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研究生: 黃日鉉
論文名稱: Inconel 625超合金於超臨界水環境下之腐蝕行為研究
Corrosion Behavior of Inconel 625 Superalloy in Supercritical Water
指導教授: 開執中
陳福榮
葉宗洸
口試委員:
學位類別: 碩士
Master
系所名稱: 原子科學院 - 核子工程與科學研究所
Nuclear Engineering and Science
論文出版年: 2009
畢業學年度: 97
語文別: 中文
論文頁數: 78
中文關鍵詞: 超臨界水腐蝕
相關次數: 點閱:2下載:0
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  • 超臨界水反應器(supercritical water-cooled reactor, SCWR)為第四代核能反應器之一,其操作環境高於水的臨界點,溫度必須超過374℃且壓力高於22.1 MPa。相對於現今輕水式反應器,超臨界水反應器的設計簡化使得安全性提高且降低成本,且超臨界水反應器操作在相當高溫的環境,因而提供相當高的熱效率,大約為45%(現今輕水式反應器熱效率約為33%)。
    超臨界水所表現出的物理性質和溫度低於臨界點以下的液態水有很大的不同,因此材料在超臨界水環境下所表現的腐蝕行為成為一值得研究的題目。而本實驗將Inconel 625試片置於高壓釜內,實驗溫度測定於600℃,壓力在24.8 MPa (3600psi),入水口溶氧濃度為8.3 ppm,透過腐蝕前後試片的單位面積質量改變量與微結構分析探討材料的腐蝕特性。於600℃之超臨界水環境下,相較於304L,Inconel 625在單位面積質量變化上並無明顯改變,利用300、600及1000小時的單位面積質量變化量得到一趨勢線,w^2.21=1.4×10^-5 t,符合拋物線律。另在表面發現8~9μm大小之孔蝕,推測孔蝕與原有的(Nb,Ti)C析出相有關。進一步分析得知氧化層呈現兩層的結構,外層為spinel Ni(Cr,Fe)2O4,內層為spinel Ni(Cr,Fe)2O4加上Cr2O3組成緻密連續的氧化層。經過輻射照射15dpa後再經過300小時600℃的腐蝕實驗後,氧化層與未經輻照之試片相比並無明顯變化,但母材之γ”有巨凝現象發生,在電子束入射方向B=[001]方向的長度約為原γ”的13倍。


    章節目錄 摘要 I 章節目錄 II 圖目錄 IV 表目錄 IX 第一章 前言及研究動機 1 第二章 文獻回顧 6 2-1金屬材料於超臨界水環境之腐蝕行為 6 2-1.1肥粒麻田鐵 6 2-1.2奧斯田不鏽鋼 7 2-1.2鎳基超合金 8 2-2金屬材料的輻射損傷 9 2-3超合金發展與應用 12 2-3.1鎳基超合金發展與應用 13 2-3.2超合金Inconel 625發展與應用 14 第三章 實驗原理與方法 31 3-1 腐蝕實驗 31 3-1.1 超臨界水循環系統 31 3-2 離子照射實驗 32 3-2.1 SRIM程式模擬計算 33 3-2.2 離子佈植照射系統 34 3-3 實驗分析 35 3-4.1 電子顯微鏡原理 35 3-4.2 電子束與物質交互作用 35 3-4.3 電子顯微鏡系統 36 3-4.4 X-光能量分散光譜儀(EDS) 37 3-4試片製備 37 第四章 實驗結果與討論 44 4-1 重量變化 44 4-2 表面分析 44 4-3 氧化層分析 45 4-3.1 氧化層厚度 45 4-3.2 TEM分析 46 4-3.3 XRD分析 47 4-4 微結構分析 48 4-5 輻射效應 49 第五章 結論 72 第六章 未來研究方向 74 參考文獻 75

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