研究生: |
李佩倫 Pei-Lun Lee |
---|---|
論文名稱: |
利用超重力場及超臨界二氧化碳合併法回收排氣中之VOCs Desorption of VOCs from Activated Carbon by Supercritical CO2 in a Rotating Packed Bed |
指導教授: |
談駿嵩
Chung-Sung Tan |
口試委員: | |
學位類別: |
碩士 Master |
系所名稱: |
工學院 - 化學工程學系 Department of Chemical Engineering |
論文出版年: | 2007 |
畢業學年度: | 95 |
語文別: | 中文 |
論文頁數: | 71 |
中文關鍵詞: | 超重力 、超臨界二氧化碳 、脫附 、四氟丙醇 、甲苯 |
外文關鍵詞: | HIGEE, supercritical CO2, desorption, TFP, Toluene |
相關次數: | 點閱:2 下載:0 |
分享至: |
查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報 |
隨著工業製程的進步,無論是半導體產業,或是其他化學工業,常常需要使用揮發性有機化合物(Volatile Organic Compounds,簡稱VOCs )作為塗裝或清洗等之溶劑,因為大量的生產製造,廢棄的有機溶液或氣體之排放量相當驚人,因此揮發性有機化合物的回收,對於環境品質保護甚為重要。過去在處理廢水廢氣時常使用固定填充床,但由於質傳效果較差,因而常需要龐大的體積才能達到所要處理的目的。以往研究顯示若改變流體性質、填充物性質和流體操作條件可增加分離或反應的效果,若再加上重力場,則溢流(Flooding)的可能性會大幅降低,亦可大幅提升質傳速率。因此,若以高速旋轉填充床(Rotating Packed Bed,簡稱RPB)所產生的超重力場提升質傳速率,則可縮減回收VOCs的設備體積,此種操作稱之為超重力技術(High Gravity,簡稱Higee)。
基於超重力場的特性,本研究分別以四氟丙醇(2,2,3,3-Tetrafluropropanol,TFP)與甲苯(Toluene)作為VOCs之代表,探討當活性碳吸附VOCs後,在超重力場下以超臨界二氧化碳脫附活性碳之效果。實驗數據顯示在315 K下,四氟丙醇與甲苯能有效被活性碳吸附於一填充床中。在超重力場下,超臨界二氧化碳能更有效的脫附四氟丙醇與甲苯,亦即超臨界二氧化碳能結合離心力而在脫附中產生加乘之效果。其脫附效率會隨著轉速及壓力的增加而提升,流速增加亦會提高脫附效率。在較低壓下(8.96 MPa、11.72 MPa),脫附效率隨溫度增加而下降,而在較高壓力下(15.86 MPa),則存在ㄧ最佳操作溫度。當活性碳粒徑較小時,因內部質傳阻力的影響較不顯著,是以提升脫附之速率。就設備體積與脫附效率而言,以超重力旋轉床取代傳統固定床是很好的選擇。
Bansal, R. C.; Donnet, J. B. Activated Carbon, Marcel Dekker Inc.: New York, 1998.
Brady, B. O.; Dooley, K. M.; Knopf, F. C.; Gambrell, R. P. Supercritical Extraction of Toxic Organics from Soil. Ind. Eng. Chem. Res., 1987, 26, 261-268.
Brunauer, S.; Emmett, P. H.; Teller, E. Adsorption of Gases in Multimolecular Layers. J. Am. Chem. Soc., 1938, 60, 309-319.
Chen, Y. S.; Liu, H. S. Absorption of VOCs in a Rotating Packed Bed. Ind. Eng.Chem. Res., 2002, 41, 1583-1588.
Chen, J. H.; Wong, D. S. H.; Tan, C. S.; Subramanian, R.; Lira, C. T.; Orth, M. Adsorption and Desorption onto and from Activated Carbon at High Pressures. Ind. Eng. Chem. Res., 1997, 36, 2808-2815.
Dubinin, M. M.; Plarnik, G. M.; Ezverina, E. F. Integrated Study of the Porous Structure of Activated Carbon from Carbonized Source. Carbon. 1964, 2, 261.
Dubinin, M. M. Adsorption Properties and Microporous Structure of Carbonaceous Adsorbents. Carbon, 1987, 593-598.
