研究生: |
林志銘 Lin, Chih-Ming |
---|---|
論文名稱: |
以刮刀溶液製程製備多層結構有機太陽電池 Fabrication of multi-layer organic solar cell by blade coating solution process |
指導教授: |
洪勝富
Horng, Sheng-Fu |
口試委員: |
孟心飛
Meng, Hsin-Fei 張志宇 Chang, Chih-Yu |
學位類別: |
碩士 Master |
系所名稱: |
電機資訊學院 - 電子工程研究所 Institute of Electronics Engineering |
論文出版年: | 2019 |
畢業學年度: | 107 |
語文別: | 中文 |
論文頁數: | 67 |
中文關鍵詞: | 有機太陽電池 、陰極介面修飾層 、大面積 、非富樂烯 、多層 、溶液製程 、三元 |
外文關鍵詞: | Organic solar cell, Cathode buffer layer, large area, Non fullerene, Multi-layer, solution process, Ternary |
相關次數: | 點閱:3 下載:0 |
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近期的文獻指出,以三元系統為主動層的太陽電池是有效提升太陽電池效率的重要方向之一,本實驗即以三元系統製備太陽電池,並且利用刮刀塗佈技術在大面積的元件上突破目前學界的紀錄,效率達7.7%,並且成功發表於國際期刊。
本實驗是以主動層材料PBDB-T:ITIC:PC71BM三元混摻,並且以氯苯(Chlorobenzene)作為溶劑,加上DIO界面活性劑,搭配正結構,以ITO為陽極,蒸鍍製程的鋁為陰極,並且以ZrOx取代傳統LiF陰極介面修飾層,相較於LiF成功將元件電性以及穩定性都提升,其大面積元件在室溫下壽命超過140天效率仍然維持原來效率80%以上,穩定性有明顯的提升。
接著將大面積不透明的成果應用於半透明大面積太陽電池,但在半透明元件的製程上發現介面層的表面型態將會嚴重影響元件電性,因此轉而利用小面積做為實驗製程上的測試。首先利用PC71BM想要將三元較為不平整的表面粗糙度填平,但發現效果並不好。接著使用一種新穎的方法,先將二元以PBDB-T:ITIC的系統置為主動層,上面上一層PC71BM,想要利用碳球對於溫度的敏感度容易擴散的效應,讓我的主動層可以變為三元系統,並且順勢降低表面粗糙度,此方法在LiF為介面層也得到不錯的結果,在製程穩定性上,以及壽命上都優於三元單層結構。雖然接著應用於本實驗室使用穩定陰極介面修飾層材料ZrOx無法得到很好的結果,但相信只要挑對介面層材料,這樣的結構應該是具有實體的可行性。接著嘗試在小面積上直接調控介面層的表面型態,透過溶液濃度的提高,可以發現濃度提高對於覆蓋率有明顯的改善,因此未來可以將濃度提高應用於大面積,因為膜面的平整度對於大面積的效率提升是最為重要的,將此結果運用於大面積應可得到不錯的結果。
Recent literature pointed out that solar cells with ternary system as the active layer are one of the important directions to effectively improve the efficiency of solar cells. This experiment is to prepare solar cells with ternary system and use blade coating technology on large-area components. Breaking through the current academic record, the efficiency is 7.7%, and it was successfully published in international journals. This experiment is based on the active layer material PBDB-T:ITIC:PC71BM ternary blending, and using Chlorobenzene as solvent, plus DIO surfactant, with positive structure, ITO as anode, evaporation process aluminum As the cathode, and replacing the traditional LiF cathode buffer layer with ZrOx, the electrical and stability of the component are improved compared with LiF. The PCE of the large-area device maintained 80% of original device at room temperature after140 days. There is a significant increase in stability.Then the opaque large-area results were applied to transparent large-area solar cells, but the surface morphology of the interface layer is found to seriously affect the electrical properties of transparent solar cell, so a small area device is used as an experimental process. First, the PC71BM was used to fill the surface roughness of the ternary, but the effect was not good. Then, I used a new method, the binary PBDB-T:ITIC system is first set as the active layer, and the upper layer PC71BM is used. I want to use the effect of the carbon sphere's sensitivity to temperature diffusion, so that my active layer can become a ternary system, and the surface roughness is also reduced by the method. This method also has good results in the cathode buffer layer LiF. Moreover, the process stability and life are better than ternary solar cell in room temperature. Although it did not obtain good results in the cathode interface modification layer material ZrOx, it is believed that such a structure should be physically feasible as long as the cathode buffer layer material is selected. Then try to directly control the surface morphology of the cathode buffer layer on a small area. Through the increase of the solution concentration, it can be found that the concentration increase has a significant improvement on the coverage rate. Therefore, the concentration increase can be applied to a large area in the future because of the flatness of the film surface is the most important thing to large area device.
