超級電容(Supercapacitor)由於具有優異的循環壽命、尖峰放電及高功率放電能力，其應用近年來日益受到重視。在各種製備超級電容的電極材料之中，奈米碳管屬於電雙層電容材料之ㄧ，其特性為具有高比表面積；而氧化釕則為偽電容材料之ㄧ，以氧化還原反應來儲存電荷，因此具有較電雙層電容高的電容量，但受限於表面積因此無法發揮最大的電容效益。本實驗的目的即結合兩者來製備複合電極，將兩種電極材料之特性加以結合，希望使電極之電容值有效地向上提高，發揮最大的經濟效益。

本實驗以微波加熱化學氣相沉積法成長奈米碳管作為底材，再以循環伏安法沉積含水氧化釕在奈米碳管上製備複合電極，複合電極最佳電容量表現為掃描速率100 mV/s下的78.5 mF/cm^2。而以純鈦板在相同製備條件所得之含水氧化釕電極，其電容量最佳表現為掃描速率100 mV/s下的63.9 mF/cm^2。可知複合電極比含水氧化釕電極具有更高的電容量，因此可知結合兩種電極材料之特性，確實使得電極之電容值有所提升，提高電極材料之經濟效益。

1.3 參考文獻
1.蘇品書, 超微粒子材料技術, 復漢出版社, 台南, (2001).
2.B.E. Conway, Electrochemical Supercapacitors-Scientific Fundamentals and Technological Applications, Kluwer Academic/Plenum, New York, (1999).
3.H.E. Becker, US Patent, 2(800), 616 (1957).
4.D.I. Boos, US Patent, 3(536), 963 (1970).
5.R. Kotz and M. Carlen, Electrochimica Acta, 45(15-16), 2483 (2000).
6.B.E. Conway, Journal of the Electrochemical Society, 138(6), 1539 (1991).
7.J.P. Zheng, J. Huang, and T.R. Jow, Journal of the Electrochemical Society, 144(6), 2026 (1997).
8.B. Pillay and J. Newman, Journal of the Electrochemical Society, 143(6), 1806 (1996).
9.S. Sarangapani, B.V. Tilak, and C.P. Chen, Journal of the Electrochemical Society, 143(11), 3791 (1996).
10.I. Tanahashi, A. Yoshida, and A. Nishino, Bulletin of the Chemical Society of Japan, 63(10), 2755 (1990).
11.A. Yoshida, S. Nonaka, I. Aoki, and A. Nishino, Journal of Power Sources, 60(2), 213 (1996).
12.J.M. Pernaut and G. Goulart, Journal of Power Sources, 55(1), 93 (1995).
13.Y. Kibi, T. Saito, M. Kurata, J. Tabuchi, and A. Ochi, Journal of Power Sources, 60(2), 219 (1996).
14.H. Shi, Electrochimica Acta, 41(10), 1633 (1996).
15.M. Ishikawa, A. Sakamoto, M. Morita, Y. Matsuda, and K. Ishida, Journal of Power Sources, 60(2), 233 (1996).
16.X.J. Liu, T. Momma, and T. Osaka, Denki Kagaku, 64(2), 143 (1996).
17.C.M. Niu, E.K. Sichel, R. Hoch, D. Moy, and H. Tennent, Applied Physics Letters, 70(11), 1480 (1997).
18.R.Z. Ma, J. Liang, B.Q. Wei, B. Zhang, C.L. Xu, and D.H. Wu, Journal of Power Sources, 84(1), 126 (1999).
19.S. Iijima, Nature, 354(6348), 56 (1991).
20.陳彥旭, 清華大學碩士論文, (2002).
21.R.H. Baughman, A.A. Zakhidov, and W.A. de Heer, Science, 297(5582), 787 (2002).
22.S. Iijima and T. Ichihashi, Nature, 363(6430), 603 (1993).
23.C. Journet, W.K. Maser, P. Bernier, A. Loiseau, M.L. delaChapelle, S. Lefrant, P. Deniard, R. Lee, and J.E. Fischer, Nature, 388(6644), 756 (1997).
24.T.W. Ebbesen and P.M. Ajayan, Nature, 358(6383), 220 (1992).
25.A. Thess, R. Lee, P. Nikolaev, H.J. Dai, P. Petit, J. Robert, C.H. Xu, Y.H. Lee, S.G. Kim, A.G. Rinzler, D.T. Colbert, G.E. Scuseria, D. Tomanek, J.E. Fischer, and R.E. Smalley, Science, 273(5274), 483 (1996).
26.Z.F. Ren, Z.P. Huang, J.W. Xu, J.H. Wang, P. Bush, M.P. Siegal, and P.N. Provencio, Science, 282(5391), 1105 (1998).
27.S.S. Fan, M.G. Chapline, N.R. Franklin, T.W. Tombler, A.M. Cassell, and H.J. Dai, Science, 283(5401), 512 (1999).
28.J. Kong, H.T. Soh, A.M. Cassell, C.F. Quate, and H.J. Dai, Nature, 395(6705), 878 (1998).
29.N.R. Franklin, Y.M. Li, R.J. Chen, A. Javey, and H.J. Dai, Applied Physics Letters, 79(27), 4571 (2001).
30.B.Q. Wei, R. Vajtai, Y. Jung, J. Ward, R. Zhang, G. Ramanath, and P.M. Ajayan, Nature, 416(6880), 495 (2002).
31.G. Gu, G. Philipp, X.C. Wu, M. Burghard, A.M. Bittner, and S. Roth, Advanced Functional Materials, 11(4), 295 (2001).

