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研究生: 胡家榮
Hu, Chia-Jung
論文名稱: 烤箱與爐管退火修復氧化鋁薄膜製作鈍化N型太陽能電池
Passivated n-type Solar Cell with Aluminum Oxide Film Recovery by Oven and Furnace Annealing
指導教授: 王立康
Wang, Li-Karn
口試委員: 李明昌
Lee, Ming-Chang
陳昇暉
Chen, Sheng-Hui
學位類別: 碩士
Master
系所名稱: 電機資訊學院 - 光電工程研究所
Institute of Photonics Technologies
論文出版年: 2024
畢業學年度: 113
語文別: 中文
論文頁數: 55
中文關鍵詞: 太陽能電池製程氧化鋁薄膜
外文關鍵詞: Solar Cell, Aluminum Oxide Film, C-V test
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  •   本實驗室近期致力於研究N型太陽能電池,如何以最低成本製作高效的N型電池是我們一直想探討的議題,先前實驗室的學長有研究過沒有氧化鋁鈍化層的N型太陽能電池,而我們則是想要在其架構上增添一層氧化鋁鈍化層,觀察效率上的影響。

      首先,我們使用N型矽基板來製作,先以電子束蒸鍍機蒸鍍一層鋁金屬薄膜,再利用爐管通氧來氧化形成氧化鋁薄膜,隨後分別用爐管與烤箱進行退火。實驗結果是爐管退火的效率最佳,最高可以達到12.99%,與先前學長沒有氧化鋁鈍化層的研究相比高1%左右,而通過烤箱退火後的晶片薄膜品質不佳,導致效率相較於爐管退火的低0.5~1%,推測原因是烤箱打開的過程中,溫度不可控制,以及烤箱不能通入任何氣體,導致退火的過程中會有雜質的產生,影響薄膜的品質。比較退火後的氧化鋁薄膜質量後,取較佳的那組,再觀察正面SiNx厚度所造成的影響,SiNx 92nm的效率相較於SiNx 100nm的較低,推測是氮化矽的厚度會影響到其中氫氣的含量,然而氮化矽的氫能夠降低表面的缺陷。


      Our laboratory has recently been committed to researching N-type solar cells. How to make high-efficiency N-type solar cells at the lowest cost is a topic we have always wanted to discuss. Previously, senior students in the laboratory have studied N-type solar cells without a passivation layer, and we want to add a passivation layer to its structure and observe the impact on efficiency.

      First, we use an N-type silicon substrate to make it. First, we use an electron beam evaporation machine to evaporate a layer of aluminum metal film, and then use the furnace tube to pass oxygen to oxidize it to form an aluminum oxide film, and then use the furnace tube and oven to anneal. The experimental result is that furnace tube annealing has the best efficiency, which can reach up to 12.99%. However, the quality of the wafer film after oven annealing is poor, resulting in an efficiency that is 0.5~1% lower than that of furnace tube annealing. It is speculated that the reason is that the oven is turned on. During the process, the temperature cannot be controlled, and no gas can be passed into the oven, resulting in the production of impurities during the annealing process, which affects the quality of the film. After comparing the quality of the annealed aluminum oxide films, select the better group and then observe the impact of the front SiNx thickness. The efficiency of SiNx 92nm is lower than that of SiNx 100nm. It is speculated that the thickness of silicon nitride will affect The hydrogen content in silicon nitride can reduce surface defects.

    目錄 第1章 導論 1 1.1 前言 1 1.2文獻回顧 1 1.2.1 太陽能電池發展 1 1.2.2 N型太陽能電池 2 1.2.3 鈍化層的選擇 5 1.2.4 氧化鋁的製備 5 1.3研究目的與動機 6 1.4論文架構 6 第2章 太陽能電池基礎原理 7 2.1 太陽能電池基本原理 7 2.2 太陽能電池等效電路 8 2.3 太陽能電池特性參數 10 2.4 鈍化層氧化鋁的基本原理 12 2.5 C-V量測 13 第3章 研究方法與規劃 16 3.1 實驗架構 16 3.2 儀器介紹 17 3.3 實驗步驟 23 3.3.1 RCA Clean 24 3.3.2 硼離子佈植(Boron Implantation) 25 3.3.3 硼退火(Boron Annealing) 26 3.3.4 磷離子佈植(Phosphorous Implantation) 26 3.3.5 磷退火(Phosphorous Annealing) 26 3.3.6 E-gun鋁膜製程 27 3.3.7 氧化(Oxidation)與爐管、烤箱退火 27 3.3.8 氮化矽保護層(SiNx) 28 3.3.9 網印電極(Screen Printing)&共燒結(Co-firing) 28 第4章 實驗數據討論 30 4.1 元件轉換效率量測 30 4.2 Suns-Voc量測 32 4.3 TEM量測 33 4.4 C-V量測 36 第5章 總結 38 附錄 40 參考文獻 51

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