DeFilippi, R. P.;Krukonis, V. J.;Robey, R. J.;Modell, M.Supercritical Fluid Regeneration of Activated Carbon for Adsorption of Pesticides, Repor;EPA-00/2-80-054;Washington, DC, 1980.
Dooley, K. M.; Kao, C. P.; Gambrell, R. P.; Knopf, F. C. The Use of Entrainers in the Supercritical Extraction of Soils Contaminated with Hazardous Organics. Ind. Eng. Chem. Res. 1987, 26, 2058-2062.
Erkey, C.; Madras, G. ; Orejuela, M.; Akgerman, A. Supercritical Carbon Dioxide Extraction of Organics from Soil. Environ. Sci. Technol. 1993, 27, 1225-1231.
Guo, K.; Feng, Y.; Yang, C.; Zheng, C. Pressure Drop of Centrifugal Gas Flow Through Rotating Beds. Ind. Eng. Chem. Res. 2000, 39, 829-834.
Guo, F.; Guo, K.; Feng, Y.; Chen, J.; Zheng, C.; Gardner, N. C. Synchronous Visual and RTD Study on Liquid Flow in Rotating Packed-bed Contactor. Chemical Engineering Science., 2000, 55, 1699-1706.
Harriott, P.; Chang, A. T. Y. Kinetics of Spent Activated Carbon Regeneration.AIChE , 1988, 34, 1656-1622.
Jou, C. G. Application of Activated Carbon in a Microwave Radiation Field to Treat Trichloroethylene.Carbon, 1998, 36, 11, 1643-1648.
Kim, K. Carbon-Electronchemical and Physicochemical Properties; John Wiley & Sons, 1987.
Kander, R. G.; Paulaitis, M. E. In Chemical Engineering at Supercrutical Conditions. Ann Arbon Science., 1983, 461.
Kumar, M. P.; Rao, D. P. Studies on a High-Gravity Gas-Liquid Contactor. Ind. Eng. Chem. Res ,1990, 29, 917-920.
Kunio, K.; Kenji, M. ; Yoshinori, S. The Thermal Regeneration of Spent Activated Carbon. J. Chem. Eng. Jap. ,1980, 13(3), 214-219.
Langmuir, I. Adsorption of Gases by Solids. J. Am. Chem. Soc., 1916, 38 (10), 2267-2295.
Langmuir, I. Adsorption of Gases on Plane Surface of Glass Mica and Platinum. J. Am. Chem. Soc., 1918, 40, 1361-1382.
Lin C. C.; Liu, H. S. Adsorption in Centrifugal Fields Basic Dye Adsorption by Activated Carbon. Ind. Eng. Chem. Res. , 2000, 39, 161-167.
Lin, C. C. Application of Granular Activated Carbon for Water And Wastewater Purification. PhD Dissertation, university of Texas at Dallas, USA, 1982.
Lin, C. C.; Chen, Y. S.; Liu, H. W. Adsorption of Dedecane from Water in a Rotating Packed Bed. J. Chin. Inst. Chem. Engrs.,2004, 5, 531-538.
Liu, H. S.; Lin, C. C.; Wu, S. S.; Hsu, H.W. Characteristics of a Rotating Packed Bed. Ind. Eng. Chem. Res. 1996, 35, 3590-3596.
Macnaughton, S. J.; Foster, N. R. Supercritical Adsorption and Desorption Behavior of DDT on Activated Carbon Using Carbon Dioxide. Ind. Eng. Chem. Res., 1995, 34, 275-282.
Madras, G.; Erkey, C.; Akgerman, A. Supercritical Fluid Regeneration of Activated Carbon Loaded with Heavy Molecular Weight Organics. Ind. Eng. Chem. Res., 1993, 32, 1163-1168.
Modell, M.; Robey, R. J.; Krukinis, V. J.; DeFilippi, R. P.;Oestreich, D. Supercritical Fluid Regeneration of Activated Carbon. Presented at the AIChE Meeting, Boston, 1979.
Munjal S.; Dudukovic M. P.; Ramachandran, P. A. Mass Transfer in Rotating Packed Beds: I. Development of Gas-Liquid and Liquid-Solid Mass-Transfer Coefficients. Chem. Eng. Sci. 1989a, 44, 2245-2256.
Munjal S.; Dudukovic M. P.; Ramachandran, P. A. Mass Transfer in Rotating Packed Beds: II. Experimental Results and Comparison with Theory and Gravity Flow. Chem. Eng. Sci. 1989b,44, 2257-2268.
