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研究生： 陳立群
Chen, Li Chun
論文名稱： 利用雙層同時狹縫式塗佈與配方設計提升鋰離子電池性能
The Enhancement of Electrochemical Performances of Lithium Ion Batteries through Two-layered Simultaneous Slot-die Coating and Formulation Design
指導教授： 劉大佼
Liu, Ta Jo
口試委員: 萬其超
Wan, Chi Chao
汪上曉
Wong, Shan Hill
蔡德豪
Tsai, De Hao
溫恕恒
Wen, Shu Heng
學位類別： 博士
Doctor
系所名稱： 工學院 - 化學工程學系
Department of Chemical Engineering
論文出版年： 2016
畢業學年度： 104
語文別： 中文
論文頁數： 164
中文關鍵詞： 鋰離子電池 、雙層狹縫式同時塗佈 、配方設計
外文關鍵詞： Lithium Ion Battery, Two-layered Simultaneous Slot-die Coating, Formulation Design
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    • 近年來鋰離子電池(Lithium Ion Batteries，LIBs)已廣泛應用於各項產品上，尤其在各類型電動汽車的應用需求更逐年增加，對鋰離子電池產率及性能也愈來愈重視。本研究利用雙層同時狹縫式塗佈與配方設計技術進行鋰離子電池極板製作。研究主軸分為兩類，首先利用不同配方設計來增進電子與離子傳導，改變配方內導電添加劑添加量比例，利用導電添加劑不同粒徑大小、形狀及應用特性來提升電池特性，其中以雙層極板所製作之電池在3C下有最高的C-rate特性，並且將電池進行循環充放電150次測試，仍有最佳放電容量，並保持最低的容量衰退率。
    其二，利用改變上下層漿料配方，在塗佈層上層減少黏著劑含量而下層增加黏著劑含量，而塗層中黏著劑成份總含量不變，利用快速乾燥中，對流作用及毛細力影響，使塗層內部黏著劑達到均勻分佈之效果，可以有效解決高溫乾燥時黏著劑遷移至表面的問題，在150℃乾燥之雙層極板所製作之電池電性相似80℃乾燥之單層極板之電池電性，以上實驗皆證明雙層同時狹縫式塗佈與配方設計技術所製作之極板，可有效提升電池性能。

    Lithium ion batteries (LIBs) have been developed for extensive industrial applications in recent years. An important application of LIBs is in the electrification of automobiles. LIBs must possess superior electrochemical properties such as high life cycle, high energy and high power density. The electrodes could be improved using a two-layered cathode produced by a simultaneous slot-die coating and formulation design. There are two targets; the first one is improvement the performance through the variation conductive additives. The two-layered cathode with an upper layer having more carbon black and a lower layer having more graphite particles was found to give the best current discharge capacity and longer life cycle.
    In the other research target, the upper and lower layers in the film contained different compositions of binder with the upper one containing less binder than the lower one. During the rapid high temperature drying of the wet film, the uneven binder migration would be reduced to a more uniform binder network structure inside the dried composite cathode. The electrochemical performance of the lithium-ion battery, assembled with the two-layered Cathode drying under 150℃ was found similar the single-layered Cathode drying under 80℃. The lithium ion batteries made with two-layered cathode produced by a simultaneous slot-die coating and formulation design offered a new approach to give a better overall battery performance.

