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研究生: 蔡雅丞
Tsai, Ya-Cheng
論文名稱: 發展簡易型檢測裝置進行家庭常見之傳統及新興汙染物檢測
Development of Simple Analytical Devices for Quantification of Household Traditional and Emerging Contaminants
指導教授: 孫毓璋
Sun, Yuh-Chang
口試委員: 楊末雄
Yang, Mo-Hsiung
施宗廷
Shih, Tsung-Ting
徐繹翔
Hsu, I-Hsiang
學位類別: 碩士
Master
系所名稱: 原子科學院 - 生醫工程與環境科學系
Department of Biomedical Engineering and Environmental Sciences
論文出版年: 2020
畢業學年度: 108
語文別: 中文
論文頁數: 77
中文關鍵詞: 家庭汙染物新興汙染物自組裝分析裝置自由有效餘氯氨氮開源電路元件塑膠微粒螢光標定螢光分析系統
外文關鍵詞: Household Contaminants, Emerging Contaminants, Free Available Residual Chlorine, Ammonium Nitrogen, Open-source Electronic Components, Integrated Analytical Devices, Microplastics, Fluorescent Labelling, Fluorescence Photography System
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  •   家庭是現今社會中屬於每個人的共同歸屬,能夠提供身心靈上最溫暖的慰藉。然而近年來家庭汙染物的安全問題在報章雜誌的報導中層出不窮,這些家庭汙染物不僅會對家庭成員造成健康危害,也曾多次引起社會大眾的恐慌。除了早已為人所知的幾種傳統家庭汙染物外,近年更有所謂的新興汙染物興起並頻繁攻佔媒體版面,其造成的影響更可由近期持續增加的家庭毒害新聞一窺端倪。然而面對上述傳統或新興家庭汙染物的危害,現行的標準檢測程序卻顯得左支右絀。對於傳統家庭污染物目前多以第三方檢測實驗室進行檢測,但其耗時且昂貴的程序無疑是一般民眾進行檢測的一大障礙,而在新興汙染物方面甚至沒有標準檢測方法供民眾參考,最終只能看著家庭汙染相關報導而一籌莫展。
    因此,本研究將以提供一般民眾在家庭自行檢測汙染物的可能為目標,開發具備快速、經濟且簡易特色的家庭汙染物分析方法。研究最初,係選擇已完整建立相關法規規範的水質傳統汙染物,分別為自由有效餘氯以及氨氮,並參考其標準檢測方法之程序,搭配市售軟硬體開源之電路元件,自行組裝出低成本且可攜式之分析裝置,提升家庭汙染物檢測方法的彈性並降低分析門檻。其次,因應新興汙染物的崛起,本研究進一步選取家庭環境中的聚氯乙烯塑膠微粒新興汙染物,參考簡易分析方法開發的流程,以自行建立的螢光攝影分析系統搭配簡易螢光標定方法,來進行家庭聚氯乙烯塑膠微粒新興汙染物的檢測。縮小新興汙染物在分析技術上家庭與自行檢測間的鴻溝,並嘗試跳脫新興汙染物檢測方法,冀望將分析化學技術應用於現場即時檢測,以突破現今新興汙染物檢測技術的瓶頸。


      Household is the warmest belonging to everyone mentally and physically in modern society. However, the issues of household contaminants has been constantly reported in the media in recent years, and they not only hazard family members but also cause panic among the society. Besides the well-known household traditional contaminants, so-called emerging contaminants have risen gradually. However, facing the threat of both traditional and emerging household contaminants, the current standard analysis methods seem to be insufficient. At present, traditional household contaminants are mostly analyzed by analytical chemistry lab. But the time-consuming and expensive procedures are undoubtedly a critical obstacle for the ordinary people. And there are even no standard analytical methods for the emerging contaminants. In the end, people could do nothing but left helpless.
      The purpose of this study is to provide the probability of determining surrounding household contaminants to public on their own. Therefore, development of a rapid, low cost and simple integrated analytical devices is necessary. At the beginning of the study, we select traditional household contaminants with established regulations (Free Available Residual Chlorine and Ammonium Nitrogen). Then, we combine open-source electronic components and standard analytical methods to build up a low-cost and portable analytical device. Facing the rise of household emerging contaminants, we choose one of contaminants and develop a fluorescent labelling method with self-construction fluorescence photography system and image analysis software to finish the determining of that household emerging contaminants (Polyvinyl Chloride Microplastics). Eventually, this study could help ordinary people overcome the critical obstacle of ensuring their household safety on their own.

