本篇論文主要是利用X光及中子小角度散射法，來研究聚苯胺高分子及其碳六十星狀衍生物於溶液中之聚集行為。聚苯胺高分子為一種共軛性導電高分子，其結構為長鏈狀且較剛硬。而碳六十分子為一足球狀結構，具有三十個雙鍵及電子轉移特性。利用化學合成的方法，可將六根的聚苯胺高分子鍵結至碳六十分子上，形成具有多個導電方向之星狀碳六十衍生物。
研究結果發現聚苯胺高分子溶於溶液中即VJ114樣品，分子間會相互吸引而聚集形成長棒狀之結構。而星狀碳六十衍生物即VJ118樣品，其分子間並無緊密的聚集情況出現，但分子與分子之間仍有交互作用力存在。顯示此種星狀導電結構，其分子間的結構較為鬆散，而導電性質將類似人體中神經之傳導。希望藉此研究之結果，能使此種星狀導電結構在製作上有更大的突破，且未來對於聚苯胺高分子與星狀碳六十衍生物將有更廣泛的應用。

[1] H.W.Kroto ,J.R.Heath ,S.C.O’Brien ,R.E.Smalley ,”C-60-Buckminsterfullerence”, Nature,Vol.318 ,pp.162(1985)
[2] R. M. Baum, “Commercial Uses of Fullerenes and Derivatives Slow to Develop” ,Chemical and Engineering News,vol. 71, pp.8(1993)
[3] J. C. W. Chien. “Polyacetylene: Chemistry. Physics. And Material Science”, Academic Press, Orlando, (1984).
[4] G. Natta. G. Mazzanti and P. Corradini, Atti Accad. Naz. Lince Rend. Cl. Sci. Fis.. Mat. Nature. 25 (1958) 3.
[5] H. Naarmann, “Structure and conductivity of organic polymers”, Angew. Chem. Int. Ed., 8 (1969) 915
[6] H. shirakawa and S. Ikeda, Polym. J. 2 (1971) 232.
[7] C.K. Chiang, C. R. Fincher Jr, Y. W. Park, A. J. Heeger, H. Shirakawa, E. J. Louis. S. C. Gau. A. G. MacDiarmid, “Electrical conductivity in doped polyacetylene”, Phys. Rev. Lett., 39 (1977) 1098
[8] W. I. David, R. M. Ibberson, J. C. Matthewman, K. Prassides, T. J. Dennis, J. P. Hare, H. W. Kroto, R. Taylor and D. R. Walton, “Crystal-Structure and Bonding of Ordered C60”, Nature, vol. 353, pp. 147 (1991)
[9] S. Bywater, “Spectroscopic Studies on the Nature of the Active-Centers in Anionic-Polymerization”, Polymer Journal, vol 12, pp. 549 (1980)
[10] Shokoku Kanaoka; Mitsuo Sawamoto and Toshinobu igashimura, “Star-Shaped Ploymers by Living Cationic Polymerization .1. Synthesis of Hetero Arm Amphiphilic Star-Shaped Polymers of Vinyl Ethers with Hydroxyl or Carboxyl Pendant Groups”, Macromol., vol. 24, pp. 2309 (1991)
[11] L. Y. Chiang, L. Y. Wang, J. S. Wu, K. H. Hsieh, “Fullerenol Derived Urethane-Connected Polyether Dendritic Polymers” J. Chem. Soc., Chem. Commun., pp. 2675 (1994)
[12] Long Y. Chiang, Lee Y. Wang, “Fullerenol Derived Urethane- Connected Polyether Dendritic Polymers” J. Chem. Soc., Chem. Commun., 2675-2676(1995)
[13] Long Y. Chiang, Lee Y. Wang, “Synthesis of polyurethane elastomers hypercross-linked by partially hydrated polyhydroxylated C60” J. poly. Reseach vol3, no.1,1-10(1996)
[14] Long Y. Chiang, Lee Y. Wang, “Synthesis of novel conducting elastomers as polyaniline-interpenetrated networks of fullerenol-polyurethanes”, Synthetic Metals84(1997)721-724(1997)
[15] L. A. Feigin and D. I. Svergun, Structure Analysis by Small Angle X-Ray and Neutron Scattering, Plenum, New York, 1987
[16] Vijayaraj Anantharaj, Lee Y.Wang, Taizoon Canteenwala and Long Y. Chang*,J. Chem. Soc.,Perkin Trans. 1,1999
[17] O. Glatter and O. Kratky, Small Angle X-ray Scattering, Academic, London, 1982.
[18] 劉文俊，清華大學工程與系統科學系博士論文，2000
[19] 宋承真，清華大學原子科學研究所碩士論文，1995
[20] 黃啟振，清華大學原子科學研究所碩士論文，1996