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研究生: 周子鑫
Chou, Tzu-Hsing
論文名稱: 非運轉中產生之低放射性固體廢棄物難測核種比例因數之可行性分析與應用
Feasibility Analysis and Application of Scaling Factor of Difficult to Measure Nuclide in Non-Operating Low Level Radioactive Waste
指導教授: 王竹方
Wang, Chu-Fang
口試委員: 邱垂煥
Chiou, Chwei-Huann
詹瑞裕
Chan, Ruey-Yu
王清海
Wang, Tsing-Hai
學位類別: 碩士
Master
系所名稱: 原子科學院 - 生醫工程與環境科學系
Department of Biomedical Engineering and Environmental Sciences
論文出版年: 2018
畢業學年度: 106
語文別: 中文
論文頁數: 110
中文關鍵詞: 比例因數放射性廢棄物
外文關鍵詞: scaling factor, radioactive waste
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  • 本報告主要是嘗試使用SF技術於某研究所核化學實驗室產生之放射性廢棄物,探討其可行性及相關之應用。首先利用移動式超鈾活度量測系統 (ISOCART)量測廢棄物中阿伐核種Am-241與Pu-239等核種及加馬核種Co-60和Cs-137的活度、表面劑量率等。接續利用盒鬚圖法排除樣品中的離群值後,並根據Co-60和Cs-137活度比值進行分群動作,共分成8群。再將前述各群進行比例因數計算。
    比例因數計算方法國際間有多種作法,本報告最後採用與EPRI建議之對數平均法作為計算比例因數之方法;從計算結果得知,難測核種Pu-239對應之關鍵核種選擇Co-60或Cs-137均可,其理論計算所得之比例因數和實際真正之比例因數誤差值在30%以內者約占6成以上,具參考價值;另難測核種Am-241對應之關鍵核種選擇則不應是Co-60或Cs-137。
    最後將算得之SF值並將其應用於TRU廢棄物接收流程中,作為接收標準之參考依據,此舉將使放射性廢棄物之營運管理更臻完善。本文案例中並成功篩選出8桶廢棄物桶疑似超過TRU廢棄物接收標準需退回重裝。


    This report mainly attempts to use SF technology in the radioactive waste generated from the laboratory, to explore its feasibility and related applications. First, using ISOCART to measure the activity and the surface dose rate of Am-241, Pu-239, Co-60, and Cs-137 in the waste. Then proceed to exclude outliers in the sample by using Box plot, and according to the activity ratios of Co-60 and Cs-137, they were divided into 8 groups. Finally, calculate the scale factor for each group.
    There are many methods for calculating the scaling factor. In this report, the logarithmic average method recommended by EPRI is used as the method for calculating the scaling factor. According to the calculation results, the key nucleus corresponding to Pu-239 can be selected as Co-60 or Cs-137.;Conversely, the key nucleus selection for the nuclear Am-241 should not be Co-60 or Cs-137. And finally we apply the calculated SF value to the TRU waste acceptance process. This will further improve the management of radioactive waste. In this case, we successfully screened out 8 barrels of waste that exceeded the TRU waste acceptance criteria and needed to be returned for reloading.

    摘要…………………………………………………………………………………………………………………....………i Abstract…………………………………………………………………………………………………………………….ii 誌謝…………………………………………………………………………………………………………………………...iii 目錄…………………………………………………………………………………………………………………………....iv 附圖目錄………………………………………………………………………………………………………………....vi 附表目錄…………………………………………………………………………………………………………….…...ix 第一章 緒論…………………………………………………………………………………………………………....1 第二章 放射性廢棄物量測…………………………………………………………………………………….8 2.1 樣品說明…………………………………………………………………………………………………………………8 2.2 移動式超鈾活度量測系統………………………………………………………………………………8 2.3 量測作業…………………………………………………………………………………………………………….…11 2.3.1 前置作業………………………………………………………………………………………………………….11 2.3.2 阿伐核種濃度量測……………………………………………………………………………………….12 第三章 比例因數計算方式說明……………………………………………………..........24 3.1 盒鬚圖判別法……………………………………………………………………………………………………….24 3.2 算術平均法…………………………………………………………………………………………………………….25 3.3 對數平均法…………………………………………………………………………………………………………….26 3.4 對數線性回歸法…………………………………………………………………………………………………….26 第四章 結果與討論…………………………………………………………………...............28 4.1 分群方法…………………………………………………………………………………………………………………..28 4.2 關鍵核種選擇………………………………………………………………………………………………………….50 4.3 計算結果…………………………………………………………………………………………………………………..51 4.3.1 算術平均法………………………………………………………………………..............52 4.3.2 對數平均法………………………………………………………………………………………………………..54 4.3.3 對數線性回歸法………………………………………………………………………………………………..56 4.3.4 計算方式差異性比較……………………………………………………………………………………….75 4.4 驗證………………………………………………………………………………………………………………………....77 4.5 比例因數應用…………………………………………………………………………………………………………..79 4.5.1 TRU 廢棄物之定義與分類………………………………………………………………………………80 4.5.2 TRU 廢棄物之接收要求………………………………………………………………………………….81 4.5.3 本文案例試算……………………………………………………………………………………………………..82 4.5.4 簡易計算方法……………………………………………………………………………………………………..85 第五章 結論及未來工作……………………………………………………………………………………….....87 第六章 參考文獻…………………………………………………………………………………………………......88 附錄、ISOCART核種量測活度報告………………………………………………………………….....90

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