    摘要         I Abstract Ⅱ 謝誌 IⅤ 目錄 V 圖目錄 IⅩ 表目錄 ⅩI 第一章 緒論 1 1.1家庭環境汙染物的危害 1 1.2家庭傳統及新興汙染物的演變 2 1.3目前家庭汙染物檢測面臨之困難 3 1.4研究目的與因應策略 5 1.5參考文獻 6 第二章 開發低成本可攜式分析裝置用於家庭傳統水質雙指標之檢測 8 2.1前言 8 2.1.1水資源於人類文明發展之意義 8 2.1.2水質監測及規範指標 9 2.1.3研究目的與因應策略 12 2.2實驗部分 14 2.2.1試劑與材料 14 2.2.2儀器設備 15 2.2.3整合型分析裝置組裝介紹 16 2.2.3.1 Arduino電路微控制器之原理 16 2.2.3.2 TCS3200光感測元件之原理 16 2.2.3.3整合裝置載台製作 17 2.2.3.4色彩分析程式指令編寫 18 2.2.3.5自組裝分析裝置 19 2.2.4色卡顏色定位能力之辨識 20 2.2.5彩色水溶液顯色可行性測試 21 2.2.6傳統水質指標顯色反應 22 2.2.6.1自由有效餘氯顯色反應 22 2.2.6.2氨氮顯色反應 23 2.2.7真實樣品製備 24 2.3結果與討論 25 2.3.1整合型分析裝置之組裝與設計理念 25 2.3.1.1 Arduino電路微控制器選擇理念 25 2.3.1.2 TCS3200光感測元件選擇理念 26 2.3.1.3 整合型裝置組裝 26 2.3.2色卡顏色座標定位能力辨識結果探討 27 2.3.3彩色水溶液顯色可行性測試探討 28 2.3.4傳統水質雙指標顯色反應效能測試 31 2.3.4.1自由有效餘氯顯色反應 31 2.3.4.2氨氮顯色反應 32 2.3.5真實樣品分析結果與方法確效 33 2.4小結 38 2.5參考文獻 39 第三章 開發以螢光標定法搭配影像分析系統用於家庭新興汙染物聚氯乙烯塑膠微粒之檢測方法 40 3.1前言 40 3.1.1塑膠製品在人類生活中的應用 40 3.1.2家庭新興汙染物聚氯乙烯塑膠微粒的產生及影響 41 3.1.3研究目的與因應策略 43 3.2實驗部分 45 3.2.1試劑與材料 45 3.2.2儀器設備 45 3.2.3螢光法標定聚氯乙烯塑膠微粒之程序 46 3.2.3.1螢光標定聚氯乙烯塑膠微粒之操作程序 46 3.2.3.2螢光標定聚氯乙烯塑膠微粒XPS樣品定性鑑定 46 3.2.4螢光定量分析系統之建置 47 3.2.5聚氯乙烯塑膠微粒真實樣品分析 50 3.3結果與討論 51 3.3.1螢光錯合物的選擇與標定機制 51 3.3.2螢光定量分析系統之調整 56 3.3.2.1激發光源之選擇 56 3.3.2.2數位相機參數比較及螢光標定閾值計算確認 58 3.3.3螢光標定聚氯乙烯塑膠微粒參數最適化 63 3.3.3.1酒精比例 63 3.3.3.2螢光標定反應濃度之影響 65 3.3.3.3螢光標定反應pH值之最適化 66 3.3.4真實樣品分析 67 3.4小結 71 3.5參考文獻 72 第四章 結語 74 附錄、論文口試審查委員意見修正情形一覽……………………………………...76

    第一章
    (1) 巧克力、麵包恐藏致癌物「縮水甘油」 牢記3招不傷身 ,ETtoday新聞雲. ,https://health.ettoday.net/news/1608920.
    (2) 鋁箔紙不可滴檸檬汁!中秋烤肉...林杰樑團隊提「12點建議」 ,ETtoday健康雲. ,https://health.ettoday.net/news/1534296.
    (3) 隔夜菜含「硝酸鹽」恐致癌?譚敦慈教你1招解毒 ,健康20. ,https://health.tvbs.com.tw/review/321585.
    (4) IKEA塑膠杯再次踩雷!連兩週塑化劑超標被退貨 ,HINET生活誌. ,https://times.hinet.net/news/22689809.
    (5) 影印機運作飄刺鼻味 原來是這種氣體 ,yahoo新聞中心. ,https://tw.news.yahoo.com/%E5%BD%B1%E5%8D%B0%E6%A9%9F%E9%81%8B%E4%BD%9C%E9%A3%84%E5%88%BA%E9%BC%BB%E5%91%B3-%E5%8E%9F%E4%BE%86%E6%98%AF%E9%80%99%E7%A8%AE%E6%B0%A3%E9%AB%94-031550602.html.
    (6) 5款台灣代工化妝品驗出石綿 長期暴露恐致癌 ,聯合新聞網. ,https://udn.com/news/story/7266/3919410.