    目錄 第一章 緒論 1 1-1背景說明 1 1-2鋰離子電池基本原理 3 1-3鋰離子電池製程成本 4 1-4研究動機 6 1-5研究架構 7 第二章 文獻回顧 9 2-1極板塗佈與乾燥程序 10 2-1-1狹縫式塗佈技術 (slot-die coating) 11 2-1-2多層狹縫式塗佈技術 13 2-1-3乾燥程序對粒子遷移影響 15 2-1-4乾燥程序對黏著劑遷移影響 19 2-1-5粒子與黏著劑遷移檢測技術 22 2-2漿料配方與極板結構設計 23 2-3電池製作程序對性能影響 26 2-3-1漿料混合分散製程對電池性能影響 27 2-3-2極板輾壓製程對電池性能影響 28 2-4電池特性分析 33 2-5雙層極板應用現況 36 2-5-1極板製程改善(重覆多次塗佈) 37 2-5-2不同特性活性物質分層塗佈 38 2-5-3不同功能層分層塗佈 41 第三章 實驗方法 48 3-1雙層外部接觸型狹縫式塗佈模具 48 3-2實驗步驟 50 3-2-1漿料配製 51 3-2-2塗佈程序 53 3-2-3極板輾壓程序 57 3-2-4極板性質檢測 57 3-2-5薄型鋰離子電池組裝程序 59 3-2-6薄型鋰離子電池電性測試 60 第四章 利用不同導電添加劑配方雙層同時塗佈以提升鋰離子電池性能 62 4-1前言 62 4-2漿料配方與結構設計 63 4-2-1配方設計概念 63 4-2-2極板結構設計 65 4-3漿料配製與塗佈乾燥 66 4-3-1雙層塗佈之極限與漿料配方關係 66 4-3-2雙層塗佈與極板輾壓 70 4-4極板結構與形態 70 4-5極板特性分析 75 4-5-1極板附著力測試 75 4-5-2極板導電度分析 77 4-6電池特性分析 80 4-6-1電池化成 80 4-6-2電池倍率測試 80 4-6-3電池循環充放電測試 88 4-6-4電池阻抗分析 90 4-7總結及未來極板設計方向 100 第五章 利用不同黏著劑配方以雙層同時塗佈提升極板乾燥速度 102 5-1前言 102 5-2單層極板乾燥實驗 103 5-3漿料配方設計與極板乾燥影響 110 5-4極板形態與元素分析分佈 115 5-5極板性質分析 124 5-5-1極板導電度測試 124 5-5-2極板附著力測試 127 5-6電池特性分析 130 5-6-1電池化成電容量測試 130 5-6-2電池倍率性能測試 132 5-6-3電池電化學阻抗測試分析 134 5-6-4電池循環充放電測試 139 5-7總結及未來極板設計方向 141 第六章 結論 143 參考文獻 146

    1. A. Manthiram, C.-A. Nazari, Lithium Batteries Science and Technology, springer (2009) 1-37.
    2. J.-M. Tarascon, M. Armand, Nature, 414 (2001) 359-367.
    3. M.S. Whittingham, Solid State Ionics, 134 (2000) 169-178.
    4. K. Matsuki, K. Ozawa, Lithium Ion Rechargeable Batteries, Wiley-Vch (2009) 1-9.
    5. X.-P. Gao, H.-X. Yang, Energy Environ. Sci., 3 (2010) 174–189.
    6. H. S. Choi, C. R. Park, Next Generation Lithium Ion Batteries for Electrical Vehicles, In-Tech (2010) 1-24.
    7. F.T. Wagner, B. Lakshmanan, M.F. Mathias, J. Phys. Chem. Lett., 1 (2010) 2204-2219.
    8. T. Horiba, Proceedings of the IEEE, 102 (2014) 939 - 950.
    9. S.T. Myung, Y. Hitoshia, Y. K. Sun, J. Mater. Chem., 21 (2011) 9891.
    10. A. Väyrynen, J. Salminen, J. Chem. Thermodynamics, 46 (2012) 80-85.
    11. J. Li, C. Daniel, D. Wood, J. Power Sources, 196 (2011) 2452-2460.
    12. D. L. Wood Ⅲ, J. Li, C. Daniel, J. Power Sources, 275 (2015) 234-242.
    13. M. Yoshio, R.J. Brodd, A. Kozawa, Lithium-Ion Batteries: Science and Technologies, Springer (2009)
    14. E. B. Gutoff, E. D. Cohen, G. I. Kheboian, Coating and Drying Defects: Troubleshooting Operating Problems, Wiley-Interscience (2006)
    15. A.L. Beguin, U. S. Patent 2681294 (1954)
    16. K. J. Ruschak, Chem. Eng Sci., 31 (1976) 1057-1060.
    17. B. G. Higgins, L. E. Scriven, Chem. Eng Sci., 35 (1980) 673-682.
    18. K.-Y. Lee, L-D. Liu, T-J Liu, Chem. Eng Sci., 47 (1992) 1703-1713.
    19. M. S. Carvalho, H. S. Kheshgi, AIChE J., 46 (2000) 1907-1917.
    20. M. Schmitt, M. Baunach, L. Wengeler, K. Peters, P. Junges, P. Scharfer, W. Schabel, Chem. Eng. Pro., 68 (2013) 32-37.
