碳化矽/碳化矽複合材料是目前核能材料中最具潛力之一，其性質優異，如：低活性、高溫機械性質佳、輻射穩定性佳、抗腐蝕…等，而本論文的主要目的則是模擬核融合反應器高溫輻射環境，研究Hi-Nicalon Type-S(HNS)碳化矽纖維/碳化矽複合材所受之輻射效應。
由於先前尚偉學長實驗中，曾發現倘若矽離子分佈與三射束共同效應區重疊，會使得氦氣泡高溫成長不明顯，也許是矽離子形成間隙原子並與空缺再結合，降低整體的材料輻射損傷，無法提供足夠的過飽和空缺來形成氦氣泡。是故本論文討論的情況刻意將共同效應區與矽離子分佈區安排至不同深度。利用本校儀器組之加速器建立起『三射束照射系統』，在特定三射束離子能量下：5.4MeV-Si3+、 740keV-He+、270keV-H+，分別進行四組三射束照射實驗，其佈值條件為：1100℃/10dpa、1200℃/10dpa、1300℃/10dpa、1200℃/80dpa，其中氦、氫濃度對材料損傷比皆分別為150appm/dpa、60appm/dpa。在低計量10dpa照射實驗中，我們皆在基材中發現氦氣泡析出，其分佈型態偏向細小且數量多(大小約2~3nm，密度約2×1022 個/m3)，這是因為氫擴散速率遠高於氦原子，有效地分散成核點並抑止氦氣泡成長所致；而溫度的提高，使得氦、氫原子及空缺擴散速率提高更容易聚集，有助於氦氣泡析出並產生粗化效應，使氦氣泡變大但是數量減少。
由於在1200℃10dpa的實驗條件下可以觀測到較大的氦氣泡，所以特別在該溫度做高劑量的照射實驗。實驗結果亦顯示，在高劑量三射束效應下材料微結構易產生劇烈變化，尤其在1200℃效應更是重大威脅。相較先前尚偉學長之高劑量實驗，800℃/100dpa時氦氣泡雖密度高(1.82×1023個/m3)，析出氦氣泡卻小(近乎高溫低劑量10dpa的結果2~3nm)，且纖維區未見氦氣泡蹤跡。再回顧1000℃/100dpa的實驗中，基材纖維都出現氣泡，且基材區有兩種尺寸的分佈(3.61nm與9.4nm)，小者密度高(1.46×1023個/m3)而大者密度低(7.11×1021個/m3)，與本論文的1200℃/80dpa結果(氦氣泡出現兩種尺寸且粗化效應更趨顯著，密度下降至1022個/m3)互有異同之處。未來應以高溫氦氣泡遷移研究為主，以深入了解其中機制。

[1] 曾煥華，“向核融合挑戰”，1986， 銀禾文化出版商
[2] Weston M. Stacey, Jr.，Fusion：An Introduction to the Physics and Technology of Magnetic Confinement Fusion， 1984，A Wiley-Interscience publication.
[3] 牛頓雜誌, 七月號/1998, 182期, p90~95.
[4] Arthur Beiser, Concepts of Modern Physics, 5th edition, 1995, McGraw-Hill, Inc.
[5] Wesson J., 1997, Tokamaks, Clarendon Press Oxford.
[6] Jean-Marie Noterdaeme, ICENES 2005, Brussels, August 22, 2005.
[7] R. H. Jones, D. Steiner, H. L. Heinisch, G. A. Newsome, H. M Kerch, J. Nucl. Mater. 245 (1997) 87-107.
[8] M. Saito, A. Hasegawa, S.Ohtsuks, K. Abe, J. Nucl. Mater. 258-263 (1998) 1562.
[9] E.V. Dyomina , P. Fenici , V.P. Kolotov , M. Zucchetti Journal of Nuclear Materials 258-263 (1998) 1784-1790.
[10]L.L. Snead, R.H. Jones, A. Kohyama, P. Fenici, J. Nucl. Mater. 233-237 (1996) 26-36.
[11]P. Fenici, A.J. Frias Rebelo, R.H. Jones, A. Kohyama, L.L. Snead, J. Nucl. Mater. 258-263 (1998) 215.
