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研究生: 陳畇綸
Chen, Yun-Lun
論文名稱: 具金屬奈米粒子之石墨烯/矽之異質太陽電池應用於電解水之應用
Silicon/Graphene Heterojunction Solar Cell with Metal Nanoparticles for Water Splitting
指導教授: 徐永珍
Hsu, Klaus Yung-Jane
口試委員: 江雨龍
賴宇紳
學位類別: 碩士
Master
系所名稱: 電機資訊學院 - 電子工程研究所
Institute of Electronics Engineering
論文出版年: 2019
畢業學年度: 107
語文別: 中文
論文頁數: 80
中文關鍵詞: 異質太陽電池電解水金屬奈米粒子石墨烯
外文關鍵詞: Heterojunction Solar Cell, Water Splitting, Metal Nanoparticles, Graphene
相關次數: 點閱:2下載:0
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  • 隨著科技日新月異,能源的收集方式逐漸多樣化。在太陽能這一部分也毫不例外,而太陽能電池的結構更是五花八門。
    本篇論文旨在利用二維材料石墨烯與氧化鋅和矽基板結合,並利用串聯和金屬奈米粒子的加成方式來提高太陽電池的開路電壓,進而將整體結構運用於水的電解上。
    為了達成電解水產氫燃料的目標,我們利用了串聯的方式提升了元件結構整體的開路電壓,試著將原本開路電壓只有0.3V左右的單一元件增加到滿足電解水反應產生所需之電壓閥值(約1.23V)。同時利用尖端放電的原理,在元件表面覆上Pt奈米粒子,來增加元件表面的粗糙度來達到電場增強的效果,以力求串聯結構可在開路電壓小於1.23V的情況下,使電解水反應產生。


    As the rapid development of technology, the ways of conserving enegy are diversified. Particularly, when it comes to solar cells, there are various kinds of structures.
    In this thesis, we demonstrated two types of solar cells mainly made of graphene and other materials such as silicon and zinc oxide.
    Furthermore, in order to apply the cells into water splitting, we added some platinum nanoparticles on the cells and connected devices in series to improve their open-circuit voltage.

    摘要 I Abstract II 致謝 III 目錄 V 圖目錄 VIII 表目錄 XI 第一章 前言 1 1.1 石墨烯的發現、特性與應用 1 1.2研究背景 2 1.3研究動機 3 1.4論文章節架構 4 第二章 材料介紹 5 2.1石墨烯的結構及特性 5 2.2拉曼光譜分析 8 2.2.1拉曼光譜簡述 8 2.2.2拉曼散射由來與基本原理 9 2.2.3石墨烯之拉曼光譜 10 2.2.4石墨烯拉曼光譜之研判 11 2.3氧化鋅的結構及特性 13 2.4氧化鋅薄膜之沉積方法 15 2.5氧化鋅的製程參數 16 2.6氧化鋅薄膜的檢測原理與分析 17 第三章 太陽能電池原理 20 3.1太陽能電池簡介 20 3.2空氣質量(Air Mass) 20 3.3 pn接面二極體原理 21 3.4理想太陽能電池等效電路 22 3.5非理想太陽能電池等效電路 23 3.6太陽能電池基本參數介紹 24 (1)短路電流(Short - Circuit Current, Isc) 25 (2)開路電壓(Open - Circuit Voltage, Voc) 25 (3)填充因子(Fill Factor, FF) 25 (4)能量轉換效率(Power Conversion Efficiency, PCE) 26 (5)外部量子效率(External Quantum Efficiency, EQE) 26 3.7蕭特基接面與歐姆接面(以n型半導體為例) 26 3.8光電化學水分解原理 30 3.9電場增強 32 第四章 元件製程 34 4.1石墨烯之生長:高溫金屬催化成長石墨烯 34 4.1.1石墨烯成長機制與參數控制 35 4.1.2銅箔的預處理(Pretreatment) 36 4.1.3常壓化學氣相沉積(APCVD)石墨烯 37 4.2石墨烯的轉移(Transfer) 41 4.2.1石墨烯的支撐層與旋塗 42 4.2.2熱解膠輔助轉移 44 4.2.3銅箔之蝕刻 46 4.2.4石墨烯的漂洗、轉移與烘烤 47 4.2.5轉移完成的石墨烯拉曼光譜圖 49 4.3以石墨烯為基礎之元件架構與製程 50 4.3.1元件設計架構 50 4.3.2元件製程 52 第五章 量測與應用 55 5.1量測儀器簡介 55 5.2量測方式 56 5.2.1歐姆檢驗 56 5.2.2 Type1之開路電壓量測 57 5.2.3 Type1各階段接面之開路電壓量測 60 5.2.4 Type2開路電壓量測 62 5.2.5 Type1, Type2開路電壓比較統整表 63 5.2.6 Type2電流-電壓曲線圖(I-V curve) 64 5.3 應用 66 第六章 結論與未來展望 77 參考文獻 78

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