本論文研究異味物質之偵測與逸散監測之問題。分為兩部分，第一部分是在128° YX-LiNbO3之表面聲波元件(SAW device)上製作感測薄膜，偵測易惡臭之胺類氣體。第二部分是利用具備無線傳輸功能之監測模組Alpha MOS RQBox，連續監測異味的逸散及其來源。
首先在感測薄膜的製備上，先以11-mercaptoundecanoic acid於元件表面形成自組裝單分子膜，再修飾上芳杯分子p-tert-butyl-calix- [n]arene (CA[n]，n=4,6)，增加薄膜在吸附分子上的選擇性。所偵測氣體為包括丙胺在內的三種胺類，及甲苯等四種有機溶劑。由感測結果中發現CA[4]與CA[6]均對於丙胺有較佳的感測能力而造成較大的頻率偏移(frequency shift)。CA[4]由於空穴結構之尺寸較小，增加立體因素之影響，導致其頻率偏移均比CA[6]要小，對於大分子的影響較大。元件的反應在丙胺濃度59-1000 ppmv的範圍內呈現良好的線性關係。丙胺之偵測極限為29.5 ppmv。另外，從X光光電子能譜(XPS)分析薄膜結構之熱穩定性的結果中發現，自組裝薄膜會在90-100°C之間開始產生結構上的損壞，即表面分子在加熱後的脫附。
在第二部分的研究中，於清華大學校園內之一異味逸散地點與其來源處進行9小時之連續監測。由監測結果中可觀察到感測器在短時間內的反應變化，逸散點與上游測點在晚間八點後均有較大的反應且持續時間長，因此可推論異味來源，有利於後續處理動作，如採樣與儀器分析，進行確認與獲得代表性之異味資訊。未來如再加裝自動取樣裝置，於感測器反應較高時自動取樣，則對於不定時的污染排放亦能進行有效的處理。

This study has focused on odor sensing material and emission problems. The first part involves the fabrication and characterization of sensing films deposited on a 128° YX-LiNbO3 based surface acoustic wave (SAW) device for the detection of organic amines, which can cause odors. The second part utilizes a wireless distributed sensor array system for real time continuous monitoring of ambient odor.
In the fabrication of sensing films, 11-mercaptoundecanoic acid (11-MUA) has rearranged on the surface of a SAW device as self- assembled monolayer, followed by modification with p-tert-butyl- calix[n]arene (CA[n], n=4,6), in order to enhance the selectivity. The device has been used to sense three amines and five organic solvents, and frequency shifts were recorded. The maximum frequency shift was observed when n-propylamine was introduced. The selectivity from cavity size of calixarenes resulted in smaller frequency shift when sensing compounds with larger molecular volume, like triethylamine. The SAW showed well dynamic range with n-propylamine concentration between 59-1000 ppmv with well linearity. The detection limit was 29.5 ppmv for n-propylamine .In addition, thermal stability of 11-MUA/CA[n] has been examed by X-ray photoelectron spectroscopy (XPS). The desorption of thiolate was observed by the thermal treatment in 100°C and 110°C.
As for monitoring ambient odor, a distributed six-sensor-array system with wireless communication capability has been demonstrated. By simultaneous monitoring the suspected site and the affected site, the source of ambient odor can be identified and facilitates the further analysis, such as GC/MS, to investigate the odor-causing substance.

第一章
1. 行政院環境保護署網站(http://www.epa.gov.tw)
2. 工業技術研究院能源與資源研究所 氣候變化綱要公約資訊網 (http://sd.erl.itri.org.tw/fccc/index.htm)
3. 吳仁彰，《電子鼻技術簡介》，科儀新知，24(5)，民國92年
4. (a) Kepley, L. J.; Crooks, R. M. Anal. Chem. 1992, 64, 3191 (b) Paolesse, R.; Monti, D.; La Monica, L.; Venanzi, M.; Froiio, A.; Nardis, A.; Di Natale, C.; Martinelli, E.; D’Amicao, A. Chem. Eur. J. 2002, 8, 2476 (c) B-Desmonts, L.; Beld, J.; Zimmerman, R. S.; Hernando, J.; Mela, P.; Parajó, M. F. G.; van Hulst, N. F.; van den Berg, A.; Reinhoudt, D. N.; C-Calama, M. J. Am. Chem. Soc. 2004, 126, 7293
5. (a) Zyryanov, G. V.; Kang, Y.; Rudkevich, D. M. J. Am. Chem. Soc. 2003, 125, 2997 (b) Dickert, F. L.; Sikorski, R. Mater. Sci. Eng. C 1999, 10, 39
6. Zhou, X. C.; Ng, S. C.; Chan, H. S. O.; Li, S. F. Y. Sense. Actuators B 1997, 42, 137
