本論文主要探討:(1)鋁合金樣品表面冰膜厚度的定量以及(2)水氣在鋁合金樣品表面吸附與脫附現象的研究，而在實驗中亦進行水氣氣壓讀值的校正，以確認定量上的準確性。
實驗系統以偏振調制紅外光譜儀為主，分析在不同氣壓下，鋁合金樣品表面的水氣吸附量。在水氣氣壓讀值的校正的實驗結果方面，定出了電容真空計、對流真空計以及水銀真空計對水氣氣壓的讀值誤差及修正因子。在鋁合金樣品表面冰膜厚度的定量實驗中，則是利用液態氮冷卻鋁合金樣品，搭配氣體動力學的公式計算，得到吸附在樣品表面的水分子層層數，而將紅外光光譜的訊號強度，換算水分子層數。
在鋁合金樣品表面水氣吸附與脫附現象的實驗中，則透過前述的兩個實驗結果，得到在真空腔內曝入水氣到飽和蒸氣壓的過程，其吸附等溫線屬於吸附等溫線的第二型，也就是BET多層吸附的模型。證明水氣在鋁合金樣品表面會有多層吸附的行為，而在飽和蒸氣壓時，在鋁合金樣品表面的水分子層，約有67層的水分子。在水氣由高氣壓往低氣壓進行的脫附過程中，鋁合金樣品表面所吸附的水分子量，多於吸附過程(由低氣壓往高氣壓進行)的水分子量，而呈現出遲滯現象。

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