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| 研究生： |
張彥博 Yen-Po Chang |
|---|---|
| 論文名稱： |
嵌入中孔洞氧化矽之金屬奈米結構:合成與鑑定 |
| 指導教授： |
趙桂蓉
Kuei-Jung Chao |
| 口試委員: | |
| 學位類別： |
碩士 Master |
| 系所名稱： |
理學院 - 化學系 Department of Chemistry |
| 論文出版年： | 2005 |
| 畢業學年度： | 93 |
| 語文別： | 中文 |
| 論文頁數： | 174 |
| 中文關鍵詞： | 中孔洞二氧化矽 、奈米結構 、奈米鉑 、奈米鈀 、奈米金 、超臨界二氧化碳 |
| 外文關鍵詞： | mesoporous silica, nanostructure, Pt, Pd, Au, supercritical carbon dioixde |
| 相關次數： | 點閱：3 下載：0 |
| 分享至: |
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利用不同的溶劑 (水，酒精，超臨界流體二氧化碳) 溶解金屬前驅物，含浸Pt、Pd 及 Au 金屬前驅物溶液於中孔洞氧化矽 (MCM-48，SBA-15，MCM-41) 上，製備出不同形態的金屬 (鉑，鈀，金) 奈米線、奈米網子、奈米棒、奈米球及奈米顆粒。
首先，第一章簡介中孔洞材料的演進與發展、超臨界流體的特性與本實驗的分析技術。第二章藉由矽烷改質劑 (TPTAC) 修飾中孔洞的表面使其帶正電荷，改變金屬前驅物之溶劑 (水或酒精)，將帶負電荷的金屬前驅物吸附於孔洞中，用室溫 NaBH4 溶液或高溫氫氣加熱使其還原，製備出不同顆粒大小與形貌的奈米金屬於中孔洞物質上 ( Pt/MCM-48，Pd/MCM-48，Pd/MCM-41，Pd/SBA-15，Au/SBA-15 等樣品)。第三章使用超臨界二氧化碳 (ScCO2) 作為金屬前驅物之溶劑，將鉑含浸到中孔洞物質上。改變反應條件如壓力、溫度、金屬前驅物的物種、升溫條件等等，製備出鉑金屬奈米結構於 MCM-48 上 (Pt/MCM-48 樣品)。金屬的奈米結構、化學性質與含量，使用粉末 X 光繞射 (PXRD)、X 光吸收光譜 (XAS)、穿透式電子顯微鏡 (TEM) 及感應耦合電漿-原子放射光譜 (ICP-AES) 來鑑定分析。
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