[12]R.H. Jones, L. Giancarli, A. Hasegawa, Y. Katoh, A. Kohyama, B. Riccardi, L.L. Snead, W.J. Weber, J. Nucl. Mater. 307-311(2002) 1057-1072
[13]B. Riccardi, L. Giancarli, A. Hasegawa, Y. Katoh, A. Kohyama, R.H. Jones, L.L. Snead, J. Nucl. Mater. 329-333(2004) 56-65
[14] L.H. Rovner and G.R. Hopkins, Nucl. Technol. 29 (1976) 274.
[15]Satoru Tanaka, Introduction to Fusion Reactor Engineering, 2001.
[16]Y. Katoh, A. Kohyama, K. Morishita, A. Kimura, Introduction to Fusion Reactor Engineering, 2001.
[17]G.R. Hopkins, R.J. Price, Nucl. Eng. Des.Fusion, Vol.2 Issue 1(1985) p.111~143
[18]R.H. Jones, Environmental Effects on SiC/SiC Composites For Fusion Structural Applications, Fusion Reactor Materials Semi-Annual Progress Report for period ending 31, 1991, DOE/ER-0313/10, p.215.
[19]T. Sample, P.Fenici, H. Kolbe, L. Orecchia, J. Nucl. Mater 212-215(1994) 1529
[20]Krishan K. Chawla, Composite Materials, 2nd edition, 1998, Springer
[21]A.R. Raffray, R.Jones, G. Aiello, M. Billone, L. Giancarli et al., Fusion Engng Des. 55 (2001) 55.
[22]KRISHAN K. CHAWLA, Composite materials.
[23]Michio Takeda, Yoshikazu Imai, Hiroshi Ichikawa, Noboru Kasai, Tadao Seguchi, Kiyohito Okamura, Comp. Sci. Tech. 59 (1999) 793-799.
[24]Michio Takeda, Akira Urano, Jun-ichi Sakamoto, Yoshikazu Imai, J. Nucl. Mater. 258-263 (1998) 1594-159.
[25]A. Hasegawa, A. Kohyama, R. H. Jone, L. L. Snead, B. Riccardi, P. Fenici, J. Nucl. Mater. 283-287 (2000) 128-137.
[26]Michio Takeda, Jun-ichi Sakamoto, Yoshikazu Imai, Hiroshi Ichikawa, Comp. Sci. Tech. 59 (1999) 813-819
[27]Michio Takeda, Akira Urano, Jun-ichi Sakamoto, Yoshikazu Imai, J. Nucl. Mater. 258-263 (1998) 1594-1599
[28]Hiroshi Araki, Hiroshi Suzuki, Wen Yang, Shinji Sato, Tetsuji Noda, J. Nucl. Mater. 258-263 (1998) 1540-1545.
[29]Development of SiC/SiC Composite for Fusion Application, A. Kohyama , Y. Katoh , L.L. Snead and R.H. Jones.
[30]T. Hinoki, L.L. Snead, Y. Katoh, A. Hasegawa, T. Nozawa, A. Kohyama, J. Nucl. Mater. 307-311(2002) 1157-1162.
[31]R. Yamada, T. Taguchi, N. Igawa, J. Nucl. Mater. 283-287 (2000) 574-578
[32]J. W. Warren, Ceram. Eng. Sci. Proc., (1985)
[33]T. M. Besmann, B.W. Sheldon, R.A. Lowden, and D. P. Stinton, Science, Vol. 253, (1991)
[34]Y. Katoh, A. Kohyama, Introduction to Fusion Reactor Engineering.
[35]J. J. Brennan, Acta Mater. 48(2000) 4619-4628.
[36]S. P. Lee, Y. Katoh, J. S. Park, S. Dong, A. Kohyama, S. Suyama, H. K. Yoon, J. Nucl. Mater. 289 (2001) 30-36.
[37]S. P. Lee, Y. Katoh, A. Kohyama, Scripta mater. 44 (2001) 153-157.
