研究生: |
李賢學 Hsien-Hsuen Lee |
---|---|
論文名稱: |
化學還原法製備奈米銀及其應用 Chemical reduction of nano-sized Ag and its applications |
指導教授: |
周更生
Kan-Sen Chou |
口試委員: | |
學位類別: |
博士 Doctor |
系所名稱: |
工學院 - 化學工程學系 Department of Chemical Engineering |
論文出版年: | 2005 |
畢業學年度: | 93 |
語文別: | 中文 |
論文頁數: | 157 |
中文關鍵詞: | 奈米銀 、噴墨 、抗菌 、導電膠 |
外文關鍵詞: | nano-sized Ag, ink-jet, antibacteria, conductive adhesive |
相關次數: | 點閱:3 下載:0 |
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本研究利用化學還原法,以PVP (Polyvinylpyrrolidone)做為保護劑,在鹼性環境中以甲醛將銀離子還原為金屬銀。經由清洗程序,可將保護劑與反應副產物去除。在最佳條件下可獲得粒徑約為28nm,PVP殘留量5%的奈米銀。
奈米銀的第一項應用為高分子導電膠,當微米銀片在導電膠中的填充量接近而未達臨界體積分率時,奈米銀的添加將有助於導電率的提升。然而,當導電膠中微米銀片的填充量高於臨界體積分率時,額外添加的奈米銀將使得銀片與奈米銀之間的接觸面積變小,進而造成體積電阻值的上升。單純使用奈米銀與PVAc(Polyvinyl acetate)所構成的奈米銀膠,可藉由含水量調整其黏度,使其得以應用於噴塗、旋轉鍍膜等塗佈程序。
第二項應用將奈米銀以噴墨印刷方式,使用家用印表機(EPSON R210)在玻璃或PI(Polyimide)薄膜上製作出導電線路。奈米銀導線在噴墨印刷之後,經由低溫乾燥、260℃、10分鐘熱處理,可得體積電阻值5.6×10-6□-cm之銀導線。銀導線表面藉由電鍍銅的方式,可在銀導線表面生成厚度超過10□m的緻密電鍍銅,有助於降低電路的電阻。此製程可做為製作印刷電路板的替代方案,省去了昂貴的微影製程,可以快速而簡便的製造出多樣化的原型產品。
本文提及的最後一項應用是將奈米銀做為抗菌劑。經過奈米銀處理的JIS白棉布以美國紡織染化協會(American Association of Textile Chemists and Colorists, AATCC)之抗菌效力評估(定量)法AATCC-100之抗菌測試方法對金黃葡萄球菌進行抗菌測試,處理後含銀105.3ppm的JIS白棉布在測試實驗中將細菌完全殺滅。布樣經過20次水洗後仍舊保有71%的奈米銀,其抗菌效果分別為>99.99%及99.4%。實驗利用噴塗、乾燥、二次造粒、熔融抽絲的程序也將奈米銀均勻地分散到尼龍纖維中,其做為人造纖維添加劑使用,具有極大的潛力。
Nanosized Ag was synthesized by chemical reduction method with PVP (Polyvinylpyrrolidone) as the protective agent. The reduction reaction was carried out by formaldehyde in an alkaline environment. The PVP and the by-product could be removed after proper washing process. Under optimum condition, nano-Ag of 28nm having 5% residual PVP could be obtained.
The first application was to use nano-Ag to get polymeric conductive adhesives. Nano-Ag will improve the conductivity of the paste with silver flake filling close to the percolation threshold. However, when the silver flake content was above the percolation threshold, the addition of nano-Ag will increase the resistivity due to the smaller contact area between flakes and these nano-Ag powders. If the paste was made from nano-Ag and PVAc (Polyvinyl acetate) only, the viscosity can be easily adjusted by water content and therefore it can be coated by either airbrush or spin coating.
The second application was to use this nano-Ag in the ink-jet printing process to make conductive lines on both glass and polyimide film using a commercial printer (EPSON R210). Conducting Ag lines with a resistivity of 5.6×10-6□-cm could be obtained after soft baking followed by the heat treatment at 260℃ for 10 minutes. The electroplating of copper makes a dense deposition over 10 □m in thickness onto the silver lines that will reduce the resistance of the circuit. That could serve as an alternative method to make the printed circuit board (PCB), which avoids the tedious and expensive photolithography steps. One can make the prototype fast and easily.
The last application investigated here is as an antibacterial reagent that helps the cloth (JIS white cotton cloth) to kill off the Staphylococcus aureus during the AATCC-100 (American Association of Textile Chemists and Colorists) test. Cotton fabrics contain nano-Ag of 105.3ppm at the start still remains about 71% of the nano-Ag after water wash for 20 times. The antibacterial effect is >99.99% and 99.4% respectively. It was also demonstrated that these nano-Ag powder could be dispersed uniformly into Nylon fibers by a series of procedures of praying, drying, re-pelleting and spinning, and thus offers great potential as a functional additive to the synthetic fibers.
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