研究生: |
藍梓文 |
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論文名稱: |
市售中草藥重金屬含量之調查研究 Investigation of the heavy metal content of commercially available herbal |
指導教授: | 杜明進 |
口試委員: | |
學位類別: |
碩士 Master |
系所名稱: |
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論文出版年: | 2014 |
畢業學年度: | 102 |
語文別: | 中文 |
論文頁數: | 108 |
中文關鍵詞: | 中草藥 、重金屬 、微波消化 、感應耦合電漿原子發射光譜儀 |
外文關鍵詞: | herbal, heavy metal, microwave digestion, ICP-AES |
相關次數: | 點閱:3 下載:0 |
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摘要
針對市售何首烏、金銀花、酸棗仁、薄荷、雞血藤、五加皮、肉桂、桔梗、麻黃、五味子、杏仁、決明子、茴香、山楂、桑葉、葛根、天冬、獨活、龍膽、羅漢果、胖大海、佛手、車前子、白果、甘草、桂枝、枸杞、黃耆、陳皮及紫蘇等三十種中藥,經由微波消化前處理後,以感應耦合電漿原子發射光譜儀(ICP-AES),進行檢測消化液中Cu、Pb、Zn、Cd、Cr、Ni及Ag等重金屬含量。
經過微波消化前處理過後的樣品分析結果,本研究所採用的中藥,其Cu、Pb、Zn、Cd、Cr、Ni及Ag等重金屬元素,濃度範圍為:Zn:5.2ppm~70.6ppm,Cu:<0.01ppm~9.2ppm,Ni:<0.01ppm~6.6ppm,Pb:<0.01ppm~4.8ppm,Cr:<0.01ppm~4.9ppm, Cd、Ag:<0.01ppm,除了Zn此重金屬元素數值檢測出來較高(例:酸棗仁70.6 ppm),其餘重金屬元素含量皆低於10 ppm。
樣品中以茴香含Cu量最高;桂枝含Pb量最高;酸棗仁含Zn量最高;車前子含Cr量最高;龍膽含Ni量最高。
Abstract
According to the market selling Polygonum multiflorum, Lonicera japonica, Semen ziziphi spinosae, Mentha, Spatholobus suberectus Dunn, Acanthopanax gracilistylus, Cinnamomum cassia Presl, Platycodon grandiflorum, Ephedra sinica, Schisandra chinensis, Prunus armeniaca, Cassia obtusifolia, Foeniculum vulgare, Crataegus pinnatifida, Morus alba, Pueraria lobata, Asparagus cochinchinensis, Angelica pubescens, Gentiana scabra, Terminalia chebula, Sterculia scaphigera, Citrus medica, Plantago asiatica, Ginkgo biloba, Glycyrrhiza uralensis, Cinnamomum cassia Presl, Lycium barbarum, Astragalus membranaceus, Citri Reticulatae, Perilla frutescens, and other 30 kinds of Chinese medicine through the microwave digestion pretreatment Inductively coupled plasma atomic emission spectrometer (ICP-AES), were detected in the digestive juice of Cu and Pb, of Zn, of Cd and Cr, Ni and Ag.
After microwave digestion pre-treatment sample analysis results, the traditional Chinese medicine used in this study, Cu, Pb, Zn, Cd, Cr, Ni and Ag heavy metals, Concentration range: Zn: 5.2ppm ~ 70.6ppm, Cu: <0.01ppm ~ 9.2ppm, Ni: <0.01ppm ~ 6.6ppm, Pb: <0.01ppm ~ 4.8ppm, Cr: <0.01ppm ~ 4.9ppm, Cd, Ag: <0.01ppm, in addition to this heavy metal Zn element values detected higher (for example,: for Semen ziziphi spinosae 70.6 ppm), the heavy metals concentrations were below 10 ppm.
Samples with the highest Cu containing Foeniculum vulgare; Cinnamomum cassia Presl with the highest Pb; Semen ziziphi spinosae with the highest Zn; Plantago asiatica with the highest Cr; Gentiana scabra with the highest Ni.
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