    21. M. Schmitt, P. Scharfer, W. Schabel, J. Coat. Technol. Res., 12 (5) (2015) 877–887.
    22. M. Schmitt, R. Diehm, P. Scharfer, W. Schabel, J. Coat. Technol. Res., 12 (5) (2015) 927–938.
    23. T. A. Russell, U. S. Patent 2761791 (1956)
    24. N. Imachi, H. Fujimoto, S. Fujitani, U. S. Patent 0026312 (2007)
    25. S. D. Taylor, A. N. Hrymak, Chem. Eng Sci., 54 (1999) 909-918.
    26. W. J. Yu, T. J. Liu, Chem. Eng Sci., 50 (1995) 917-920.
    27. S. Y. Lu, Y. P Lin, T. J. Liu, Polym. Eng. Sci., 41(10) (2001) 1823-1820.
    28. Lin, Y. N. S. Y. Huang, T. J. Liu, Polym. Eng. Sci., 45 (2005)1590-1599.
    29. M. Schmitt, S. Raupp, D. Wagner, P. Scharfer, W. Schabel, J. Coat. Technol. Res., 5 (2015) 877-887.
    30. A. F. Routh, W. B. Zimmerman, Chem. Eng Sci., 59 (2004) 2961-2968.
    31. C. M. Cardinal, Y. D. Jung, K. H. Ahn, L. F. Francis, AIChE Journal, 56 (2010) 2769-2780.
    32. M.Yamamura, KONA Powder and Particle Journal, 29 (2011) 39-52.
    33. F. Buss, C. C. Roberts, K. S. Crawford, K. Peters, L. F. Francis, J. Colloid and Interface science, 359 (2011) 112-120.
    34. S. Lim, K. H. Ahn, M. Yamamura, Langmuir, 29 (2013) 8233-8244.
    35. Y. Komoda, S. Kobayashi, H. Suzuki, J. Coat. Technol. Res., 12 (5) (2015) 939–948.
    36. Z. Liu, P. P. Mukherjee, J. Electrochem. Soc., 161 (2014) E3248-E3258.
    37. P. Bernada, D. Bruneau, TAPPI Journal, 79 (1996) 130-143.
    38. Z. Zhen, Z. Wang, Advanced Materials Research, 790 (2013) 45-48.
    39. Y. Li, W. Gu, B. He, Advanced Materials Research, 881-883 (2014) 1460-1463.
    40. Z. H. Zhen, Z. H. Chen, D. S. Lin, China Pulp & Paper, 25 (2006) 4-7.
    41. L. Yun, J. H. Yan, K. F. Chen, Journal of South China University of Technology, 28 (2000) 59-64.
    42. J. Vanderhof, E. Bradford, TAPPI Coating Conference Proceeding, Atlanta, USA (1990) 173-177.
    43. A. E. Ranger, C. Flnstp, Paper Technology, 35 (1994) 40-46.
    44. H. Hagiwara, W. J. Suszynski, L. F. Francis, J. Coat. Technol. Res., 11 (2014) 11-17.
    45. C.-C. Li, Y.-W. Wang, J. Electrochem. Soc., 158 (2011) A1361-A1370.
    46. C.-C. Li, Y.-W. Wang, J. Power Sources, 227 (2013) 204-210.
    47. E. Ligneel, B. Lestriez, A. Hudhomme, D. Guyomard, J. Electrochem. Soc., 154 (2007) A235-A241.
    48. B. G. Westphal, H. Bockholt, T. Günther, W. Haselrieder, A. Kwade, ECS Transaction, 64 (22) (2015) 57-68.
    49. S. D. Risio, N. Yan, Colloids and Surfaces A: Physicochem. Eng. Aspects, 289 (2006) 65-74.
    50. Y.-H. Zang, J. Du, Y. Du, Z. Wu, S. Cheng, Y. Liu, Langmuir, 26 (23) (2010) 18331-18339.
    51. B. Son, M.-H. Ryou, J. Choi, T. Lee, H. K. Yu, J. H. Kim, Y. M. Lee, ACS Appl. Mater. Interfaces, 6 (2014) 526−531.
    52. S. Nakao, T. Ueno, T. Shinpuku, M. Kanda, A. Ota, A. Yoshino, The 53rd Battery Symposium, Fukuoka, Japan (2012) 2A16.
    53. H. Fukumitsu, M. Ohmori, K. Morooka, T. Takahashi, S. Shimada, S. Suehiro, The 53rd Battery Symposium, Fukuoka, Japan (2012) 3C05.