7. Wang, C.; He, X-W.; Chen, L-X. Talanta 2002, 57,1181
8. Cao, Z.; Murayama, K.; Aoki, K. Anal. Chim. Acta 2001, 448, 47
9. Dermody, D. L.; Crooks, R. M.; Kim, T. J. Am. Chem. Soc. 1996, 118, 11912
10. 葉雨松，《空氣品質監測站介紹》，科儀新知，26(5)，民國94年
11. 王介亨、王家麟，《環境中揮發性有禨物質監測儀器》，科儀新知，26(5)，民國94年
12. 行政院環保署，中華民國環境保護月報，第197期，民國94年

第二章
1. 吳朗，《電子陶瓷/壓電》，全欣資訊，台北巿，1994
2. Cheeke, J. D. N.; Wang, Z. Sense. Actuators B 1999, 59, 146
3. Sauerbrey, G.; Z. Phys. 1959, 155, 206
4. Ulman, A. Chem. Rev. 1996, 96, 1533
5. Bigelow, W. C.; Pickett, D. L.; Zisman, W. A. J. Colloid Interface Sci. 1946, 1, 513
6. Nuzzo, R. G.; Allara, D. L. J. Am. Chem. Soc. 1983, 105, 4481
7. (a) Allara, D. L.; Nuzzo, R. G. Langmuir 1985, 1, 45 (b) Allara, D. L.; Nuzzo, R. G. Langmuir 1985, 1, 45 (c) Ogawa, H.; Chihera, T.; Taya, K. J. Am. Chem. Soc. 1985, 107, 1365
8. (a) Sagiv, J. J. Am. Chem. Soc. 1980, 102, 92 (b) Wasserman, S. R.; Tao, Y. –T.; Whitesides, J. M. Langmuir 1989, 5, 1074
9. Duevel, R. V.; Corn, R. M. Anal. Chem. 1992, 64, 337
10. Schön, J. H.; Meng, H.; Bao, Z. Adv. Mater. 2002, 14, 232
11. Gustche, C. D. Calixarenes, The Royal Society of Chemistry, Cambridge, England, 1989
12. Bayer, A. Ber. 1872, 5, 280
13. Zinke, A.; Kretz, R.; Leggewie, E.; Hossinger, K. Monatsh. Chem. 1952, 83, 1213
14. Cornforth, J. W.; Hart, P. D.; Nicholls, G. A.; Rees, R. J. W.; Stock, J. A. Brit. J. Pharmacol. 1955, 10, 73.
15. Kammerer, H.; Happel, G.; Caesar, F. Makromol. Chem. 1972, 162, 179
16. Munch, J. H. Makromol. Chem. 1977, 178, 69
17. Gutsche, C. D.; Muthukrishnan, R. J. Org. Chem. 1978, 43, 4905
18. Moran, J. R.; Karbach, S.; Cram, D. J.; J. Am. Chem. Soc. 1982, 104, 5826
19. Grate, J. W.; Patrash, S. J. Anal. Chem. 1996, 68, 913
20. Hartmann, J.; Hauptmann, P.; Levi, S.; Dalcanale, E. Sense. Actuators B 1996, 35-36, 154
21. Cao, Z.; Murayama, K.; Aoki, K. Anal. Chim. Acta 2001, 448, 47
22. Huisman, B. –H.; van Velzen, E. U. T.; van Veggel, F. C. K. M.; Engbersen, J. F. J.; Reindoudt, D. N. Tetrahedron Lett. 1995, 36, 3273
23. Weib, T.; Schierbaum, K. D.; Van Velzen, U. T.; Reindoudt, D. N.; Göpel, W. Sense.Actuators B 1995, 26-27, 203
24. Kim, T.; Crooks, R. M.; Tsen, M.; Sun, L. J. Am. Chem. Soc. 1995, 117, 3963
25. Dermody, D. L.; Crooks, R. M.; Kim, T. J. Am. Chem. Soc. 1996, 118, 11912
26. Dermody, D. L.; Lee, Y.; Kim, T.; Crooks, R. M. Langmuir, 1999, 15, 8435
27. Eckel, R.; Ros, R.; Decaer, B.; Mattay, J.; Anselmetti, D. Angew. Chem. Int. Ed. 2005, 44, 484
28. 楊永瑞，《以表面聲波震盪電路為基礎之生化感測系統》，國立清華大學碩士論文，民國94年
29. Pishko, M. V.; Revzin, A.; Simonian, A. L. Sensors 2002, 2, 79
30. Wade, L. G. Jr. Organic Chemistry, 4th ed, Prentice-Hall Inc. Press, New Jersey, 1999, Chapter 1
31. 《材料分析》汪建民 主編，中國材料科學學會，新竹市，民國87年
32. Porter, M. D.; Bright, T. B.; Allara, D. L.; Chidsey, C. E. D. J. Am. Chem. Soc. 1987, 109, 3359
33. Ishida, T.; Fukushima, H.; Muzutani, W.; Miyashita, S.; Ogiso, H.; Ozaki, K.; Tokumoto, H. Langmuir 2002, 18, 83
34. Bensebaa, F.; Ellis, T. H.; Badia, A.; Lennox, R. B.; J. Vac. Sci. Technol. A 1995, 13, 1331
35. Valiokas, R.; Östblom, M.; Svedhem, S.; Svensson, S. C. T.; Liedberg, B. J. Phys. Chem. B 2002, 106, 10401
