研究生: |
林勝賢 Lin, Sheng-Hsien |
---|---|
論文名稱: |
酵素型生物燃料電池奈米質傳模擬與實作實驗量測 Nanoscale Mass Transfer Simulation and Fabrication Experiment of an Enzymatic Biofuel Cell |
指導教授: |
洪哲文
Hong, Che-Wun |
口試委員: | |
學位類別: |
碩士 Master |
系所名稱: |
工學院 - 動力機械工程學系 Department of Power Mechanical Engineering |
論文出版年: | 2009 |
畢業學年度: | 97 |
語文別: | 中文 |
論文頁數: | 73 |
中文關鍵詞: | 酵素型生物燃料電池 、分子動力模擬 、羥離子 |
外文關鍵詞: | Enzymatic Biofuel Cell, Molecular Dynamics Simulation, Hydronium Ion |
相關次數: | 點閱:2 下載:0 |
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本論文針對酵素型生物燃料電池(Enzymatic Biofuel Cell)在微觀尺度下進行奈米流力質傳分析,藉由葡萄糖溶液與羥離子(H3O+)的幾何結構建立,並配合分子動力模擬軟體、巨觀質傳模擬分析與實作手段,實際製作一酵素型生物燃料電池,以實驗驗證相關理論分析模擬,進而探討酵素型生物燃料電池的性能特性。
生物燃料電池通常指的是將生質燃料像是酒精、醣類或是有機化合物轉化成電能的電化學裝置。其中酵素型生物燃料電池主要使用是酵素當作觸媒而非白金之類的貴重金屬,例如本論文中電池實驗使用的葡萄糖氧化酵素(Glucose Oxidase)和漆酵素(Laccase),其利用酵素的催化特性與專一性將葡萄糖和氧氣作氧化還原的電化學反應以產生電能。其中陽極在氧化還原反應過程中產生質子並藉由擴散原理傳遞至陰極,所以我們知道酵素型生物燃料電池藉由電化學反應所產生之功率乃與質子於電解質內的移動性能有著密不可分的關係,因此本論文藉由相關模擬分析與電池實作實驗來研究相關物理性質所造成的影響及趨勢,以瞭解酵素燃料電池的性質與反應特性。
生物燃料電池的應用範圍相當廣泛,像是生物產氫、鹽沼沉積物發電和生物感測器…等領域皆有應用,而酵素型生物燃料電池因為其組成之元件主要是生物元件而且所輸出之功率較低,所以其適用於植入人體(或動物體)內作為人體醫療儀器以及生物感測的電源供應來源,像是生醫發電機、血糖發電與生物感測器等應用。
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