    54. N. Hatakeyama, E. Suzuki, K. Okushi, R. Miura, A. Suzuki, A. Miyamoto, T. Miyuki, A. Koyama, N. Eda, R. Nagai, A. Ota, The 55rd Battery Symposium, Kyoto, Japan (2014) 2A03.
    55. M. Park, X. Zhang, M. Chung, G. B. Less, A. M. Sastry, J. Power Sources, 195 (2010) 7904-7929.
    56. Y.-M. Chen, C.-W. Wang, X. Zhang, A. M. Sastry, J. Power Sources, 195 (2010) 2851-2862.
    57. J. W. Fergus, J. Power Sources, 195 (2010) 939-954.
    58. J. C. Arrebola, A. Caballero, L. Hernán, J. Morales, Electrochemical and Solid-State Letters 8 (12) (2005) A641-A645.
    59. M. Takahashi, S. Tobishima, K. Takei, Y. Sakurai, Solid State Ionic, 148 (2002) 283-289.
    60. K. M. Shaju, G. V. S. Rao, B. V. R. Chowdari, Electrochimica Acta, 48 (2002) 145-151.
    61. M. Dubarry, C. Truchot, B. Y. Liaw, J. Power Sources, 258 (2014) 408-419.
    62. H.-S. Kim, M. Kong, K. Kim, I.-J. Kim, H.-B. Gu, J. Power Sources, 171 (2007) 917-921.
    63. C. L. Tan, H. J. Zhou, W. S. Li, X. H. Hou, D. S. Lü, M. Q. Xu, Q. M. Huang, J. Power Sources, 184 (2008) 408-413.
    64. R. Vacassy, H. Hofmann, N. Papageorgiou, M. Grätzel, J. Power Sources, 81-82 (1999) 621-626.
    65. S. B. Chikkannanavar, D. M. Bernardi, L. Liu, J. Power Sources, 248 (2014) 91-100.
    66. S. Jung, J. Power Sources, 264 (2014) 184-194.
    67. Z. F. Ma, X. Q. Yang, X. Z. Liao, X. Sun, J. McBreen, Electrochemistry Communications, 3 (2001) 425-428.
    68. K. G. Gallagher, S.-H. Kang, S. U. Park, S.Y. Han, J. Power Sources, 196 (2011) 9702-9707.
    69. T. Nukuda, T. Inamasu, A. Fujii, D. Endo, H. Nakagawa, S. Kozono, T. Iguchi, J. Kuratomi, K. Kohno, S. Izuchi, M. Oshitani, J. Power Sources, 146 (2005) 611–616.
    70. P. Albertus, J. Christensen, J. Newman, J. Electrochem. Soc., 156 (2009) A606-A618.
    71. A. J. Smith, S. R. Smith, T. Byrne, J. C. Burns, J. R. Dahn, J. Electrochem. Soc., 159 (2012) A1696-A1701.
    72. H. Y. Tran, C. Täubert, M. Fleischhammer, P. Axmann, L. Küppers, M. Wohlfahrt-Mehrens, J. Electrochem. Soc.,158 (2011) A556-A561.
    73. L.-C. Chen, D. Liu, T.-J. Liu, C. Tiu, C.-R. Yang, W.-B. Chu, C.-C. Wan, Journal of Energy Storage, 5 (2016) 156–162.