2.5 參考文獻
1.B.E. Conway, Journal of the Electrochemical Society, 138(6), 1539 (1991).
2.S. Sarangapani, B.V. Tilak, and C.P. Chen, Journal of the Electrochemical Society, 143(11), 3791 (1996).
3.M. Ishikawa, M. Morita, M. Ihara, and Y. Matsuda, Journal of the Electrochemical Society, 141(7), 1730 (1994).
4.S.T. Mayer, R.W. Pekala, and J.L. Kaschmitter, Journal of the Electrochemical Society, 140(2), 446 (1993).
5.G.L. Bullard, H.B. Sierraalcazar, H.L. Lee, and J.L. Morris, Ieee Transactions on Magnetics, 25(1), 102 (1989).
6.R. Kotz and M. Carlen, Electrochimica Acta, 45(15-16), 2483 (2000).
7.D.R. Crow, Principles and Application of Electrochemistry, 2nd ed, Chapman and Hall Ltd, London, (1979).
8.J.P. Zheng, J. Huang, and T.R. Jow, Journal of the Electrochemical Society, 144(6), 2026 (1997).
9.Y.M. Shyu and F.C.N. Hong, Diamond and Related Materials, 10(3-7), 1241 (2001).
10.王世育, 台灣大學博士學位論文, (2004).
11.B.E. Conway, Electrochemical Supercapacitors-Scientific Fundamentals and Technological Applications, Kluwer Academic/Plenum, New York, (1999).
12.B.E. Conway, V. Birss, and J. Wojtowicz, Journal of Power Sources, 66(1-2), 1 (1997).
13.J.P. Zheng and T.R. Jow, Journal of the Electrochemical Society, 142(1), L6 (1995).
14.J.P. Zheng, P.J. Cygan, and T.R. Jow, Journal of the Electrochemical Society, 142(8), 2699 (1995).
15.Y. Takasu, T. Nakamura, H. Ohkawauchi, and Y. Murakami, Journal of the Electrochemical Society, 144(8), 2601 (1997).
16.T.C. Wen and C.C. Hu, Journal of the Electrochemical Society, 139(8), 2158 (1992).
17.A.M. Couper, D. Pletcher, and F.C. Walsh, Chemical Reviews, 90(5), 837 (1990).
18.C. Arbizzani, M. Mastragostino, and L. Meneghello, Electrochimica Acta, 41(1), 21 (1996).
19.H. Wendt, Electrochimica Acta, 29(11), 1513 (1984).
20.S. Trasatti, Electrochimica Acta, 36(2), 225 (1991).
21.K. Engelsmann, W.J. Lorenz, and E. Schmidt, Journal of Electroanalytical Chemistry, 114(1), 1 (1980).
22.M. Vukovic and D. Cukman, Journal of Electroanalytical Chemistry, 474(2), 167 (1999).
23.S. Ardizzone, G. Fregonara, and S. Trasatti, Electrochimica Acta, 35(1), 263 (1990).
24.J.E. Weston and B.C.H. Steele, Journal of Applied Electrochemistry, 10(1), 49 (1980).
25.T.R. Jow and J.P. Zheng, Journal of the Electrochemical Society, 145(1), 49 (1998).
26.蔡文達 and 張仍奎, 材料會訊, 第八卷第三期 (2001).
27.M. Ue, K. Ida, and S. Mori, Journal of the Electrochemical Society, 141(11), 2989 (1994).
28.A.J. Bard and L.R. Faulkner, Electrochemical Methods, Fundamentals and Application, John Wiley & Sons, Singapore, (1980).
29.D. Plectcher, A First Course in Electrode Processes, The Electrochemical Consultancy, England, (1991).
30.D.R. Crow, Principles and Application of Electrochemistry, 4th ed, Chapman and Hall Ltd, UK, (1994).
31.D. Plectcher and F.C. Walsh, Industrial Electrochemistry, Chapman and Hall Ltd, New York, (1990).
32.田福助, 電化學-理論與應用, 高立圖書出版公司, 臺北市, (1996).
33.D.A. Skoog, F.J. Holler, and T.A. Nieman, Principles of instrumental analysis, 5th ed, Harcourt Brace College Publishers, (1998).
34.H. Hiura, T.W. Ebbesen, K. Tanigaki, and H. Takahashi, Chemical Physics Letters, 202(6), 509 (1993).
35.P.C. Eklund, J.M. Holden, and R.A. Jishi, Carbon, 33(7), 959 (1995).
36.陳瑋駿, 中正大學碩士學位論文, (2002).
37.李明宗, 逢甲大學碩士學位論文, (2002).

4.4 參考文獻
1.S. Hadzi-Jordanov, H. Angerstein-Kozlowska, M.Vukovic, and B.E. Conway, Journal of The Electrochemical Society, 125(9), 1471 (1978).
2.B.E. Conway, Electrochemical Supercapacitors-Scientific Fundamentals and Technological Applications, Kluwer Academic/Plenum, New York, (1999).
3.C.C. Hu and Y.H. Huang, Journal of the Electrochemical Society, 146(7), 2465 (1999).
4.J.P. Zheng and T.R. Jow, Journal of the Electrochemical Society, 142(1), L6 (1995).
5.C.C. Hu, Y.H. Huang, and K.H. Chang, Journal of Power Sources, 108(1-2), 117 (2002).
6.S. Bhaskar, P.S. Dobal, S.B. Majumder, and R.S. Katiyar, Journal of Applied Physics, 89(5), 2987 (2001).
7.S.Y. Mar, C.S. Chen, Y.S. Huang, and K.K. Tiong, Applied Surface Science, 90(4), 497 (1995).