    (7) 打造無毒廚房!使用不沾鍋切記5重點 清潔劑也要留心 ,ETtoday新聞雲. ,https://www.ettoday.net/news/20191111/1573404.htm.
    (8) 土地遭傾到焚化爐渣,毒物恐有致癌風險…房產專家:被汙染過的房子,你敢住嗎? ,風傳媒. ,https://www.storm.mg/lifestyle/1712998.
    (9) 煎台材質揭秘!劣質鐵板用久恐釋毒物 ,yahoo新聞中心. ,https://tw.news.yahoo.com/%E7%85%8E%E5%8F%B0%E6%9D%90%E8%B3%AA%E6%8F%AD%E7%A7%98-%E5%8A%A3%E8%B3%AA%E9%90%B5%E6%9D%BF%E7%94%A8%E4%B9%85%E6%81%90%E9%87%8B%E6%AF%92%E7%89%A9-143026981.html.
    (10) Web of Science ,Clarivate Analytics. ,http://apps.webofknowledge.com/WOS_GeneralSearch_input.do?product=WOS&search_mode=GeneralSearch&SID=E2tUlQoukEfUEl2CyYB&preferencesSaved=.
    (11) Sébastien Sauvé; Desrosiers, M. Chemistry Central Journal, 2014, 8, 15.
    (12) Environmental protection expenditure ,European Environment Agency. ,https://www.eea.europa.eu/airs/2018/resource-efficiency-and-low-carbon-economy/environmental-protection-expenditure.
    (13) Emerging Contaminants and Federal Facility Contaminants of Concern ,Environmental Protection Agency. ,https://www.epa.gov/fedfac/emerging-contaminants-and-federal-facility-contaminants-concern.
    (14) Johnny Gasperi; C.Sebastian; V.Ruban; M.Delamain; S.Percot; Laure Wiest; C.Mirande; E.Caupos; D.Demare; MDialloKessooKessoo. EnvironmentalScienceandPollutionResearch, 2014, 21, 5267-5281.
    (15) Noguera-Oviedo, K.; Aga, D. S. J Hazard Mater, 2016, 316, 242-51.
    第二章
    (1) United Nations Conference on Sustainable Development ,Department of Economic and Social Affairs. ,https://sustainabledevelopment.un.org/rio20nationalreports.html.
    (2) 飲用水供應和環境衛生聯合監測規劃 ,World Health Organization. ,https://www.who.int/water_sanitation_health/monitoring/coverage/zh/.
    (3) 河川汙染指數 ,行政院環境保護署. ,https://wq.epa.gov.tw/Code/Business/Standard.aspx.
    (4) Saltali, K.; Sari, A.; Aydin, M. J Hazard Mater, 2007, 141, 258-63.
    (5) Schindler, D. W.; Carpenter, S. R.; Chapra, S. C.; Hecky, R. E.; Orihel, D. M. Environ Sci Techno,l 2016, 50, 8923-9.
    (6) 水質標準與各國水質標準比較表 ,台北自來水事業處. ,https://www.water.gov.taipei/cp.aspx?n=B96B3009F7951CD4.
    (7) 淨水場淨水處理 ,臺北自來水事業處. ,https://www.water.gov.taipei/cp.aspx?n=360E42FDB19DF7E2.
    (8) 水中餘氯檢測方法-分光光度計法 (NIEA W408.51A) ,行政院保護署. ,https://www.epa.gov.tw/niea/4625E0243CEC29C1.
    (9) 水中氨氮檢測方法-靛酚比色法 (NIEA W448.51B) ,行政院保護署. ,https://www.epa.gov.tw/niea/4034F5B8E3A33B00.
    (10) TCS3200 PROGRAMMABLE COLOR LIGHT-TO-FREQUENCY CONVERTER ,Texas Advanced Optoelectronic Solutions. ,https://www.mouser.com/catalog/specsheets/TCS3200-E11.pdf.
    (11) IDE of ARDUINO ,ARDUINO Co. Ltd. ,https://www.arduino.cc/en/Main/Software.
    (12) DPD Free Chlorine Reagent ,HACH Co. Ltd. ,https://www.hach.com/dpd-free-chlorine-reagent-powder-pillows-5-ml-pk-100/product?id=7640189156.
    (13) ARDUINO Co. Ltd. ,ARDUINO. ,https://www.arduino.cc/.
    (14) Anzalone, G. C.; Glover, A. G.; Pearce, J. M. Sensors, (Basel) 2013, 13, 5338-46.
    (15) de L. M. de Morais, C.; Carvalho, J. C.; Sant'Anna, C.; Eugênio, M.; Gasparotto, L. H. S.; Lima, K. M. G. Analytical Methods, 2015, 7, 7917-7922.
    第三章
    (1) Roland Geyer, J. R. J., Kara Lavender Law. Science. Advanges. 2017, 3, e1700782.
