本論文以建立揮發性有機氣體自動化分析系統為目的，將氣體檢測方法所需的人力、時間控制到最精簡的程度：不□鋼採樣罐清洗系統可同時進行10組採樣罐清洗、自動化氣體樣品採集器可進行12組定點逐時樣品採集工作；16組不□鋼罐自動進樣系統、樣品前濃縮裝置、進樣、化合物的分離偵檢乃至於最後的自動定性、定量工作，達成完整的自動化分析功能。整套分析系統以美國環保署公告的TO-14A與TO-15為架構，確認數據產生的過程能夠達到品保及品管的要求，針對56種臭氧前驅物方法偵測極限低於0.5ppbv；精確度□10%；準確度□13%。
為求掌握環境空氣品質狀況的時效性，將分析系統拓展到揮發性有機化合物自動化現場即時監測系統的建立。利用吸附劑進行常溫下(300C)樣品前濃縮，程式升溫以400C作為起始溫度，避免現場即時分析系統需補充冷凝劑的不便；樣品進樣及樣品前濃縮(20min)、分離、偵檢、自動定性定量完整分析流程時間共1小時，提高分析數據在時間上的解析度。環境實測部份以新竹科學園區為對象，針對園區常見的12種氣態污染物質進行連續五天的空氣監測，五天內系統穩定性為正負5%以內。

The purpose of this thesis is to establish an automatic volatile organic compounds analysis system, which saves man power and reduces analysis time. The analysis system includes 10-canister cleaning system, 12-canister auto-sampler, 16-canister auto-injection system and sample preconcentration trap. Qualitative and quantitative data acquisition can be conducted by automation. The analytic method is based on US EPA TO-14A and TO-15. In addition, QA/QC is accomplished with TO guidiance. Our results show that MDL□0.5ppbv, precision□10% and accuracy□13% for 56 ozone precursor.
Besides, this work also extended the system to real time in-situ VOCs monitoring. An adsorbent was used as a sample preconcentration trap at 300C with initial oven temperature of 400C to limit usage of liquid nitrogen. Each hourly run includes procedures such as sample injection(20min), preconcentration, separation, detection, automatic qualititive and quantitative data aquisition. During 5 days measurment, the systematic stablity was within 5%.

【1】 Koren, H.S., Devlin, R.B., Graham, D.E., Mann, R. and McDonnell, W.F.,(1989)” The inflammatory response in human lung exposed to ambient levels f ozone. In: Atmospheric Ozone Research and Its Policy Implications”, T. Schneider, S.D. Lee, G.J.R. Wolters and L.D. Grant (Eds) Elsevier Science Publishers, Amsterdam.
【2】 Cody, R.P., Weisel, C.P., Birnbaum, G. and Lioy P.J. (1992) “The effect of ozone associated with summertime photochemical smog on the frequency of asthma visits to hospital emergency departments”, Environ. Res., 58, 184-194.
【3】 Middleton, J.T., Kendrick, J.B., Jr, and Schwalm, H.W. (1950) Injury to herbaceous plants by smog or air pollution, Plant Disease Reptr., 34, 245-252.
【4】 Carter, W.P.L., and. Fredrick W.L,(1991) “Evaluation of detailed gas-phase atmospheric reaction mechanism using environmental chamber data”, Atmospheric Environment, 25(12), 2771-2806.
【5】 Carter, W.P.L., (1994) “Development of Ozone Reactivity Scales for Volatile Organic Compounds”, J. Air Waste Manage. Assoc., 44, 881-889.
【6】 U.S. EPA, (1999) “The Determination of Volatile Organic Compounds (VOCs) In Ambient Air Using Specially Prepared Canisters With Subsequent Analysis By Gas Chromatography” Compendium Method TO-14A.
【7】 U.S. EPA, (1997) “The Determination of Volatile Organic Compounds (VOCs) In Air Collected In Specially Prepared Canisters And Analyzed By Gas Chromatography/Mass Spectrometry(GC/MS)” Compendium Method TO-15.
【8】 U.S. EPA, (1997) “The Determination of Volatile Organic Compounds (VOCs) In Air Using Active Sampling onto Sorbent Tubes” Compendium Method TO-17.
【9】 Zimmerman, P.R., (1979)“Testing of Hydrocarbon Emissions from Vegetation, Leaf Litter, and Aquatic Surfaces, and Development of A Methodology for Compiling Biogenic Emission Inventories”, EPA-450/4-70-004, U.S. EPA, Washington, D.C.
【10】McClenny, W.A., Pleil,J.D., Evans, G.F., Oliver, K.D., Holdren, M.W.,and Winberry, W.T.,(1991)“Canister-Based Method for Monitoring Toxic VOCs in Ambient Air”, J. Air Waste Manage, 41, 1308-1318.
【11】Gholson, A.R., Jayanty, R.K.M., Storm, J.F.,(1990) “Evaluation of Aluminum Canisters for Collection and Storage of Air Toxics ” , Anal. Chem, 62, 1899-1902.
【12】Brymer, D.A., Ogle, L.D., Jonse, C.J., and Lewis, D.L.,(1996) “Viability of Using SUMMA Polished Canister for The Collection and Storage of Parts per Billion by Volume Level Volatile Organics”, Environ. Sci. Technol. 30, 188-195.
【13】行政院環保署環境檢驗所,(2000) ”不□鋼採樣筒/氣相層析質譜儀法”.
【14】http://www.epa.gov.tw
【15】Nelson, P.F., and Qulgley, S.M.,(1982)” Non-Methane Hydrocarbon in the Atmosphere of Sydney, Australis”, Environ. Sci, Technol., 16, 650-655.
【16】Carter, W.P.L.(1994) “Develop of ozone reactivity scales for volatile Organic Compounds” J.Air Waste Manag. Assoc.,44, 881.
【17】Wang, J-L.;Ding, W-H.; Chen, T-Y.(2000)”Source determination of light non-methane hydrocarbons by simultaneous multi-site sampling in a metropolitan area” Chemosphere 2, 11.
【18】McClenny, W. A., Oliver, K.D. and Daughtrey, E.H., (1995) Jr. ”Analysis of VOCs in Ambient Air Using Multisorbent Packings for VOC Accumulation and Sample Drying,” J. Air and Waste Management Assoc., 792-800.
【19】張志忠,(1997)” 鹵碳化物分析系統之建立與實際大氣量測”, 國立中央大學化學研究所碩士論文.
【20】馬志宏,(1998)” The Analysis of Volatile Organic Compounds in Ambient Air and It’s Application”, 國立清華大學原子科學系碩士論文.
【21】葉銘鵬,(1994)” Canister-Based Method for Monitoring VOCs in ambient Air”, 國立清華大學原子科學碩士論文.