簡易檢索 / 詳目顯示

研究生: 于璉光
Yu, Lien Kuang
論文名稱: 利用三光布拉格表面繞射量測Si/Si0.8Ge0.2/Si介面應力變化
Probing Interfacial Strains in Si/Si0.8Ge0.2/Si Using Three-Beam Bragg-Surface Diffraction
指導教授: 張石麟
Chang,Shih Lin
口試委員: 黃玉山
Huang, Yu Shan
蘇雲良
Soo,Yun-Liang
學位類別: 碩士
Master
系所名稱: 理學院 - 物理學系
Department of Physics
論文出版年: 2016
畢業學年度: 104
語文別: 中文
論文頁數: 49
中文關鍵詞: 三光布拉格表面繞射介面應力同步輻射實驗
外文關鍵詞: Three-Beam Bragg-Surface Diffraction, Interfacial Strains, NSRRC
相關次數: 點閱:3下載:0
分享至:
查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報
  • 現今的半導體元件中,大部分是由薄膜系統所構成,在奈米尺寸下,其應變(strain)對元件特性有顯著的影響,為了可以更清楚了解元件的特性,本實驗利用X光三光布拉格表面繞射(X-ray Three-Beam Bragg-Surface Diffraction,BSD)實驗方法進行介面應力的探討。
    本實驗於國家同步輻射研究中心BL17B1光束線進行,利用對稱式布拉格繞射光和一個沿著樣品表面傳遞之表面繞射光所組成之布拉格表面繞射幾何,以能量為12keV的入射光同時激發基板與薄膜,收取空間強度分布解析介面應變。
    本實驗之樣品為矽與矽鍺薄膜成長在矽基板上,以Si/Si0.8Ge0.2/Si表示,利用布拉格表面繞射之幾何,並選擇(0 0 4)/(2 0 2)、(0 0 4)/(0 2 2)、(0 0 4)/(-2 0 2)三組反射面,藉由空間強度分布圖解析得知矽鍺為三斜晶體(triclinic structure),矽為正交晶體(orthorhombic structure),且矽鍺為了與矽晶體匹配,將其a、b軸縮短(Δa、Δb <0),並利用c軸釋放其應變(Δc >0)。


    The semiconductor devices are composed of thin-film systems, therefore, the strain is one of the important factors to the performance of the device. We probe interfacial strains in Si/Si0.8Ge0.2/Si using three-beam Bragg-surface diffraction.
    The experiment was performed on BL17B1 beamline at the National Synchrotron Radiation Research Center (NSRRC).The Bragg-surface diffraction consists of a symmetric Bragg diffraction and a surface diffraction, propagating along the interface of the sample. The incident X-rays are 12keV and excite the substrate and thin film simultaneously. The interfacial strains are analyzed according to the spatial intensity distributions.
    The sample is a silicon and silicon-germanium thin films grown on the silicon substrate(Si/Si0.8Ge0.2/Si).Three reflecting surfaces,(0 0 4)/(2 0 2)、(0 0 4)/(0 2 2)、(0 0 4)/(-2 0 2), are measured in this study. We find that the silicon-germanium is a triclinic structure and the silicon is nearly a orthorhombic structure. The thin film is deformed to accommodate the lattice mismatches so that the a and b-axis are shortened and the c-axis is stretched.

    目錄 中文摘要........................I 英文摘要........................II 誌謝...........................III 目錄...........................IV 圖表目錄........................V 第一章 緒論.....................1 第二章 材料介紹與樣品分析........2 2.1 Si1-xGex材料介紹.....................2 2.2 樣品分析.....................3 第三章 理論介紹.....................5 3.1 基本波場方程式.....................5 3.2 波場分布.....................8 3.3 邊界條件.....................13 第四章 實驗原理與分析方法.....................15 4.1三光布拉格表面繞射.....................15 4.2掠角繞射.....................20 4.3晶格常數分析方法.....................21 4.3.1晶格常數理論計算.....................21 4.3.2二階表面繞射光與入射光波向量之修正...........24 第五章 實驗方法.....................28 5.1光源與儀器介紹.....................28 5.2實驗步驟與方法.....................29 第六章 實驗結果與分析.....................34 6.1布拉格繞射與掠角繞射.....................34 6.2 三光布拉格表面繞射實驗.....................35 6.2.1實驗二階表面繞射光選取與實驗結果...........35 6.2.2改變方位角φ之實驗結果....................41 6.3薄膜強度震盪分析.............................45 第七章 結論.......................................48 參考文獻..........................................49

    參考文獻
    [1].姚潔宜,”X光的奇妙世界”,奈米通訊 NANO COMMUNICATION 22卷No.2
    [2].林麗娟,”X光繞射原理及其應用”,工業材料86期, 83年2月
    [3]. Roberts, M.M. et al. “Elastically relaxed free-standing strained-silicon nanomembranes.” Nature Mater.5,388-393(2006)
    [4]. J. P. Dismukes,”Lattice Parameter and Density in Germanium-Silicon Alloys.” J.Phys.Chem.68,3021-3027
    [5]. John C. Bean “Strained-Layer Epitaxy of Germanium-Silicon Alloys.” Science.230,127-131(1985)
    [6]. S.-L. Chang, “X-ray multiple-wave diffraction: theory and Applications”, Springer, Berlin(2004)
    [7]. Yu.P.Stetsko, and S.-L. Chang, “An Algorithm for Solving Multiple-Wave Dynamical X-ray Diffraction Equations.” Acta Cryst. A5328-34(1997)
    [8].J.-H. Yan, ”Studying of Probing Interfacial Strains in ZnO/Al2O3 Using Multi-Beam X-ray Diffraction.” Mater’s thesis, NTHU(2014).
    [9].Y.-Z Zheng, “Depth profiles with sub-picometer resolution of the interfacial strains of Si0.7Ge0.3/Si using three-beam Bragg-surface diffraction.” Doctor’s thesis, NTHU(2015).
    [10]. T.-W. Wu,” Study of Probing Interfacial Strains in SiGe/Si Using Three-Beam Bragg-Surface Diffraction.” Mater’s thesis, NTHU(2014).
    [11]. C.-H. Chu,” Measuring Strain Field of Semiconductor Surface Structure by Dynamical Effects of X-ray Bragg-surface Diffraction.” Doctor’s thesis,NTHU(2010).

    無法下載圖示 全文公開日期 本全文未授權公開 (校內網路)
    全文公開日期 本全文未授權公開 (校外網路)

    QR CODE