研究生: |
易漢威 Han-Wei Yi |
---|---|
論文名稱: |
大氣懸浮微粒中水溶性陰陽離子之採樣分析研究 |
指導教授: | 洪益夫 |
口試委員: | |
學位類別: |
碩士 Master |
系所名稱: |
原子科學院 - 生醫工程與環境科學系 Department of Biomedical Engineering and Environmental Sciences |
論文出版年: | 2004 |
畢業學年度: | 92 |
語文別: | 中文 |
論文頁數: | 91 |
中文關鍵詞: | 懸浮微粒 、陰、陽離子 、離子層析 、因素分析 |
相關次數: | 點閱:2 下載:0 |
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懸浮微粒是指大氣環境中除了水分子以外之固態或液態微粒,一般定義為粒徑100μm以下之粒狀物。依來源可分為原生性以及衍生性兩種。原生性氣膠的主要來源是物理破碎以及污染源的一次排放所產生,衍生性氣膠則是原生性氣膠經過大氣化學所產生的產物,常見的種類有硝酸鹽、硫酸鹽類等。
本研究與新竹市及桃園縣環保局合作,利用高量採樣法在新竹市三個、桃園縣七個人工測站,自九十二年七月起至九十三年二月止進行總懸浮微粒的採樣。並以離子層析法進行其中水溶性陰陽離子的分析,共計分析Na+、NH4+、K+、Mg2+、Ca2+、F-、Cl-、Br-、NO3-、PO43-、SO42-等十一種陰陽離子,並以因素分析進行來源探討。
分析結果發現,TSP中之陰陽離子的分佈以硫酸根、硝酸根、鈉離子為主要成分,平均濃度以桃園縣較高。而冬季的TSP及陰陽離子濃度較夏、秋二季為高,與文獻中之研究相比較,有類似的結果。而由因素分析的結果判斷陰陽離子的來源,推測新竹及桃園地區的TSP中陰陽離子的主要來源為交通污染以及固定污染源的排放,海洋飛沫及陸地揚塵之鹽分以及特殊污染源之排放亦為來源之一,亦與文獻之研究結果相似。
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