    74. J. Molenda, Solid State Ionics, 175 (2004) 203-213.
    75. J. Molenda, Solid State Ionics, 176 (2005) 1687-1694.
    76. K.-J. Euler, R. Kirchhof, H. Metzendorf, J. Power Sources, 5 (1980) 255–262.
    77. D. Adler, L. P. Flora, S. D. Senturia, Solid State Communications, 12 (1973) 9-12.
    78. S. Babinec, H. Tang, A. Tailk, S. Hughes, G. Meyers, J. Power Sources, 174 (2007) 508-514.
    79. G. Liu, H. Zheng, X. Song, V.S. Battaglia, J. Electrochem. Soc., 159 (2012) A214-A221.
    80. J. Xu, S.-L. Chou, Q.-F. Gu, H.-K. Liu, S.-X. Dou, J. Power Sources, 225 (2013) 172-178.
    81. M. Yoo, C. W. Frank, S. Mori, S. Yamaguchi, Polymer, 44 (2003) 4197–4204.
    82. S. Lee, E.-Y. Kim, H. Lee, E.-S. Oh, J. Power Sources, 269 (2014) 418-423.
    83. Z. Liu, A. Yu, J. Y. Lee, J. Power Sources, 74 (1998) 228-233.
    84. J. K. Hong, J. H. Lee, S. M. Oh, J. Power Sources, 111 (2002) 90-96.
    85. S. E. Cheon, C. W. Kwon, D. B. Kim, S. J. Hong, H. T. Kim, S. W. Kim, Electrochim. Acta, 46 (2000) 599-605.
    86. Y. Cai, C.-l. Fan, Electrochim. Acta, 58 (2011) 481-487.
    87. Z. Liu, A. Yu, J. Y. Lee, J. Power Sources, 74 (1998) 228-233.
    88. W.-R. Jin, S.-G. Lu, J. Pang, Chinese J. Inorganic Chemistry, 27(9) (2011) 1675-1684.
    89. L. Liu, Y. Dai, Y. Yao, Materials Review, 21 (2007) 267-269.
    90. M.-G. Jin, Chinese J. Power Sources, 29 (2005) 78-91.
    91. H. Zheng, R. Yang, G. Liu, X. Song, V. S. Battaglia, J. Phys. Chem., C 116 (2012) 4875-4882.
    92. Q.-C. Zhuang, H. Zheng, X. Song, V.S. Battaglia, J. Electrochem. Soc.,159 (2012) A214-A221.
    93. D. Guy, B. Lestriez, R. Bouchet, V. Gaudefroy, D. Guyomard, Electrochem. Solid-state Lett., 8 (2005) A17-A21.
    94. G. Liu, H. Zheng, A. S. Simens, A. M. Minor, X. Song, V. S. Battaglia, J. Electrochem. Soc., 154 (2007) A1129-A1134.
    95. D. Guy, B. Lestriez, R. Bouchet, D. Guyomard, J. Electrochem. Soc., 153 (2006) A679-A688.
    96. L.-J. Her, J.-L. Hong, C.-C. Chang, J. Power Sources, 161 (2006) 1247-1253.
    97. M. Yoo, C. W. Frank, S. Mori, Chem. Mater., 15 (2003) 850-861.
    98. M. Yoo, C. W. Frank, S. Mori, S. Yamaguchi, Chem. Mater., 16 (2004) 1945-1953.
    99. W. Haselrieder, B. Westphal, H. Bockholt, A. Diener, S. Höft, A. Kwade, Int. J. Adhes. Adhes., 60 (2015) 1-8.
    100. G. Reinhart, T. Zeilinger, J. Kurfer, M. Westermeier, C. Thiemann, M. Glonegger, M. Wunderer, C. Tammer, M. Schweier, M. Heinz, Future Trends in Production Engineering, Springer-Verlag Berlin Heidelberg (2012) 3-12.
    101. T. Marks, S. Trussler, A. J. Smith, D. Xiong, J. R. Dahn, J. Electrochem. Soc., 158 (2011) A51-A57.
    102. P. A. Tanguy, F. Thibault, C. Dubois, A. Ait-Kadi, Chemical Engineering Research and Design, 77 (1999) 318-324.
    103. G. Zhou, P. A. Tanguy, C. Dubois, Chemical Engineering Research and Design 78 (2000) 445-453.
    104. D. Liu, L.-C. Chen, T.-J. Liu, T. Fan, E.-Y. Tsou, C. Tiu, Advances in Chemical Engineering and Science, 4 (2014) 515-528.
    105. K. M. Kim, W. S. Jeon, I. J. Chung, S. H. Chang, J. Power Sources, 83 (1999) 108-113.
    106. G.-W. Lee, J. H. Ryu, W. Han, K. H. Ahn, S. M. Oh, J. Power Sources, 195 (2010) 6049-6054.
    107. J. Kim, M. Eom, S. Noh, D. Shin, J. Power Sources, 244 (2013) 476-481.
    108. W. Haselrieder, S. Ivanov, H. Y. Tran, S. Theil, L. Froböse, B. Westphal, M. Wohlfahrt, A. Kwade, Progress in Solid State Chemistry, 42 (2014) 157-174.
