由於目前對於塗佈行為的研究大都著重在單相溶液，而實際上工業界產品所使用的塗液大多為多相的懸浮液系統，因此本研究將以甘油水溶液作為主要塗液，藉由添加微粒至塗液中研究其效應，本實驗塗液系統是將不同粒徑的聚甲基丙烯酸甲酯 (PMMA) 粒子良好分散在甘油水溶液內，使其與甘油形成分散良好的懸浮液，而本實驗所使用模具分成兩大部份，第一部分利用狹縫式塗佈進行懸浮微粒塗液對其塗佈行為影響的研究，發現添加微粒有助於穩定其動態潤濕線，因而延後空氣滲入的現象，有效地提升最大塗佈速度並擴大塗佈視窗，且隨著粒子數量密度的上升，最大塗佈速度也隨之提高，而其中以小粒徑的微粒效果較佳。第二部份則進行添加微粒對淋幕式塗佈行為的影響，實驗發現添加微粒後，塗佈視窗有顯著地擴大，不僅有效提高最大塗佈速度，且有助降低最小成膜流量，增加淋幕穩定性。在相同粒徑下，其存在一最適化的粒子濃度，但仍以高粒子數量密度效果較佳，上述的研究動機均希望對於最大塗佈速度能有所提升，以利其工業化的最終目標。

[1].Ruschak, K.J. (1976). “Limiting Flow in a Pre-metered Coating Device”, Chemical Engineering Science, 31, 1057-1060.
[2].Beguin, A.E. (1954). “Method of Coating Strip Material”, US Patent 2,681,694.
[3].Russel, T.A., Wilson R.M. and Sanford C.R. (1956). “Multiple Coating Apparatus”, US Patent 2, 761,417.
[4].Russel, T.A. (1956). “Multiple Coating Apparatus”, US Patent 2,761,418.
[5].Landau and Levich (1942). “Dragging of a Liquid by a Moving Plate”, Acta Physicochim 17, 42-54.
[6].Deryagin, B.V. and Levi, S.M. (1964). “Film Coating Theory”, The Focal Press, London.
[7].Tallmadge, J.A., Weinberger, C.B. and Faust, H.L. (1979). “Bead Coating Instability：A Comparison of Speed Limit Data with Theory”, AIChE Journal 25, 1056-1072.
[8].Higgins, B.G. and Scriven, L.E. (1980). “Capillary Pressure and Viscous Pressure Drop Set Bounds on Coating Bead Operability”, Chemical Engineering Science 35, 673-682.
[9].Hens, J. and Boiy, L. (1986). “Operation of the Bead of a Pre-metered Coating Device”, Chemical Engineering Science 41, 1827-1832.
[10].Saito, T. and Ruch, R. (1980). “Stabilization of Colloid Dispersions by Polymer Adsorption”, Marcel Dekker, New York.
[11].Gutoff, E.B. and Kendrick, C.E. (1987). “Low Flow Limits of Coatability on a Slide Coater”, AIChE Journal 33, 141-145.
[12].Gilbert, N. and Eckel, A. (1992). “Analysis of Extrusion Coating in the Presence of External Forces”, AIChE Spring National Meeting, New Orleans.
[13].Lee, K.Y., Liu, L.D. and Liu, T.J. (1992). “Minimum Wet Thickness in Extrusion Slot Coating”, Chemical Engineering Science 47, 1703-1713.
[14].Sullivan, T.M. and Middleman, S. (1986). “Film Thickness in Blade Coating of Viscous and Viscoelastic Liquids”, Journal of Non-Newtonian Fluid Mechanics 21, 13-38.
[15].Cohen, E. D. and Gutoff E. B. (1992). “Modern Coating and Drying Technology”, VCH Publishers, New York.
[16].Cohen, E. D. and Gutoff E. B. (1995). “Coating and Drying Defects”, Wiley Interscience, New York.
[17].Kistler, S. F. and Schweizer P. M., eds. (1997). “Liquid Film Coating”, Chapman & Hall, London.
[18].Burley, R. and Kennedy, B.S. (1976). “An Experimental Study of Air Entrainment at a Solid/Liquid/Gas Interface”, Chemical Engineering Science 31, 901-911.
[19].Ning, C.Y., Tsai, C. C. and Liu, T. J. (1996). “The Effect of Polymer Additives on Extrusion Slot Coating”, Chemical Engineering Science 51, 3289-3297.
[20].M. Yamamura, H. Miura, and H. Kage. (2005). “Postponed Air Entrainment in Dilute Suspension Coatings”, AIChE Journal 51, 2171-2177.
