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研究生： 賴怡廷
Lai, Yi-Ting
論文名稱： 利用還原氧化石墨烯及奈米銀線製備高性能可撓曲透明導電膜之研究
High performance flexible transparent conductive films based on reduced graphene oxides and silver nanowires
指導教授： 戴念華
Tai, Nyan-Hwa
口試委員: 戴念華
Nyan-Hwa Tai
葉孟考
Meng-Kao Yeh
邱博文
Po-Wen Chiu
李紫原
Chi-Young Lee
學位類別： 碩士
Master
系所名稱： 工學院 - 材料科學工程學系
Materials Science and Engineering
論文出版年： 2014
畢業學年度： 102
語文別： 中文
論文頁數： 94
中文關鍵詞： 奈米銀線 、還原氧化石墨烯 、p型摻雜效應 、透明導電軟板 、單一製程
外文關鍵詞： silver nanowires, reduced graphene oxide, p-type doping, flexible transparent conductive films, one-step process
相關次數： 點閱：3  下載：0 
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    • 本研究使用單一製程，製備一具有奈米銀線(AgNWs)和p型摻雜還原氧化石墨烯(p-rGO)的新型複合導電奈米材料，並具備均勻且分散性良好的特性。將此複合溶液塗佈在聚對苯二甲酸乙二酯(PET)基板上，可得到高性能的透明導電薄膜(TCFs)，並具備可彎曲的性質。本研究發現鑑於p型摻雜還原氧化石墨烯的添加，不僅可以橋接未接觸的AgNWs，還可以提供更多電洞載子，並降低AgNWs線與線之間的接觸電阻，在不降低TCFs透光度的情況下，p-rGO可以有效增加導電效果。此外p-rGO也可牢靠的將AgNWs固定在基板上，因而提升AgNWs和基板之間的附著力。本實驗將此複合導電奈米材料塗佈在PET基板上製備TCFs，其最佳光電表現可達94.68%(在可見光波550 nm)的透光性與25.0 ohm/sq的片電阻值。此外將此TCFs經過曲率半徑為5 mm的彎曲測試，以及各經過1000次的伸張與壓縮的彎曲耐久度測試，此TCFs的片電阻值皆沒有顯著的上升，表示本TCFs可應用於可撓曲電子產品上。研究顯示以本複合導電奈米材料製備的TCFs是未來光電產業中取代現有透明導電材料的一個絕佳選項。

    This work demonstrates an one-step process to synthesize uniformly dispersed hybrid nanomaterial containing silver nanowires (AgNWs) and p-type reduced graphene (p-rGO). The hybrid nanomaterial was coated onto a polyethylene terephthalate (PET) substrate to prepare high performance flexible transparent conductive films (TCFs). The p-rGO plays the role of bridging discrete AgNWs, providing more electron holes, and lowering the resistance of the contacted AgNWs, which enhances the electrical conductivity without sacrificing too much transparence of the TCFs. In addition, the p-rGO also improves the adhesion between AgNWs and substrate by covering the AgNWs on substrate tightly. The study shows that coating of the hybrid nanomaterials on the PET substrate demonstrates exceptional optoelectronic properties with a transmittance of 94.68% (at a wavelength of 550 nm) and a sheet resistance of 25.0 ohm/sq. Furthermore, no significant variation in electric resistance can be detected even though the film was subjected to a bend loading with a radius of curvature of 5.0 mm or the film was loaded with a reciprocal tension or compression for 1000 cycles. The study shows that the fabricated flexible TCFs have the potential to replace indium tin oxide film in the optoelectronic industry.

    摘要……………………………………………………………………….I Abstract………………………………………………………………...II 致謝……………………………………………………………………..Ⅳ 目錄…………………………………………………………………Ⅵ 表目錄………………………………………………………………Ⅹ 圖目錄………………………………………………………………..XI 第一章 緒論…………………………………………………………......1 1.1 前言………………………………………………….……….…1 1.2 研究動機………………………………………………………..2 第二章 文獻回顧………………………………………………………..4 2.1 透明導電膜簡介………………………………………………..4 2.1.1 金屬薄膜類……………………………………..……..…..5 2.1.2 金屬氧化物薄膜…………………………………………..6 2.1.2.1 銦錫氧化物………………………………………..6 2.1.2.2 氧化鋅型…………………………………………..8 2.1.3 導電高分子類……………………………………………..9 2.1.4 新型碳材料類……………………………………………10 2.2 奈米銀線簡介…………………………………………………12 2.3 奈米銀線之製備………………………………………………12 2.3.1 紫外光照射光還原法製備………………………………13 2.3.2 固-液相電弧法製備……………………………………...13 2.3.3 脈衝超聲電化學法製備…………………………………14 2.3.4 晶種異質成核法製備……………………………………14 2.3.5 電化學法製備……………………………………………15 2.3.6 多元醇法製備……………………………………………16 2.4 石墨烯簡介……………………………………………………19 2.5 石墨烯之製備…………………………………………………20 2.5.1 機械剝離法製備…………………………………………20 2.5.2 液相剝離法製備…………………………………………21 2.5.3 在碳化矽基板上成長……………………………………21 2.5.4 在金屬基板上析出成長…………………………………22 2.5.5 化學氣相沉積法製備……………………………………22 2.5.6 氧化石墨烯還原法製備…………………………………23 第三章 實驗方法與分析………………………………………………44 3.1 實驗材料………………………………………………………44 3.2 製程設備與材料分析儀器……………………………………44 3.2.1 高速離心機………………………………………...……44 3.2.2 超音波震盪機………………………………………...…45 3.2.3 真空電漿機………………...……………………………45 3.2.4 塗佈棒…………………….......…………………………45 3.2.5 場發射掃描式電子顯微鏡………………...……………46 3.2.6 X光繞射分析儀…………………………………………46 3.2.7 X光光電子能譜儀………………………………………46 3.2.8 紫外光/可見光分光光譜儀…………………...………...47 3.2.9 拉曼光譜儀…………………………………...…………47 3.3 實驗步驟及方法………………………………………………48 3.3.1 製備氧化石墨烯……………………………...…………48 3.3.2 單一製程製備奈米銀線/p型摻雜石墨烯複合導電溶液……………………………………….....………….….49 3.3.3 製備透明導電膜……………………………………...…50 第四章 結果與討論……………………………………………………54 4.1 氧化石墨烯之特性分析………………………………………55 4.1.1 表面形貌分析…………………………………………...55 4.1.2 X光繞射光譜分析………………………………………55 4.2 奈米銀線之特性分析…………………………………………56 4.2.1 表面形貌分析…………………………………………...56 4.2.2 X光繞射光譜分析………………………………………57 4.3 新型複合導電奈米材料之特性分析…………………………57 4.3.1 表面形貌分析…………………………………………...57 4.3.2 拉曼光譜分析…………………………………………...58 4.3.3 X光光電子能譜儀分析…………………………………59 4.4 透明導電膜特性分析…………………………………………60 4.4.1 透明導電膜之光電表現………………………………...60 4.4.2 透明導電膜之彎曲測試………………………………...61 4.4.3 透明導電膜之耐彎曲次數測試………………………...62 4.4.4 透明導電膜之附著力測試……………………………...63 4.4.5 新型複合導電奈米材料機制探討……………………...63 第五章 結論……………………………………………………………79 參考文獻………………………………………………………………..80

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