    109. A. Ponrouch, M. R. Palacín, J. Power Sources, 196 (2011) 9682-9688.
    110. C.-C. Li, Y.-S. Lin, J. Power Sources, 220 (2012) 413-421.
    111. H. Zheng, L. Zhang, G. Liu, X. Song, V. S. Battaglia, J. Power Sources, 217 (2012) 530-537.
    112. H. Nakajima, T. Kitahara, Y. Higashinaka, Y. Nagata, ECS Transaction, 64 (22) (2015) 87-95.
    113. H. Usui, K. Kishimoto, H. Suzuki, Chem. Eng Sci., 56 (2001) 2979-2989.
    114. M. Zhu, J. Park, A. M. Sastry, J. Electrochem. Soc., 158 (2011) A1155-A1159.
    115. W. Porcher, B. Lestries, S. Jouanneau, D. Guyomard, J. Electrochem. Soc., 156 (2009) A133-A144.
    116. J.-H. Lee, J.-S. Kim, Y. C. Kim, D. S. Zang, U. Paik, Ultramicroscopy, 108 (2008) 1256-1259.
    117. W. Zhang, X. He, W. Pu, J. Li, C. Wan, Ionics, 17 (2011) 473-477.
    118. B. Bitsch, J. Dittmann, M. Schmitt, P. Scharfer, W. Schabel, N. Willenbacher, J. Power Sources, 265 (2014) 81-90.
    119. B. P. N. Nguyen, S. Chazelle, M. Cerbelaud, W. Porcher, B. Lestriez, J. Power Sources, 262 (2014) 112-122.
    120. J. Choi, B. Son, M.-H. Ryou, S. H. Kim, J. M. Ko, Y. M. Lee, J. Electrochem. Sci. Tech., 4 (2013) 27-33.
    121. D. Sawada, Y. Morita, D. Nishimura, T. Sasakawa, D. Ogata, N. Eda, The 54rd Battery Symposium, Osaka, Japan (2013) 1B06.
    122. D. Kehrwald, P. R. Shearing, N. P. Brandon, P. K. Sinha, S. J. Harris, J. Electrochem. Soc., 158 (2011) A1393-A1399.
    123. S. J. Harris, P. Lu, J. Phys. Chem. C, 117 (2013) 6481-6492.
    124. I. V. Thorat, D. E. Stephenson, N. A. Zacharias, K. Zaghib, J. N. Harb, D. R. Wheeler, J. Power Sources, 188 (2009) 592-600.
    125. W.-R. Jin, S.-G. Lu, J. Pang, Chinese J. Power Sources, 35 (2011) 499-502.
    126. J. Newman, J. Electrochem. Soc., 142 (1995) 97-101.
    127. M. Doyle, T. F. Fuller, J. Newman, J. Electrochem. Soc., 140 (1993) 1526-1533.
    128. P. Arora, R. E. White, M. Doyle, J. Electrochem. Soc., 145 (1998) 3647-3667.
    129. Q. Zhang, R. E. White, J. Power Sources, 179 (2008) 793-798.
    130. Q.-C. Zhuang, T. Wei, L.-L. Du, Y.-L. Cui, L. Fang, S.-G. Sun, J. Phys. Chem. C, 114 (2010) 8614-8621.
    131. X.-Y. Qiu, Q.-C. Zhuang, Q.-Q. Zhang, R. Cao, Y.-H. Qiang, P.-Z. Ying, S.-G. Sun, J. Electroanalytical Chem., 687 (2012) 35-44.
    132. D. Lu, W. Li, X. Zuo, Z. Yuan, Q. Huang, J. Phys. Chem. C, 111 (2007) 12067-12074.
    133. S. S. Zhang, K. Xu, T. R. Jow, Electrochim. Acta, 49 (2004) 1057-1061.
    134. M.-S. Wu, P.-C. Julia Chiang, J.-C. Lin, J. Electrochem. Soc., 152 (2005) A1041-A1046.
    135. E.-G. Shim, T.-H. Nam, J.-G. Kim, H.-S. Kim, S.-I. Moon, Electrochim. Acta, 54 (2009) 2276-2283.
    136. L. A. Riley, S. V. Atta, A. S. Cavanagh, Y. Yan, S. M. George, P. Liu, A. C. Dillom, S.-H. Lee, J. Power Sources, 196 (2011) 3317-3324.
