研究生: |
林鈺孝 Lin, Yu-Xiao |
---|---|
論文名稱: |
探討於超重力旋轉床中添加無機鹽類對二氧化碳及氧氣吸收之影響 Effects of Inorganic Salts On Absorption of Carbon Dioxide and Oxygen in a Rotating Packed Bed |
指導教授: |
談駿嵩
Tan, Chung-Sung |
口試委員: |
陳郁文
賴慶智 |
學位類別: |
碩士 Master |
系所名稱: |
工學院 - 化學工程學系 Department of Chemical Engineering |
論文出版年: | 2013 |
畢業學年度: | 101 |
語文別: | 中文 |
論文頁數: | 83 |
中文關鍵詞: | 二氧化碳捕獲 、超重力旋轉床 、氧氣吸收 、無機鹽類 、化學吸收 |
外文關鍵詞: | CO2 Capture, Rotating Packed Bed, Oxygen Absorption, Inorganic Salts, Chemical Absorption |
相關次數: | 點閱:2 下載:0 |
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氧氣裂化吸收劑會增加化學吸收法之操作成本,文獻上多以Na2SO3做為氧氣抑制劑,然而,其具有需補充及清除副產物之問題。本研究以添加無機鹽類之方式,降低氧氣在吸收劑中之飽和溶解度,進而降低吸收劑之溶氧量。由於無機鹽類之添加屬於物理抑制,因此沒有補充鹽類或是去除副產物之必要。
由CO2捕獲實驗結果可知,本研究所添加的四種無機鹽類(KCl、NaCl、LiCl及LiBr),在相同濃度下(1.5 m)因受到Salting-out Effect及Salt Effect之影響,使CO2 Capture Efficiency有0.29%-9.70%之降幅,其中以KCl影響最小。由溶氧量量測結果可知,添加1.5 m之KCl於15% PZ/15% DETA中可使吸收劑之飽和溶氧量降低32.2%。
以反應曲面法對氣體流率、溫度及KCl濃度等三個因子進行分析,結果顯示,氣體流率為影響CO2 Capture Efficiency之最顯著因子,其次為溫度及KCl濃度;而溫度為影響DO Value之最顯著因子,其次為氣體流率及KCl濃度。由Regression Model計算所得之最佳操作條件下,吸收劑DO Value較未添加鹽類之配方降低46.6%,較添加Na2SO3之配方降低10.1%。證明添加無機鹽類進行氧氣抑制具有其可行性,同時,RPB之HTU為0.02 (m)遠低於傳統填充塔之3.4 m,證明以化學吸收法搭配RPB進行CO2吸收,能有效縮減設備體積。
理論再生能耗計算之結果顯示,含鹽配方受到蒸氣壓及比熱下降之影響,在蒸發熱及顯熱部分較不含鹽配方降低5%,可視為此吸收劑配方額外之優點。
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