研究生: |
曾靖淵 |
---|---|
論文名稱: |
添加微粒對淋幕式塗佈行為的影響 |
指導教授: |
汪上曉
劉大佼 |
口試委員: | |
學位類別: |
碩士 Master |
系所名稱: |
工學院 - 化學工程學系 Department of Chemical Engineering |
論文出版年: | 2007 |
畢業學年度: | 96 |
語文別: | 中文 |
中文關鍵詞: | 塗佈 、淋幕 、微粒 、空氣滲入 |
相關次數: | 點閱:2 下載:0 |
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工業上的塗佈產品多為懸浮液流體,而本實驗以淋幕式塗佈為研究系統,探討溶液中添加顆粒對其塗佈行為的影響。在淋幕式塗佈實驗中,主要的塗佈缺陷為踵形(heel)及空氣滲入(air entrainment),其中塗佈速度上限空氣滲入的發生受到流體物性及邊桿高度影響。實驗流體分成甘油水溶液與甘油加入聚甲基丙烯酸甲酯(PMMA)顆粒之懸浮液兩個部份來討論。
關於甘油水溶液相關的研究發現到當流體黏度越小或表面張力越大,可使塗液承受較高剪切形變量(shear rate)時仍能維持穩定,所以塗佈速度較快。在淋幕式塗佈實驗中,固定流量下提高淋幕落下的距離會抑制空氣滲入的發生使塗佈速度增快。
在懸浮液的研究發現,添加顆粒會使流體的塗佈視窗擴大,最小成膜流量降低,由於塗佈時顆粒隨淋幕落下擠壓氣液交界面,使動態濕潤線往上游移動,延遲空氣滲入的發生,使流場在更高的塗佈速度也可以穩定,而塗佈速度的增加量和加入顆粒的數量密度有關,當數量密度達到最佳值時塗佈速度增加最大,且不論流體的黏度、表面張力改變或淋幕落下的高度變化,顆粒使空氣滲入延後的現象都會發生。
柒:參考文獻
7-1英文文獻
1. Brown, D.R.,’’A Study of the Behavior of thin sheet of Moving Liquid ’’, J. Fluid Mech., 10,297-303 (1961)
2. Burley, R. and Kennedy B. S., 1976, “An Experimental Study of Air Entrainment at a Solid-Liquid-Gas Interface”, Chem. Eng. Sci. 31, 901
3. Burley, R. and Jolly R. P. S., 1983, “Entrainment of air into liquids by a high speed continuous solid surface”, Chem. Eng. Sci 39 (9) 1357-1372
4. Bolton, B., and Middleman S., ”Air Entrainment in a Roll Coating System,” Chem. Eng. Sci., 35, 597 (1980)
5. Blake, T. D., Clarke A. and Ruschak K. J., 1994, “Hydrodynamic Assist of Dynamic Wetting”, AIChE J. 40, 229-242
6. Boisvert, J. P., Persello J. and Guyard A., 2003, “Influence of the Surface Chemistry on the Structural and Mechanical Properties of Silica-Polymer Composites”, J. of Polymer Science 41, 3127-3138
7. Blake, T. D., Dobson R. A. and Ruschak K. J., 2004, “Wetting at high capillary numbers”, J. of Colloid and Interface Science 279, 198-205
8. Cohen, E. D. and Gutoff E. B., 1992, “Modern Coating and Drying Technology”, VCH Publishers, New York
9. Cohen, E. D. and Gutoff E. B., 1995, “Coating and Drying Defects”, Wiley Interscience, New York
10. Chibowski, 2001, “Studies of the Influence of Acetate Groups from Polyvinyl Alcohol on Adsorption and Electrochemical Properties of the TiO2-Polymer Solution Interface”, J. of Dispersion Science and Technology 22, 281-289
11. Derjaguin B. V. and Laudau L. Acta Physicochim. USSR 1941, 14: 633~662
12. Eistein, A.,’’A New determination of the molecular dimension’’, Ann. Physik.,19,289-306 (1906)
13. Gutoff, E. B. and Kendrick C. E., 1987, “Low Flow Limits of Coating on A Slide Coater”, AIChE J. 33, 141.
14. Guegan Q. http://arxiv.org/ftp/physics/papers/0607/0607158.pdf
15. Hughes, D.J.,” Method for Simultaneously Applying a Plurality of Coated Layers by Forming a Stable Multilayer Free-Falling Vertical Curtain”, USP 3,508,947(1970)
16. Higgins, B. G. and Scriven L. E., “Capillary Pressure and Viscous Pressure Drop Set Bounds on Coating Bead Operability,” Chem. Eng. Sci. 35, 673 (1980).
17. Kistler, S. F. and Schweizer P. M., eds., 1997, “Liquid Film Coating”, Chapman & Hall, London
18. Kistler, S. F. and Scriven L. E., “Coating Flow Theory By Finite Element and Asymptotic Analysis of The Navier-Stokes System”, International J. For Numerical Methods in Fluids 4, 207-229 (1984)
19. LaMer W. K., Healy T. W. Rev. Pure Appl. Chem., 1963, 13: 112~133
20. Lin, S.P.,’’Stability of a Viscosity Liquid Curtain’’, J. Fluid Mech., 104,111-118 (1981)
21. Mooney, M., ’’The viscosity of a concentrated suspension of spherical particles ’’,J. Colloid Sci. 6,162-170 (1951)
22. M. Yamamura, H. Miura, and H. Kage, 2005, “Postponed Air Entrainment in Dilute Suspension Coatings”, AIChE J, 51, 2171-2177
23. M. Yamamura, A. Matsunaga, Y. Mawatari, K. Adachi, H. Kage “Particle-assisted dynamic wetting in a suspension liquid jet impinged onto a moving solid at different flow rates” Chem. Eng. Sci., 61 (2006), 5421-5426.
24. Perry, R. T., “Fluid Mechanics of Entrainment Through Liquid- Liquid and Liquid-Solid Junction ”,Ph.D. Thesis, Chem. Eng., U. of Michigan, 1996; University Microfilms, 76-14, 639 (1967).
25. Ruschak, K.J. (1979), “Limiting Flow in A Pre-metered Coating Device,” Chem. Eng. Sci., 31, 1057.
26. Reiter T.C.,’’Curtain coating method and apparatus”, USP 4,830,887 (1989)
27. Shima, R., ’’A Treatment of the viscosity of concentrated suspensions’’,Journal of Applied Physics, 23,1020-1024 (1992)
28. Swedish Ceramic Institute (2003) http://www.keram.se/eng/pdf
/surface_chemistry.pdf
29. Verwey E. J. and Overbeek J. Th. G. , ”Theory of Stability of Lyophobic Colloids”. Elsevier, Amsterdam, 1948
7-2中文文獻
1. 楊佳瑋(2006)”添加微粒對預調式塗佈視窗之影響”,國立清華大學化學工程博士論文。
2. 高濂 孫靜 劉陽橋(2005)”奈米粉體的分散及表面改性”,五南文化事業機構。