    137. S.-W. Roh, M.-S. Han, T.-K. Kim, S.-S. Kim, J.-K. Hong, U. S. Patent 052379 (2012)
    138. T. Suzuki, H. ABE, Y. Wakizaka, U. S. Patent 0122366 (2013)
    139. N. G. Sung, D. H. Ryu, C. H. Ku, J. J. Kim, H. L. Shim, U. S. Patent 0224584 (2013)
    140. H. Suzuki, T. Tanaka, Y. Konishi, G. Li, S. Mizutani, Y. Hosoya, U. S. Patent 099495 (2006)
    141. H. Sugiyama, J. P. Patent 034215 (2008)
    142. M. Matsuu, T. Numata, T. Noguchi, J. P. Patent 293875 (2008)
    143. K. Mitani, T. Atsumi, J. P. Patent 064574 (2009)
    144. K. Zaghib, M. Petitclerc, P. CHAREST, A. Guerfi, M. Dontigny, U. S. Patent 301866 (2009)
    145. Z. Chen, Y. Wang, F. Zhao, Z. Yu, Y. Xie, J. Xie, J. Hu, L. Xu, U. S. Patent 0115024 (2012)
    146. T. Zhou, J. Tu, X. Chen C. N. Patent 102332558 (2012)
    147. J. Li, P. Lai, W. Zhao, Y. Chen, J. Wu, X. Gao, C. N. Patent 103066250 (2013)
    148. K. Zhong, X. Xia, J. Xue, Y. Tong, C. N. Patent 103515577 (2014)
    149. Z. He, P. Xia, L. Zheng, Wu Xia, L. Yan, H. Zhou, B. Zhan, J. Zhan, B. Tang, J. Wang, C. N. Patent 202268433 (2012)
    150. Z. Lv, F. Liu, Z. Yuan, J. Liu, C. N. Patent 203150652 (2013)
    151. W.B. Chu, D-J. Liu, C.C. Chen. L.-C. Chen, S.-T. Tseng, S.H. Wen, C.R. Yang, T. W. Patent I473330 (2014)
    152. N. Imachi, Y. Takano, H. Fujimoto, Y. Kida, S. Fujitani, J. Electrochem. Soc., 154 (2007) A412-A416.
    153. J. F. Whitacre, K. Zaghib, W. C. West, B. V. Ratnakumar, J. Power Sources, 177 (2008) 528-536.
    154. K. Takahata, J. P. Patent 176540 (2009)
    155. K. Utsugi, H. Yamamoto, J. Iriyama, M. Mori, T. Miura, Y. Bannai, M. Miyachi, I. Yamazaki, W. O. Patent 03073535 (2003)
    156. H. Shiota, H. Urushibata, T. Mitani, F. Uchikawa, U. S. Patent 6727021 (2004)
    157. P.-Y. Wu, W.-B. Chu, C.-R. Yang, J.-J. Lee, J.-P. Pan, T.-H. Wang, Y.-M. Peng, T. W. Patent I431834
    158. G. Shida, C. N. Patent 102130322 (2011)
    159. I. Doberdo, N. Loffler, N. Laszczynski, D. Cericola, N. Penazzi, S. Bodoardo, G.T. Kim, S. Passerini, J. Power Sources, 248 (2014) 1000-1006.
    160. S. Lee, E.S. Oh, J. Power Sources, 244 (2013) 721-725.
    161. X.M. Feng, X.P. Ai, H.X. Yang, Electrochemistry Communications, 6 (2004) 1021-1024.
    162. J. Christensen, J. Electrochem. Soc., 157 (2010) A366-A380.
    163. X. Zhang, S. Niu, Z. Shi, P. Li, D. He, C. N. Patent 102607240 (2012).
    164. N. G. Sung, D. H. Ryu, C. H. Ku, J. J. Kim, H. L. Shim, U. S. Patent 0224584 (2013).
    165. H. Ito, K. Abe, M. Ishida, Akihiro Nakano, T. Maeda, T. Munakata, H. Nakajima, T. Kitahara, J. Power Sources, 248 (2014) 822-830.
    166. A. Ponrouch, M. R. Palacín, J. Power Sources, 212 (2012) 233-246.
    167. C.-C. Li, J.-H. Jean, Chemistry and Physics, 94 (2005) 78-86.
    168. Y. Du, Y.-H. Zang, J. Du, Ind. Eng. Chem. Res., 50 (2011) 9781-9786.
    169. M. M. Mandanas, G. L. Messing, Thermochimica Acta, 363 (2000) 37-45.
    170. R. Dominko, M. Gaberscek, J. Drofenik, M. Bele, S.Pejovnik, J. Jamnik, J. Power Sources, 119-121 (2003) 770-773.
    171. Q. Zhuang, S. Xu, X. Qiu, Y. Cui, L. Fang, S. Sun, Progress in Chemistry, 22 (2010) 1044-1057.

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