    (2) Carsten Lassen, S. F. H., Kerstin Magnusson,; Fredrik Norén, N. I. B. H., Pernille Rehne Jensen, Torkel Gissel Nielsen, Anna Brinch.The Danish Environmental Protection Agency, 2015
    (3) 毒性化學物質資料 ,行政院環境保護署. ,https://toxicdms.epa.gov.tw/Chm_/Chm_index.aspx?vp=SDS.
    (4) Joung, H. T.; Seo, Y. C.; Kim, K. H.; Seo, Y. C. Chemosphere, 2006, 65, 1481-9.
    (5) IARC MONOGRAPHS ON THE IDENTIFICATION OF CARCINOGENIC HAZARDS TO HUMANS ,International Agency for Research on Cancer. ,https://monographs.iarc.fr/list-of-classifications/.
    (6) Castagnoli, E.; Backlund, P.; Talvitie, O.; Tuomi, T.; Valtanen, A.; Mikkola, R.; Hovi, H.; Leino, K.; Kurnitski, J.; Salonen, H. Indoor Air, 2019, 29, 903-912.
    (7) Jens Hùjslev Petersen, E. T. N. Z Lebensm Unters Forsch A, 1998, 206, 156-160.
    (8) Njati, S. Y.; Maguta, M. M. Environ. Pollut., 2019, 249, 1091-1105.
    (9) Alimi, O. S.; Farner Budarz, J.; Hernandez, L. M.; Tufenkji, N. Environ Sci Technol, 2018, 52, 1704-1724.
    (10) Coffin, S.; Lee, I.; Gan, J.; Schlenk, D. Environ Pollut, 2019, 246, 452-462.
    (11) Vianello, A.; Jensen, R. L.; Liu, L.; Vollertsen, J. Sci Rep, 2019, 9, 8670.
    (12) Zuccarello, P.; Ferrante, M.; Cristaldi, A.; Copat, C.; Grasso, A.; Sangregorio, D.; Fiore, M.; Oliveri Conti, G. Water Res, 2019, 157, 365-371.
    (13) Hammel, S. C.; Levasseur, J. L.; Hoffman, K.; Phillips, A. L.; Lorenzo, A. M.; Calafat, A. M.; Webster, T. F.; Stapleton, H. M. Environ Int, 2019, 132, 105061.
    (14) Hendrickson, E.; Minor, E. C.; Schreiner, K. Environ Sci Technol, 2018, 52, 1787-1796.
    (15) Xu, J.-L.; Thomas, K. V.; Luo, Z.; Gowen, A. A. TrAC Trends in Analytical Chemistry, 2019, 119.
    (16) Erni-Cassola, G.; Gibson, M. I.; Thompson, R. C.; Christie-Oleza, J. A. Environ Sci Technol, 2017, 51, 13641-13648.
    (17) COMPOUND SUMMARY 8-Hydroxyquinoline ,National Center for Biotechnology Information, USA. ,https://pubchem.ncbi.nlm.nih.gov/compound/8-Hydroxyquinoline#section=Information-Sources.
    (18) Zhang, F.; Liu, X.; Huang, F.; Zhuo, Z.; Lu, L.; Xu, Z.; Wang, Y.; Tao, X.; Bian, W.; Tang, W. Chinese Science Bulletin, 2011, 56, 479-483.
    (19) Enyedy, E. A.; Domotor, O.; Varga, E.; Kiss, T.; Trondl, R.; Hartinger, C. G.; Keppler, B. K. J Inorg Biochem, 2012, 117, 189-97.
    (20) Prata, J. C.; Reis, V.; Matos, J. T. V.; da Costa, J. P.; Duarte, A. C.; Rocha-Santos, T. Sci Total Environ, 2019, 690, 1277-1283.
    (21) Podpora, M.; Korbaś, G. P.; Kawala-Janik, A., YUV vs RGB—Choosing a Color Space for Human-Machine Interaction. In Position Papers of the 2014 Federated Conference on Computer Science and Information Systems, 2014; pp 29-34.
    (22) 橡皮擦含PVC? 檢驗可膠帶黏、用火燒 ,TVBS 新聞網. ,https://news.tvbs.com.tw/other/103836.
    (23) PVC橡皮擦有毒 影響學童生殖與發育 ,聯合報系 元氣新聞網. ,https://health.udn.com/health/story/6054/348579.
    (24) 橡皮擦禁用可塑劑列國家標準 兒童健康有保障 ,環境資訊中心. ,https://e-info.org.tw/node/59209.
    (25) Tsumura, Y.; Ishimitsu, S.; Saito, I.; Sakai, H.; Tsuchida, Y.; Tonogai, Y. Food Addit Contam, 2003, 20, 317-24.

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