[1] "<Light-sensitive electric device including silicon.pdf>."
[2] M. A. Green, "The path to 25% silicon solar cell efficiency: History of silicon cell evolution," Progress in Photovoltaics: Research and Applications, vol. 17, no. 3, pp. 183-189, 2009.
[3] M. A. Green, "Thin-film solar cells: review of materials, technologies and commercial status," Journal of Materials Science: Materials in Electronics, vol. 18, no. S1, pp. 15-19, 2007.
[4] T. D. Lee and A. U. Ebong, "A review of thin film solar cell technologies and challenges," Renewable and Sustainable Energy Reviews, vol. 70, pp. 1286-1297, 2017.
[5] S. Kim, J.-W. Chung, H. Lee, J. Park, Y. Heo, and H.-M. Lee, "Remarkable progress in thin-film silicon solar cells using high-efficiency triple-junction technology," Solar Energy Materials and Solar Cells, vol. 119, pp. 26-35, 2013.
[6] Y. Cui et al., "Achieving Over 15% Efficiency in Organic Photovoltaic Cells via Copolymer Design," Adv Mater, vol. 31, no. 14, p. e1808356, Apr 2019.
[7] "<c39770000578.pdf>."
[8] "<cm049654n.pdf>."
[9] H. Hoppe and N. S. Sariciftci, "Organic solar cells: An overview," Journal of Materials Research, vol. 19, no. 7, pp. 1924-1945, 2011.
[10] W. Zhao, S. Zhang, and J. Hou, "Realizing 11.3% efficiency in fullerene-free polymer solar cells by device optimization," Science China Chemistry, vol. 59, no. 12, pp. 1574-1582, 2016.
[11] W. Zhao, S. Li, S. Zhang, X. Liu, and J. Hou, "Ternary Polymer Solar Cells based on Two Acceptors and One Donor for Achieving 12.2% Efficiency," Adv Mater, vol. 29, no. 2, Jan 2017.
[12] S.-R. Tseng, H.-F. Meng, K.-C. Lee, and S.-F. Horng, "Multilayer polymer light-emitting diodes by blade coating method," Applied Physics Letters, vol. 93, no. 15, 2008.
[13] N. Agrawal, M. Zubair Ansari, A. Majumdar, R. Gahlot, and N. Khare, "Efficient up-scaling of organic solar cells," Solar Energy Materials and Solar Cells, vol. 157, pp. 960-965, 2016.
[14] K. Zhang et al., "Efficient Large Area Organic Solar Cells Processed by Blade-Coating With Single-Component Green Solvent," Solar RRL, vol. 2, no. 1, 2018.
[15] L. Lucera et al., "Highly efficient, large area, roll coated flexible and rigid OPV modules with geometric fill factors up to 98.5% processed with commercially available materials," Energy & Environmental Science, vol. 9, no. 1, pp. 89-94, 2016.
[16] L. Mao et al., "Flexible silver grid/PEDOT:PSS hybrid electrodes for large area inverted polymer solar cells," Nano Energy, vol. 10, pp. 259-267, 2014.
[17] J. E. Lewis, E. Lafalce, P. Toglia, and X. Jiang, "Over 30% transparency large area inverted organic solar array by spray," Solar Energy Materials and Solar Cells, vol. 95, no. 10, pp. 2816-2822, 2011.
[18] L. Lucera et al., "Printed semi-transparent large area organic photovoltaic modules with power conversion efficiencies of close to 5 %," Organic Electronics, vol. 45, pp. 209-214, 2017.
[19] P.-T. Tsai, K.-C. Yu, C.-J. Chang, S.-F. Horng, and H.-F. Meng, "Large-area organic solar cells by accelerated blade coating," Organic Electronics, vol. 22, pp. 166-172, 2015.