[38]T. Yano, K. Budiyanto, K. Yoshida, T. Iseki, Fusion Engng Des. 41(1998)157-163.
[39]Y.W. Kim, J.S. Song, S.W. Park, J.G. Lee, J. Mater. Sci. 28(1993) 3866.
[40]T. Tanaka, N. Tamari, I. Kondoh, M. Iwasa, J. Ceram Soc. Japan 103(1)(1995)1.
[41]K. Park, J. Mater. Sci. 32(1997)295-300
[42]Bor-Wen Lin, J. Am. Ceram. Soc. 69(1986)C67
[43]T. Hinoki, W. Zhang, A. Kohyama, S. Sato, T. Noda, J. Nucl. Mater. 258-263 (1998) 1567-1571.
[44]C. A. Lewinsohn, R. H. Jones, G. E. Youngblood, C. H. Henager Jr. J. Nucl. Mater. 258-263 (1998) 1557-1561.
[45]C.H. Henager Jr., R.H. Jones, J. Am Ceram. Soc. 77(1994) 2381
[46]Michio Takeda, Yoshikazu Imai, Yutaka Kagawa, Shu-Qi Guo, Mater. Sci. Eng. A286 (2000) 312-323.
[47]T.M. Besmann, J.C. McLaughlin, Hau-Tay Lin, J. Nucl. Mater. 219(1995) 31-35
[48]L.L. Snead, M.C. Osborne, R.A. Lowden, J. Strizak, R.J. Shinavski, K.L. More, W.S. Eatherly, J. Bailey, A.M. Williams, J. Nucl. Mater. 253(1998) 20-30.
[49]C. Droillard, J. Lamon, X. Bourrat, Mat. Res. Soc. Proc., 1995, 365, 371-376.
[50]Droillard, C. and Lamon, J., J. Am. Ceram. Soc., 1996, 79(4), 849-858.
[51]T. Hinoki, L.L. Snead, Y. Katoh, A. Kohyama, R. Shinavski, J. Nucl. Mater. 283-287(2000) 376-379.
[52]Takashi Nozawa, Kazumi Ozawa, Sosuke Kondo, Tatsuya Hinoki, Yytai Katoh, Lance L. Snead, Akira Kohyama, J. ASTM International, March 2005, Vol.2, No.3
[53]T. Taguchi, T. Nozawa, N. Igawa, Y. Katoh, S. Jitsukawa, A. Kohyama, T. Hinoki, L.L. Snead, J. Nucl. Mater. 329-333(2004) 572-576
[54]H. Kishimoto , Y. Katoh , A. Kohyama J. Nucl. Mater. 307–311 (2002) 1130–1134.
[55]方柏傑，國立清華大學工程與系統科學研究所碩士論文，2002.
[56]W. Zhang, T. Hiniki, Y. Katoh, A. Kohyama, T. Noda, T. Muroga, J. Yu, J. Nucl. Mater. 258-263 (1998) 1577.
[57]J.F. Ziegler, J.P. Biersack, and U. Littmark, Stopping and Range of Ions in Solids, Vol. 1 (Pergamon Press, New York,1985)
[58]物理會刊十二卷一期1990年
[59]Donald R. Olander, “Fundamental aspects of nuclear reactor fuel elements”, 1976.
[60]L. El-Guebaly, ARIES II/IV Report, to be published
[61]科儀叢書3, 材料電子顯微鏡學, 國科會精儀中心.
[62]汪建民, 杜正恭, 材料分析 中國材料科學學會 1998.
[63]R. F. Egerton, “Electron-energy loss spectroscopy in the electron microscopy “, Plenum Press, New York, (1996)
[64]H. Shuman, C. F. Chang and A. P. Somlyo, Ultramicorsc., 19,121 (1986).
