研究生: |
簡欣怡 Chien, Hsin-Yi |
---|---|
論文名稱: |
製備聚醯胺-胺樹狀高分子/金屬複合奈米粒子作為雷達/紅外線兼容隱身材料之研究 Preparation of dendrimer / metal nanocomposites for compatible stealth materials between radar and infrared region |
指導教授: |
李育德
Lee, Yu-Der |
口試委員: | |
學位類別: |
碩士 Master |
系所名稱: |
工學院 - 化學工程學系 Department of Chemical Engineering |
論文出版年: | 2010 |
畢業學年度: | 98 |
語文別: | 中文 |
論文頁數: | 88 |
中文關鍵詞: | 紅外和雷達複合隱身材料 、樹狀大分子 、四氧化三鐵 、奈米銀 |
外文關鍵詞: | Infrared and radar multi-functional camouflage, Dendrimer, Iron oxide, silver nanoparticles |
相關次數: | 點閱:3 下載:0 |
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因四氧化三鐵奈米磁性粒子具磁滯現象,有助於雷達波損耗;而奈米銀粒子則具低發射率,可作為紅外線隱身材料,故實驗將製備金屬銀/四氧化三鐵奈米複合粒子,希望本材料能兼具雷達波及紅外線的隱身效果。
本研究可分為兩部份,第一部份為聚醯胺-胺樹狀高分子PAMAM之合成,希望能掌握合成步驟及結果鑑定方法,研究結果顯示,目前掌握合成技術至第四代,且產量可達25克以上。
第二部份為聚醯胺-胺高分子複合奈米粒子之研究,先利用樹狀分子內部空腔製備奈米銀粒子(dendrimer-encapsulated silver nanoparticles) ,並由TEM影像鑑定結果,確定所製備出的奈米銀粒子粒徑約為3 nm且分散性極佳;再經由調控反應溫度製備粒徑約20 nm之四氧化三鐵奈米粒子,為避免其聚集,對其作表面修飾,先使帶負電性之聚苯乙烯磺酸鈉披覆在四氧化三鐵表面,並經zeta potential 、EDAX及FT-IR等結構組成分析確定其包覆成功;之後,再使帶正電之奈米銀粒子包覆其上,以UV-Vis、zeta potential、EDAX、XRD及FT-IR等做結構鑑定,並以TEM作型態觀察,其聚集體大小約130 nm。
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