[21].Chu, W.B., Yang, J.W., Wang, Y.C., Liu, T.J., Tiu, C. and Guo, J. (2006), “The Effect of Inorganic Particles on Slot Die Coating of Poly(Vinyl Alcohol) Solutions”, Journal of Colloid and Interface Science 297, 215-225.
[22].Chu, W.B., Yang, J.W., Liu, T.J., Tiu, C. and Guo, J. (2007), “The Effects of pH, Molecular Weight and Degree of Hydrolysis of Poly(Vinyl Alcohol) on Slot Die Coating of PVA Suspensions of TiO2 and SiO2”, Colloids and Surfaces A: Physicochemical and Engineering Aspects 302, 1-10
[23].Brown, D.R. (1961). “A Study of the Behavior of thin sheet of Moving Liquid ’’, Journal of Fluid Mechanics 10,297-303.
[24].Lin, S.P. (1981). “Stability of a Viscosity Liquid Curtain’’, Journal of Fluid Mechanics 104,111-118.
[25].Kistler, S. F. (1983). “The Fluid Mechanics of Curtain Coating and Related Viscous Free Surface Flow with Contact Lines’’, PhD Thesis, pp. 414–421, Univ. of Minnesota.
[26].Hughes, D.J. (1970). ” Method for Simultaneously Applying a Plurality of Coated Layers by Forming a Stable Multilayer Free-Falling Vertical Curtain”, US Patent 3,508,947.
[27].Reiter T.C. (1989). ’’Curtain Coating Method and Apparatus”, US Patent 4,830,887.
[28].Kistler, S. F. and Scriven L. E. (1984). “Coating Flow Theory by Finite Element and Asymptotic Analysis of the Navier-Stokes System”, International Journal for Numerical Methods in Fluids 4, 207-229.
[29].Blake, T. D., Clarke A. and Ruschak K. J. (1994). “Hydrodynamic Assist of Dynamic Wetting”, AIChE Journal 40, 229-242.
[30].Blake, T. D., Dobson R. A. and Ruschak K. J. (2004). “Wetting at high capillary numbers”, Journal of Colloid and Interface Science 279, 198-205.
[31].M. Yamamura, A. Matsunaga, Y. Mawatari, K. Adachi, H. Kage. (2006). “Particle-assisted dynamic wetting in a suspension liquid jet impinged onto a moving solid at different flow rates” Chemical Engineering Science 61, 5421-5426.
[32].Buonopane, R.A., Gutoff, E.B. and Rimore, M.M.T. (1986). “Effect of. Plunging Tape Surface Properties on Air-Entrainment Velocity”, AIChE Journal 32, 682-683.
[33].Blake, T. D., and Ruschak K. J. (1997). “Wetting: Static and Dynamic Contact Lines”, Liquid Film Coating, S. F. Kistler and P. M. Schweizer, Editors, Chapmans Hall, London.
[34].Clarke, A. (2002). “Coating on a Rough Surface”, AIChE Journal 48, 2149-2156.
[35].Benkreira, H. (2004). “The effect of substrate roughness on air entrainment in dip coating”, Chemical Engineering Science 59, 2745.
[36].Macosko, C.W. (1994). “Rheology：Principles Measurements and Applications”, Wiley-VCH Publishers, New York.
[37].Liang, G.G. and Hawkett, B.S. (2005). “The Determination of the Isoelectric Point from Measurements of Dispersion Viscosity as a Function of pH”, Journal of Dispersion Science and Technology 26, 469-472.
[38].Chibowski. (2001). “Studies of the Influence of Acetate Groups from Polyvinyl Alcohol on Adsorption and Electrochemical Properties of the TiO2-Polymer Solution Interface”, Journal of Dispersion Science and Technology 22, 281-289.
[39].Boisvert, J. P., Persello J. and Guyard A. (2003). “Influence of the Surface Chemistry on the Structural and Mechanical Properties of Silica-Polymer Composites”, Journal of Polymer Science 41, 3127-3138.
[40].Eistein, A. (1906). ’’A New Determination of the Molecular dimension’’, Ann. Physik., 19, 289-306.
[41].Mooney, M. (1951). ’’The Viscosity of a Concentrated Suspension of Spherical Particles ’’, Journal of Colloid and Interface Science 6,162-170.
[42].曾靜淵, (2007)., 添加微粒對淋幕式塗佈行為的影響, 國立清華大學化學工程研究所碩士論文.
[43].Krieger, I. M. (1972), “Rheology of Monodisperse Latices’’, Advances in Colloid and Interface Science 3, 111-136.
[44].Van der Aerschot, E. and Mewis, J. (1992), “Equilibrium Properties of Reversibly. Flocculated Dispersions’’, Colloids and Surfaces 69,15-22.