本論文旨在以簡單快速的方法合成不同形貌的二氧化鈦
anatase 奈米顆粒與三維奈米結構。第一部份是以非水溶液的溶
膠-凝膠法，加入不同配位基與調整合成溫度，來控制二氧化鈦的
非等向性成長，產生不同的形貌的奈米顆粒。透過 X 光粉末繞射
儀與電子顯微鏡，來對合成的奈米顆粒的結構、大小、形貌與自
組裝的行為進行分析，並且使用核磁共振儀與傅立葉紅外光譜
儀，討論反應參數對合成機制的影響。本論文中，我們合成出具
有暴露較大 {001} 晶面並小於 3 nm 的二氧化鈦 anatase 奈米顆
粒，以及子彈型、六角柱形、長棒狀的二氧化鈦奈米顆粒。第二
部份為利用奈米顆粒作為建造基本單元 (NBBs) ，以不同的界面
活性劑，合成出具有高度結晶性的中孔洞二氧化鈦奈米結構，預
期未來在光催化的應用上具有發展潛力。

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