研究生: |
陳建男 Chen, Jian Nan |
---|---|
論文名稱: |
微型化可攜式氨氣感測系統 The miniaturized portable ammonia sensing system |
指導教授: |
洪勝富
Horng, Sheng Fu |
口試委員: |
冉曉雯
Zan, Hsiao Wen 呂家榮 Lu, Chia Jung 孟心飛 Meng, Hsin Fei |
學位類別: |
碩士 Master |
系所名稱: |
電機資訊學院 - 電子工程研究所 Institute of Electronics Engineering |
論文出版年: | 2015 |
畢業學年度: | 103 |
語文別: | 中文 |
論文頁數: | 74 |
中文關鍵詞: | 氨氣感測 、呼氣氨 、即時性感測 、非侵入式 |
相關次數: | 點閱:4 下載:0 |
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本篇論文利用Poly(3-octylthiophene-2,5-diyl)並搭配刮刀塗佈聚苯乙烯奈米球(Nano-sized polystyrene sphere)技術製作高孔洞密度垂直式二極體元件,藉由偵測通過氨氣氣體造成的電流變化得知氨氣的濃度,並且擁有製程成本低廉、即時偵測、高靈敏度、非侵入式等優勢。並且著手將整體感測系統微小化,通過各種實驗測試排除人體呼氣水氣,找出合適的氣體採集方式提供呼氣感測另外該方法必須能穩定度的量測,並且系統能夠偵測到100 ppb氨氣濃度,而在本篇論文中也提到利用許多不同量測方法來簡化量測系統減少系統成本,另外可搭配微處理器模組來運算感測元件電壓降變化,取代量測機組使感測系統成為可攜式即時量測設備。
We use Poly (3-octylthiophene-2,5-diyl) to serve as sensing material and producing a high porous density vertical diode by blade coating process to detect ammonia. The ammonia gas sensor in air background sensing system can detect the ammonia concentration from 100 part per billion (ppb) to 1 part per million (ppm) with good resolution. Besides, we try many ways to enhance the sensing system’s reliability. For example, utilizing the gastight syringe to avoid the electric signal noise during gas injection. And we also investigate how to collect human breath properly, thus sensing system can detect breath-ammonia without disturbing by the high humidity in breath or the variation of background flow. In addition, high-end measurement instrument is replaced by a microprocessor, which computes ammonia sensor’s voltage signal to identify the ammonia concentration to miniaturize sensing system. The miniaturized portable ammonia sensing system has many advantages such as non-invasive sensing, real-time sensing, low-cost and room temperature operation.
1. Pijnenburg, M.W.H. and J.C. De Jongste, Exhaled nitric oxide in childhood asthma: a review. Clinical & Experimental Allergy, 2008. 38(2): p. 246-259.
2. Righettoni, M., A. Tricoli, and S.E. Pratsinis, Si:WO3 Sensors for Highly Selective Detection of Acetone for Easy Diagnosis of Diabetes by Breath Analysis. Analytical Chemistry, 2010. 82(9): p. 3581-3587.
3. Endre, Z.H., et al., Breath ammonia and trimethylamine allow real-time monitoring of haemodialysis efficacy. Physiological Measurement, 2011. 32(1): p. 115.
4. Kearney, D., T. Hubbard, and D. Putnam, Breath Ammonia Measurement in Helicobacter pylori Infection. Digestive Diseases and Sciences, 2002. 47(11): p. 2523-2530.
5. Adrover, R., et al., Breath-Ammonia Testing of Healthy Subjects and Patients with Cirrhosis. Digestive Diseases and Sciences, 2012. 57(1): p. 189-195.
6. Hibbard, T., et al., Point of Care Monitoring of Hemodialysis Patients with a Breath Ammonia Measurement Device Based on Printed Polyaniline Nanoparticle Sensors. Analytical Chemistry, 2013. 85(24): p. 12158-12165.
7. Risby, T.H. and S.F. Solga, Current status of clinical breath analysis. Applied Physics B, 2006. 85(2-3): p. 421-426.
8. Timmer, B., W. Olthuis, and A.v.d. Berg, Ammonia sensors and their applications—a review. Sensors and Actuators B: Chemical, 2005. 107(2): p. 666-677.
9. Greenspan, L., Humidity fixed points of binary saturated aqueous solutions. Journal of Research of the National Bureau of Standards, 1977. 81(1): p. 89-96.
10. Khajavi, S., F. Kapteijn, and J. Jansen, Separation Based on Molecular Level Using Zeolitic Membranes. Diffusion Fundamentals, 2005. 3: p. 22.1-22.2.
11. Toshiba Develops Breath Analyzer for Medical Applications