鑑定分析 37 3-4-1氮氣等溫物理吸附 37 3-4-2 傅立葉轉換紅外線光譜儀 (FTIR) 37 3-4-3 元素分析 (Elemental Analysis) 37 肆、實驗結果與討論 39 4-1 不同操作變數對吸附量的影響 39 4-1-1 吸附系統再現性測試 39 4-1-2 電流 (電壓)與升溫速率之效應 39 4-1-3 不同再生時間之效應 40 4-1-4 不同再生溫度之效應 40 4-1-5 不同吸附溫度之效應 (等溫吸附曲線) 41 4-1-6 不同吸附時間之效應 41 4-2 碳纖維布的改質 41 4-2-1 碳纖維布表面改質呈親水性-利用H2SO4/HNO3作為氧化劑 42 4-2-2 利用密封迴流加熱法將胺類物質嫁接於碳纖維布上 42 4-2-3 高溫氨氣煅燒改質碳纖維布 43 4-2-4 胺類含浸改質碳纖維布 44 4-2-5 胺類嫁接改質碳纖維布 46 4-2-6 碳纖維布表面改質呈親水性 + 胺類含浸改質碳纖維布 47 4-2-7 利用電漿來改質ACFC表面性質 48 4-3 利用導電高分子PANi吸附CO2 48 伍、結論 61 陸、參考文獻 64

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