[65]F. Hofer and P. Warbichler, Ultramucrosc., 63:21 (1996)
[66]N. Bonnet, C. Coliex, C. Mory and M. Tence, Scanning Microscopy 2(Suppl.) 351 (1988)
[67]A. Berger, J. Mayer and H. Kohl, Ultramicrosc., 55:101 (1994)
[68]P. A. Crozier and R. F. Egerton, Ultramicrosc., 27:9 (1988)
[69]D. B. Williams and C. B. Carter, “Transmission Electron Microscopy”, Plenum Press. New York & London, (1996)
[70]T. Malis, S. Cheng and R. F. Egerton, J. Electron. Microsc. Tech. 8:8471 (1988)
[71]T. Hinoki, W. Zhang, A. Kohyama, S. Sato, T. Noda, Journal of Nuclear Materials 258-263 (1998) 1567-1571
[72]S. Sato, H. Serizawa, H. Araki, T. Noda, A. Kohyama, Journal of Alloys and Compounds 355 (2003) 142–147.
[73]Tetsuji Noda, Mitsutane Fujita, Hiroshi Araki, Akira Kohyama, Fusion Engineering and Design, 61-62 (2002) 711-716.
[74]P. Jung, J. Nucl. Mater. 191–194 (1992) 377.
[75]A. Hasegawa, M. Saito, S. Nogami, K. Abe, R.H. Jones, H. Takahashi, J. Nucl. Mater. 264 (1999) 355.
[76]Tjacka Bus, Properties of Silicon Carbide, 2001.
[77]Lim CS, JOURNAL OF MATERIALS SCIENCE 35 (12): 3029-3035 JUN 2000.
[78]曾子懷，國立清華大學工程與系統科學研究所碩士論文,2005.
[79] P. Jung, J. Nucl. Mater, 191-194 (1992) 377.
[80]G.A. Esteban, A. Perujo, F. Legarda, L.A. Sedano, B. Riccardi, Journal of Nuclear Material, 307-311 (2002) 1430-1435
[81] A. Hasegawa, B. M. Oliver, S. Nogami, K. Abe, R. H. Jones, J. Nucl. Mater. 283-287 (2000) 811-815.
[82]A. Hasegawa, S. Miwa, S. Nogami, A. Taniguchi, T. Taguchi, K. Abe, Journal of Nuclear Materials 329–333 (2004) 582–586.
[83]K. Hojou, S. Furuno, K.N. Kushita, H. Otsu, K. Izui, Nucl. Instr. and Meth. Phys. Res. B 91 (1994) 534.
[84]T.Taguchi, N. Igawa, S. Miwa, E. Wakai, S. Jitsukawa, L.L. Snead, A. Hasegawa, Journal of Nuclear Materials 335 (2004) 508–514.
[85]T.S. Duh, K.M. Yin , J.Y. Yan , P.C. Fang , C.W. Chen ,J.J. Kai, F.R. Chen , Y. Katoh , A. Kohyama, J. of Nucl. Mater. 329-333 (2004) 518-523.
[86]耿緒祖，國立清華大學工程與系統科學研究所碩士論文,2005
[87]陳建文，國立清華大學工程與系統科學研究所碩士論文,2002
[88]葉陶然,熱核融合研究,核研季刊13期1995.4
[89] Andreas Fissel, Journal of Crystal Growth 212 (2000) 438}450
[90]李尚偉，國立清華大學工程與系統科學研究所碩士論文,2006
[91]陳科夆，國立清華大學工程與系統科學研究所博士論文,2008
[92] A. A. Lucas, Phys. Rev. B 28, 2485 (1983).
[93] H. Ryssel, “Ion Implantation”, 1986
[94]R.J. Price, Properties of silicon carbide for nuclear fuel particle coatings. Nucl. Tech. 35 (1977), pp. 320–336
[95] T. Taguchi, N. Igawa, S. Miwa, E. Wakai, S. Jitsukawa,L.L. Snead, A. Hasegawa, J. of Nucl. Mater. 367–370 (2007) 698–702
[96] T. Taguchi, N. Igawa, S. Miwa, E. Wakai, S. JitsukawaL.L. Snead, A. Hasegawa, J. of Nucl. Mater. 335 (2004) 508–514
[97] http://fusedweb.llnl.gov/
[98] 尹衍升，氧化鋯陶瓷及其複合材料，2004，化學工業出版社
[99] Yajima, Nature 273, 525 - 527 (15 June 1978