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研究生: 葉宥麟
You-Lin Ya
論文名稱: 浸沾式塗佈法改善rr-P3HT場效電晶体效能之研究
The Study on improving the efficiency of rr-P3HT Field-effect transistors by dip-coating
指導教授: 洪勝富
Sheng-Fu Horng
孟心飛
Hsin-Fey Meng
齊正中
Cheng-Chung Chi
口試委員:
學位類別: 碩士
Master
系所名稱: 電機資訊學院 - 電子工程研究所
Institute of Electronics Engineering
論文出版年: 2006
畢業學年度: 94
語文別: 中文
論文頁數: 55
中文關鍵詞: P3HT浸沾式塗佈法場效電晶体有機
相關次數: 點閱:3下載:0
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  • 平面顯示器中OLED因其有可撓性且有良好的亮度和對比,成為當今研究的熱門主題之一,而OLED中的PLED更有著可發展大尺寸和成本低廉的優點,本實驗室的研究重點在於製作PLED並藉由主動式驅動電路,發展一個基本的顯示器架構。其中主動式驅動電路利用二個有機薄膜電晶体再加上一個電容形成所謂的2T1C來驅動LED的主動式元件,如何提升2T1C中transistor的效能,即是我們的努力目標,這裡我們試驗以Dipping coating來達到此目的。本論文研究以dip-coating的方式來改善rr-P3HT場效電晶体的效能;我們以玻璃為基板,鍍上金屬鉻當gate,使用APCVD生長200nm左右的氧化層,以lift off的方法製作Source、Drain的金電極;之後再以dip-coating的方式產生HMDS(使基板更親水、P3HT(主動層),以dip-coating所製作出來的薄模有比一般的成膜方法擁有更好的自組性即膜內分子的排列比一般方式整齊,所產生出來的FET元件都可達到不錯的mobility性質。我們研究使用氯仿(Chloroform)、對二甲苯(P-xylene)、甲苯(toluene)來作為P3HT的溶劑;改變溶液的濃度和dip-coating拉速來觀察對試片載子遷移率(mobility)和on/off ratio的影響,嘗試不同條件來提升元件的效能,並試驗以氮氣回烤、封裝後續處理來提升on/off ratio。我們的結果使電晶体載子遷移率達到 的order,最好的結果是0.298 略微超越目前文獻上所發表的以玻璃為基板、P3HT為材料中最高0.28 而on/off ratio也有3000左右,成功地達到效能提升的成果。


    We try to improve the performance of rr-P3HT Field Effect Transistor by dip coating.
    Glass is the substrate with SiO2(APCVD) gate dielectric layer about 200nm. .S-D(Au) is deposited by (thermally grow) and lifted off. Afterward we dip the sample into HMDS and solution with P3HT to make the active layer. We change the different solvents of P3HT (Chloroform、P-xylene、Toluene), the concentration of solutions and the speed of dip coating to observe the variation of sample mobility and on/off ratio. Finally we try to make samples exposure to N2 gas or packed for several days to increase the on/off ratio. Our results is that sample mobility achieve order and the best is 0.298 with 3000 on/off ratio.

    目錄 第一章 序論 1.1 研究背景-----------------------------------------------------------------------------------5 1.2 研究動機與方向--------------------------------------------------------------------------5 1.3 論文架構-----------------------------------------------------------------------------------6 第二章 實驗原理與參考文獻 2.1 P3HT的性質-------------------------------------------------------------------------------7 2.2 dipping coating-----------------------------------------------------------------------------9 2.3 回烤-----------------------------------------------------------------------------------------10 2.4有機薄膜場效電晶体的結構、運作方式和參數計算------------------------------11 第三章 實驗流程 3.1 元件結構-----------------------------------------------------------------------------------12 3.2 元件製作流程-----------------------------------------------------------------------------12 3.3 元件量測----------------------------------------------------------------------------------19 第四章 實驗結果分析 4.1元件mobility的改善--------------------------------------------------------------------20 4.2on/off ratio的改善------------------------------------------------------------------------42 第五章 總結----------------------------------------------------------------------------53 參考文獻---------------------------------------------------------------------------------------54

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