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研究生: 陳立穎
Chen, Li-Ying
論文名稱: 開發用於水果成熟度檢測的電子鼻系統
Development of an Electronic-Nose System for Fruit Maturity Detection
指導教授: 鄭桂忠
Tang, Kea-Tiong
口試委員: 劉奕汶
Liu, Yi-Wen
吳財福
Wu, Tsai-Fu
學位類別: 碩士
Master
系所名稱: 電機資訊學院 - 電機工程學系
Department of Electrical Engineering
論文出版年: 2018
畢業學年度: 107
語文別: 中文
論文頁數: 70
中文關鍵詞: 電子鼻揮發性有機化合物水果氣味成熟度氣相層析質譜分析儀
外文關鍵詞: Electronic nose, volatile organic compounds, fruit odor, maturity, TD-GC-MS
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  • 本研究首先會利用熱脫附儀氣相層析質譜儀(TD-GC-MS)聯用系統,針對不同成熟階段的水果進行氣味分析,證明透過TD-GC-MS系統可以分析不同階段間的氣體種類差異。在獲得目標氣體後,我們利用金屬氧化物半導體氣體感測器陣列開發出一種高靈敏度的電子鼻系統(E-nose),用於識別水果果實的成熟度。
    在本論文中,我們開發出一套電子鼻系統,該系統具有作為非破壞性系統的潛力,用於監測在成熟過程中由水果產生的揮發性有機化合物的變化。除了此電子鼻系統,我們還額外提出了一個相機系統來監控水果的果皮顏色,作為識別的另一個特徵。 透過將電子鼻和相機系統結合在一起,我們提出了一種用於水果成熟度監測的非破壞性解決方案。雙電子鼻/相機系統提供了最佳的可分性測量,並顯示了水果四個成熟階段的完美分類:未成熟、半成熟、完全成熟和過熟。
    為了降低演算法運算複雜度,我們使用主要成分分析和線性判別方法來降低數據資料的維度,也利於後續觀察資料的分佈情況,而辨識方法則使用了最近K個鄰居法和支持向量機進行分類器準確率的評估。最初單一電子鼻系統辨識結果約達到平均80多%左右,隨後加入了外表顏色變化的特徵後,會達到更佳的分群效果,最終辨識準確率可以達到100%。


    In this research, thermal desorption tendon with gas chromatography-mass spectrum (GC-MS) system has been used to find the target of volatile organic compounds (VOCs) in fruit with different maturity. After getting the target gas, we utilize Metal Oxide Semiconductor (MOS) gas sensor arrays to develop a highly sensitive electronic nose system (E-nose) for identifying maturity of fruit .
    In this thesis, we propose an E-nose system that has potential as a non-destructive system for monitoring variation in the volatile organic compounds produced by fruit during the maturing process. In addition to the E-nose system, we also propose a camera system to monitor the peel color of fruit as another feature for identification. By incorporating E-nose and camera systems together, we propose a non-destructive solution for fruit maturity monitoring. The dual E-nose/camera system presents the best class separability measure and shows a perfect classification of the four maturity stages of banana: Unripe, half-ripe, fully ripe, and overripe.
    This study proposes a dual E-nose/camera system that utilizes both smell and vision information for improving fruit ripeness classification. This non-destructive system aims to monitor fruit maturity and provide better accuracy in identifying fruit ripeness stages. In order to reduce the complexity of algorithm operations, the principal component analysis (PCA) and linear discriminant (LDA) methods were used to reduce the dimension of data and visualize the distribution of the data. We used the nearest K-neighbor method (KNN) and support vector machine (SVM) classification with leave-one-out cross validation. The initial accuracy was about 80%. After adding the color feature, the result showed that this method yielded better classification and the accuracy achieve up to 100% in classifying fruit maturity.

    目錄 摘要 i Abstract ii 圖目錄 vii 表目錄 x 第1章 緒論 11 1.1 研究背景 11 1.2 氣體感測系統基本架構 11 1.3 研究動機與目的 13 第2章 文獻回顧 15 2.1氣體檢測相關文獻 15 2.2水果成熟度判斷相關文獻 16 第3章 熱脫附儀氣相層析質譜儀聯用系統 17 3.1 基本原理與架構 17 3.1.1 熱脫附儀 18 3.1.2 氣相層析質譜儀 19 3.2 實驗流程與分析方法 19 3.2.1 樣品採樣 20 3.2.2 樣品萃取 21 3.2.3 數據分析 24 3.2.3.1滯留時間 24 3.2.3.2訊號峰高度 25 3.2.3.3訊號峰面積 25 第4章 實驗系統架構 27 4.1整體系統架構 27 4.1.1信號讀取系統 28 4.1.1.1 氣體感測設備 28 4.1.1.2 顏色量測設備 33 4.2實驗環境與系統架設 34 4.2.1 實驗樣品與氣室 34 4.2.2 實驗流程與步驟 36 第5章 數據分析與演算法開法 38 5.1 訊號前處理 39 5.2 特徵擷取 39 5.2.1 差分法(Difference) 40 5.2.2 相對差異法(Relative difference) 40 5.2.3 分數差異法(Fractional difference) 41 5.3 正規化 42 5.4 降維演算法 43 5.4.1 主要成分分析(Principal Component Analysis, PCA) 44 5.4.2 線性判別分析(Linear Discriminant Analysis, LDA) 46 5.5分類演算法 48 5.5.1 K個最近鄰居判別(K-Nearest Neighbor, KNN) 48 5.5.2 支持向量機(Support Vector Machine, SVM) 49 5.6 交叉驗證方法 52 第6章 實驗結果與討論 53 6.1實驗結果 53 6.1.1 TD-GC-MS檢測結果 54 6.1.2數據分佈與結果 57 6.2 綜合分析結果 63 6.2.1 類別離散度評估 63 6.2.2 分類辨識率結果 65 第7章 結論 66 7.1 總結 66 7.2 未來工作 67 參考文獻 68

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