光合成DNA-奈米粒子複合材料於有機記憶體元件研究

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研究生：	許惟廷 Hsu, Wei-Ting
論文名稱：	光合成DNA-奈米粒子複合材料於有機記憶體元件研究 Photo-triggered DNA-nanoparticles composite in the application of organic memory devices
指導教授：	洪毓玨 Hung, Yu-Chueh
口試委員:	金雅琴黃淑娟
學位類別：	碩士 Master
系所名稱：	電機資訊學院 - 光電工程研究所 Institute of Photonics Technologies
論文出版年：	2012
畢業學年度：	100
語文別：	中文
論文頁數：	109
中文關鍵詞：	DNA 、有機記憶體、奈米粒子、光化學法
相關次數：	點閱：3 下載：0
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近年來去氧核醣核酸 (DNA) 生物高分子逐漸受到越來越多的關注，也發現其應用在光電方面上諸多有潛力的特性，同時由於金屬離子具有易吸附在DNA上的特性，使得DNA為一個適用於金屬奈米粒子合成的模板。
在本研究中我們呈現DNA和數種表面活性劑的製備，並且探討其在光、熱和電方面的特性。此外我們利用光化學法合成銀奈米粒子，應用在有機記憶體元件上，結構為DNA混合銀奈米粒子的有機層包覆銀和ITO電極，此記憶體元件擁有雙穩態的特性，到達臨界電壓時可以從低導態 (OFF) 躍遷成高導態 (ON)，而開關電流比可達102~103，且無論在低導態或高導態，資料儲存時間都可達105秒以上，在此我們提供了一種藉由照光來實現有機記憶體元件的方法。

第一章  文獻回顧與介紹....................................1
    1.1  DNA分子介紹與其應用.............................1
1.1.1  DNA分子簡介............................... 1         1.1.2  DNA材料的發展與其應用.....................3
1.2  金屬奈米粒子的介紹與其應用.......................8
        1.2.1  金屬奈米粒子簡介........................... 8
        1.2.2  金屬奈米粒子的製備方法.....................10
        1.2.3  金屬奈米粒子於DNA分子上之應用............14
        1.2.4  金屬奈米粒子的其他應用.....................15
    1.3  有機記憶體的介紹與其應用........................16
        1.3.1  有機記憶體的發展.......................... 16
        1.3.2  有機記憶體的種類...........................20
        1.3.3  有機記憶體的參數...........................21
1.3.4  傳導機制...................................22
    1.4  研究動機........................................26
    1.5  論文架構........................................27
第二章  DNA材料製備與特性..............................28
    2.1  DNA材料製備................................... 28
        2.1.1  DNA-CTMA製備............................30
        2.1.2  DNA-VBTMA、DNA-BTMA、DNA-PTMA製備... 30
    2.2  DNA材料特性....................................32
        2.2.1  FTIR光譜.................................. 32
        2.2.2  UV光譜....................................35
        2.2.3  折射率.....................................37
        2.2.4  溶解度.................................... 37
        2.2.5  能階.......................................38
        2.2.6  熱特性.....................................39
        2.2.7  薄膜特性...................................40
        2.2.8  電特性.....................................42

第三章  有機記憶體元件製備方法與量測.....................46
    3.1  有機記憶體元件製備方法.......................... 46
    3.2  有機記憶體元件量測儀器..........................53
        3.2.1  電性量測儀器.............................. 53
        3.2.2  TEM量測儀器..............................54
3.2.3  膜厚量測儀器.............................. 54
3.2.4  UV/VIS光譜量測儀器........................55

第四章  結果與討論.......................................57
4.1  TEM量測....................................... 57
4.2  元件特性量測....................................68
        4.2.1  不同照光時間...............................70
    4.2.2  不同濃度...................................73
4.2.3  添加銀奈米粒子.............................75
4.2.4  穩定性量測.................................77
4.2.5  反應時間量測...............................82
4.2.6  C-V量測...................................84
4.3  機制討論........................................88
4.4  DNA-CTMA與DNA-VBTMA之比較.................97

第五章  結論與未來展望..................................99
參考文獻................................................100

                                

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