36. Yang, H. C.; Dermody, D. L.; Xu, C.; Ricco, A. J.; Crooks, R. M. Langmuir 1996, 12, 726
37. Martin, S. J.; Frye, G. C.; Senturia, S. D. Anal. Chem. 1994, 66, 2201
38. Christofides, C.; Mandelis, A. J. Appl. Phys. 1990, 68, 15
39. Andreetti, G. D.; Ungaro, R.; Pochini, A. J. Chem. Soc., Chem. Commun. 1979, 1005
40. Tsuzuki, S.; Honda, K.; Uchimaru, T.; Mikami, M.; Tanabe, K. J. Am. Chem. Soc. 2000, 122, 11450
41. Gustche, C. D.; Iqbal, M.; Alam, I. J. Am. Chem. Soc. 1987, 109, 4314
42. Brouwer, E. B.; Udachin, K. A.; Enright, G. D.; Ripmeester, J. A. Chem. Commun. 2000, 1905
43. Steed, J. W.; Atwood, J. L. Supramolecular Chemistry; John Wiley & Sons, Chichester, 2000
44. Wade, L. G. Jr. Organic Chemistry, 4th ed, Prentice-Hall Inc., New Jersey, 1999, Chapter 19
45. Love, J. C.; Estroff, L. A.; Kriebel, J. K.; Nuzzo, R. G.; Whitesides, G. M. Chem. Rev. 2005, 105, 1103
46. Surface Analysis: The Principal Techniques, Vickerman, J. C. Ed, John Wiley & Sons, Chichester, 1997
47. Beer, P. D.; Gale, P. A.; Smith, D. K. Supramolecular Chemistry; Oxford University Press, Oxford, 1999

第三章
1. U.S. EPA, Compendium method TO-14A, The determination of volatile organic compounds (VOCs) in ambient air using specially prepared canisters with subsequent analysis by gas chromatography, 1999
2. U.S. EPA, Compendium method TO-15, The determination of volatile organic compounds (VOCs) in air collected in specially prepared canisters and analyzed by gas chromatography/mass spectrometry (GC/MS), 1999
3. 行政院環保署環境檢驗所，空氣中揮發性有機化合物檢測方法－不□鋼採樣筒/氣相層析質譜儀法 NIEA A715.12B，民國94年
4. U.S. EPA, Compendium method TO-17, The determination of volatile organic compounds (VOCs) in air using active sampling onto sorbent tubes, 1997
5. Hashmonay, R. A.; Yost, M. G.; Manane, Y.; Benayahu, Y. Atmos. Environ. 1999, 33,735
6. 張寶額、楊人芝《紅外光遙測技術於石化廠區監測之應用》，工研院環安中心十週年論文集
7. U.S. EPA, Compendium method TO-16, Long-path open-path Fourier transfer infrared monitoring of atmospheric gases, 1996
8. 馮天治，《高科技園區污（雨）水系統空氣中揮發性有機化合物之探討》，國立清華大學碩士論文，新竹市，民國92年
9. RQ BOX Manual, Version 1.0, ALPHA M.O.S., 2004
10. 吳泉毅、楊宗燁、林鴻明《奈米半導體材料之氣體感測性質》，物理雙月刊，25(3)，2003
11. 吳仁彰《電子鼻技術簡介》，科儀新知，24(5)，2003
12. Luo, D. H.; Hosseini, H. G.; Stewart, J. R. Sense. Actuators. B 2004, 98, 253
13. Mantini, A.; Di Natale, C.; Macagnano, A.; Paolesse, R.; Finazzi-Agro, A.; D’Aminco, A. Crit. Rev. Biomed. Eng. 2000, 28, 481
14. Delpha, C.; Lumbreras, M.; Siadat, M. Sense. Actuators. B 2004, 98, 46
15. Alpha M.O.S, Technical Note N-SAS-05: LY Sensors, 2002
16. Harkov, R.; Kebbekus, B.; Bozzelli, J. W. J. Air Pollut. Control Assoc. 1983, 33, 1177
17. Kuo, H.-W.; Wei, H.-C.; Liu, C.-S.; Lo, Y.-Y.; Wang. W.-C.; Lai, J.-S.; Chan, C. C. Atmos. Environ. 2000, 34, 3331
18. 范姜威鎧，《台北市道路鄰近地區及加油站空氣中揮發性有機化合物濃度調查研究》，國立陽明大學碩士論文，民國88年
19. Department of the Environment and Heritage, Technical Report No.8: Personal Monitoring of Selected VOCs: The Contribution of Woodsmoke to Exposure, Commonwealth of Australia, 2004
20. Agency for Toxic Substances and Disease Registry (ATSDR), Toxicological Profile for Toluene (Update), U.S. Public Health Service, U.S. Department of Health and Human Services, Atlanta, 1994
21. 周明顯，《環境臭味及控制》，科學發展，387，2005
22. 何玉琦，《應用嗅覺與儀器方法分析水中臭味之研究》，國立成功大學碩士論文，民國93年