[20] K.-M. Huang et al., "Highly efficient and stable organic solar cell modules processed by blade coating with 5.6% module efficiency and active area of 216 cm2," Progress in Photovoltaics: Research and Applications, vol. 27, no. 3, pp. 264-274, 2019.
[21] S. Hong et al., "A series connection architecture for large-area organic photovoltaic modules with a 7.5% module efficiency," Nat Commun, vol. 7, p. 10279, Jan 5 2016.
[22] S.-L. Lim et al., "Efficient, large area organic photovoltaic modules with active layers processed with non-halogenated solvents in air," Organic Electronics, vol. 43, pp. 55-63, 2017.
[23] S. Berny et al., "Solar Trees: First Large-Scale Demonstration of Fully Solution Coated, Semitransparent, Flexible Organic Photovoltaic Modules," Adv Sci (Weinh), vol. 3, no. 5, p. 1500342, May 2016.
[24] S. Strohm et al., "P3HT: non-fullerene acceptor based large area, semi-transparent PV modules with power conversion efficiencies of 5%, processed by industrially scalable methods," Energy & Environmental Science, vol. 11, no. 8, pp. 2225-2234, 2018.
[25] K.-M. Huang et al., "Nonfullerene Polymer Solar Cell with Large Active Area of 216 cm2 and High Power Conversion Efficiency of 7.7%," Solar RRL, 2019.
[26] "<2013_Book_OrganicSolarCells.pdf>."
[27] Q. Li et al., "Insights into Charge Separation and Transport in Ternary Polymer Solar Cells," ACS Appl Mater Interfaces, vol. 11, no. 3, pp. 3299-3307, Jan 23 2019.
[28] W. Zhao et al., "Fullerene-Free Polymer Solar Cells with over 11% Efficiency and Excellent Thermal Stability," Adv Mater, vol. 28, no. 23, pp. 4734-9, Jun 2016.
[29] W. Zhao, S. Li, S. Zhang, X. Liu, and J. Hou, "Ternary Polymer Solar Cells based on Two Acceptors and One Donor for Achieving 12.2% Efficiency," Adv Mater, vol. 29, no. 2, Jan 2017.
[30] Y. Lin et al., "An electron acceptor challenging fullerenes for efficient polymer solar cells," Adv Mater, vol. 27, no. 7, pp. 1170-4, Feb 18 2015.
[31] B. Petter Jelle, C. Breivik, and H. Drolsum Røkenes, "Building integrated
photovoltaic products: A state-of-the-art review and future research
opportunities," Solar Energy Materials and Solar Cells, vol. 100, pp. 69-96,
2012.
[32] B. A. Courtright and S. A. Jenekhe, "Polyethylenimine Interfacial Layers in
Inverted Organic Photovoltaic Devices: Effects of Ethoxylation and Molecular
Weight on Efficiency and Temporal Stability," ACS Appl Mater Interfaces, vol.
7, no. 47, pp. 26167-75, Dec 2 2015.
[33] E. I. Haskal, A. Curioni, P. F. Seidler, and W. Andreoni, "Lithium–aluminum
contacts for organic light-emitting devices," Applied Physics Letters, vol. 71,
no. 9, pp. 1151-1153, 1997.
[34] Z. Tan et al., "High performance polymer solar cells with as-prepared zirconium acetylacetonate film as cathode buffer layer," Sci Rep, vol. 4, p. 4691, Apr 15 2014.
[35] "<清大電子 黃垣翰 碩士論文.pdf>."
[36] T. G. Dane et al., "Influence of solvent polarity on the structure of drop-cast electroactive tetra(aniline)-surfactant thin films," Phys Chem Chem Phys, vol. 18, no. 35, pp. 24498-505, Sep 21 2016.
[37] W. Zhao et al., "Fullerene-Free Polymer Solar Cells with over 11% Efficiency and Excellent Thermal Stability," Adv Mater, vol. 28, no. 23, pp. 4734-9, Jun 2016.
[38] W. Liu et al., "Solution-Processed 8-Hydroquinolatolithium as Effective Cathode Interlayer for High-Performance Polymer Solar Cells," ACS Appl Mater Interfaces, vol. 8, no. 14, pp. 9254-61, Apr 13 2016.
[39] Y. Chen et al., "Insights into the working mechanism of cathode interlayers in polymer solar cells via [(C8H17)4N]4[SiW12O40]," Journal of Materials Chemistry A, vol. 4, no. 48, pp. 19189-19196, 2016.