本論文旨在利用兩端親水、中間疏水的兩性高分子與不同構形及親疏水端類型之分子，合成多層次孔洞MFI與CHA沸石，調控並觀察其對沸石結構、形貌與孔洞性質的影響。在合成具MFI結構silicalite-1沸石部分，我們嘗試混入陽離子界面活性劑、胺基高分子、三甲基苯等分子，發現帶正電的四級銨親水端或長丙氧基鏈疏水段對於多層次孔洞silicalite-1的合成及其形貌影響最為顯著。另一方面，我們設計不同親疏水端種類的兩性高分子，混合結構導向試劑三甲基金剛烷氫氧化銨 (TMAdaOH) 合成具CHA結構的SSZ-13沸石，並觀察到不同兩性高分子對引導沸石結構、形貌的顯著差別，例如共價鍵結二甲基化金剛烷胺與二溴丁烷所合成之親水端與結構間作用力較強，受短丙氧基鏈限制其自由度而干擾CHA結構形成，以及長丙氧基鏈疏水段會在沸石表面造成缺陷的現象。此外，我們嘗試調整TMAdaOH與兩性高分子間的比例，得到有少量中孔洞形成且表面帶有缺陷的球狀SSZ-13沸石顆粒。

In this study, we aimed at design of tri-block polymers comprising propylene oxide chain connecting two ends of triquaternary ammonium groups, and used them and molecules with different types of amphiphilic groups for the synthesis of hierarchical zeolites in order to observe their influences on zeolite structure, morphology, and porosity. In the synthesis of hierarchical silicalite-1 with MFI structure, we added compunds including hexadecyl-trimethyl-ammonium bromide, poly(propylene glycol) bis(2-aminopropyl ether), or 1,3,5-trimethylbenzene and found that the surfactant with cationic quaternary ammonium groups or long propylene oxide chain strongly influenced the structure, crystallinity, and morphology of hierarchical silicalite-1. On the other hand, in the synthesis of SSZ-13 with CHA structure, we added tri-block polymers designed with different amphiphilic groups to synthesize hierarchical SSZ-13 with N,N,N-trimethyl-1-adamantammonium hydroxide (TMAdaOH) as structure-directing agent. We observed that the tri-block surfactants with different amphiphilic group induced the formation of zeolitic materials with diverse mophology and affected the zeolite crystallinity. We noted that 1-adamantyl-N+(CH3)2-C4H8Br hydrophilic group that interacts strongly with zeolite framework interfered the CHA structure formation when it is confined by short propylene oxide chain, and that tri-block polymers with long propylene oxide chain created defects on the surface of zeolite particles. Besides, we adjusted the ratio of TMAdaOH and tri-block polymers to synthesize spherical SSZ-13 particles with irregular surface defects and some mesoporosity.

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