研究生: |
翁崇瑄 Weng, Chung-Hsiung |
---|---|
論文名稱: |
熔鹽合成法製備鈦酸鋇奈米線及其壓電性質和應用 Piezoelectric Properties and Applications of Barium Titanate Nanowires Synthesized by Molten Salt Method |
指導教授: |
林樹均
Lin, Su-Jien |
口試委員: |
李勝隆
洪建龍 |
學位類別: |
碩士 Master |
系所名稱: |
工學院 - 材料科學工程學系 Materials Science and Engineering |
論文出版年: | 2014 |
畢業學年度: | 102 |
語文別: | 中文 |
論文頁數: | 159 |
中文關鍵詞: | 奈米線 、鈦酸鋇 、壓電 |
相關次數: | 點閱:3 下載:0 |
分享至: |
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本研究利用 K2Ti4O9 奈米線作為反應前驅物,而後再將 K2Ti4O9 奈米線與BaCO3粉末在共晶鹽 KCl-NaCl 中以熔鹽合成法透過離子置換過程成功製備出 BaTiO3 奈米線,其反應是利用self-sacrificing template effect 及 Kirkendall effect,所合成的產物形貌與前驅物 K2Ti4O9 奈米線相近,而後將 BaTiO3 奈米線放置於高溫爐內於退火 2 小時使得表面平坦化及奈米線反應更完全,並且晶粒排列成長成單晶結構。
本研究以壓電力顯維鏡來量測 BaTiO3 奈米線的壓電性質,壓電量測分別以 VPFM 及 LPFM 兩種模式量測,其中以 VPFM 模式量測下壓電係數 d33 經計算約為 0.89 pm/V,而以 LPFM 模式量測下測得的壓電係數 d15 為 51.9 pm/V,以 LPFM 模式所偵測到的壓電係數相當優良,證明 BaTiO3奈米線有良好的壓電特性。本研究利用 BaTiO3 奈米線與 PDMS 高分子混合成功製備出奈米發電機作為應用,並添加奈米碳管幫助分散奈米線分散,當添加12 wt % BaTiO3 奈米線及1 wt % 奈米碳管時奈米發電機可得到最高的輸出電壓及輸出電流,約為 1.8 V及125 nA,而在極化處理過後奈米發電機的輸出電壓及輸出電流更可達到 3.4 V及300 nA,由此可證明由 BaTiO3 奈米線所製作而成的奈米發電機具有絕佳的發電能力。
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