Perrotti, A. E., Rodman, C. A. Factors involved with Biological Regeneration of Activated Carbon. AIChE, 1974, 70 (144), 317-325
Ramshaw, C.; Mallinson, R. H. Mass Transfer Process. U.S. Patent 4, 383, 255, 1981.
Rao, D. P.; Sharma, A. Gas-Phase Mass Transfer in a Centrifugal Contactor. Ind. Eng. Chem. Res. 2001, 40, 384-392.
Rao, D. P.; Goswami, P. S.; Bhowal, A. Process Intensification in Rotating Packed Beds(HIGEE) : An Appraisal. Ind. Eng. Chem. Res., 2004, 43, 1150-1162.
Recasens, F.; McCoy, B. J.; Smith, J. M. Desorption Processes : Supercritical Fluid Regeneration of Activated Carbon. AIChE, 1989, 35(6), 951-958.
Schnider, G. M. Physicochemical Principles of Extraction with Supercritical Gases. Angew. Chem. Int. Ed. Engl., 1978, 17, 716-727.
Smisek, M.; Cerny, S. Activated Carbon; Elserier : New York, 1970.
Srinivasan, M. P.; Smith, J. M.; McCoy, B. J. Supercritical Fluid Desorption from Activated Carbon. Chem. Eng. Sci., 1990, 45 (7), 1885-1895.
Stenzel, M. H. Removal Organics by Activated Carbon Adsorption. Chemical Engineering Process., 89(4), 1993, 36-43.
Sutlkno,T.; Himmelstein, K. J. Desorption of Phenol from Activated Carbon by Solvent Regeneration. Ind. Eng. Chem. Fundam., 1983, 22, 420-425.
Tan, C. S. ; Liou, D. C. Desorption of Ethyl Acetate from Activated Carbon by Supercritical Carbon Dioxide. Ind. Eng. Chem. Res., 1988, 27, 988-991.
Tan, C. S.;Liou, D. C. Supercritical Regeneration of Activated Carbon Loaded with Benzene and Toluene. Ind. Eng. Chem. Res., 1989a, 28, 1222-1226.
Tan, C. S.;Liou, D. C. Regeneration of Activated Carbon Loaded with Toluene by Supercritical Carbon Dioxide. Sep. Sci. Technol., 1989b, 24(1-2), 111-127.
Tan, C. S.; Lin, C. C; Liu, W. T. Removal of Carbon Dioxide by Absorption in a Rotating Packed Bed. Ind. Eng. Chem. Res., 2003, 42, 2381-2386.
Vivian, J. E.; Brain, P. L. T.; Krukonis, V. J. Influence of Gravitational Force on Gas Absorption in Packed Columns. AIChE, 1965, 11, 1087-1090.
Walker, P. L.; Cariaso, O. C.; Ismail, I. M. K. Oxygen Chemisorption on As-Received and Acid-Treated Activated Carbon. Carbon, 1980, 18, 375-377.
Zhang, J. Experiment ang Modeling of Liquid Flow and Mass Transfer in Rotating Packed Bed. PhD Dissertation, Beijing University of Chemical Technology.
Zheng, C. ; Guo, K. ; Feng, Y. ;Yang, C.; Gardner, N.C. Pressure Drop of Centripetal Gas Flow through Rotating Beds. Ind. Eng. Chem. Res., 2000, 39, 829-834.
蔣本基., "活性碳物理化學特性對VOCs吸附之影響, " 工業污染防治手冊,第58期, 1996.
蔣本基、張璞, "有機溶劑蒸氣之吸附及脫附研究," 工業污染防治,第58期, 1996.
邱正宏, "吸附於活性碳表面揮發性有機物之熱脫附動力學研究, " 碩士論文,國立中山大學環境工程研究所(1993)。
楊英傑,"以球狀活性碳吸附水溶液中甲苯及其脫附方法之研究," 碩士論文,國力成功大學化學工程研究所 (1992)。
鄭仲恩, "以超重力技術自排放氣體中移除二氧化碳," 碩士論文,國立清華大學化學工程研究所(2004)。
陳昱邵, "旋轉填充床中黏度對貭傳影響之研究," 博士論文,國立台灣大學化學工程研究所(2004)。
賴慶智, "超臨界狀態下之吸附及擴散現象," 博士論文,國立清華大學化學工程研究所(1993)。