利用赤鐵礦改質之微濾膜移除模擬電廠廢水中之鈷核種之研究

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研究生：	李政憲 Lee, Cheng Hsien
論文名稱：	利用赤鐵礦改質之微濾膜移除模擬電廠廢水中之鈷核種之研究 REMOVAL OF COBALT NUCLIDES FROM SIMULATED NUCLEAR LIQUID WASTEWATER USING HEMATITE MODIFIED ULTRAFILTRATION MEMBRANES
指導教授：	王竹方 Wang, Chu Fung
口試委員:	蔣本基 Chiang, Pen Chi 談駿嵩 Tan, Chung Sung 王潔 Wang, Jane
學位類別：	碩士 Master
系所名稱：	原子科學院 - 核子工程與科學研究所 Nuclear Engineering and Science
論文出版年：	2016
畢業學年度：	104
語文別：	英文
論文頁數：	77
中文關鍵詞：	微濾膜、黏滯度、Poiseuille Equation 、Gibbs-Donnan effect 、表面改質
外文關鍵詞：	ultrafiltration membrane, viscosity, Poiseuille Equation, Gibbs-Donnan effect, surface modification
相關次數：	點閱：2 下載：0
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微濾膜本身無法過濾離子等級的粒子，但是經由改質後可以有幾乎同等於奈濾膜的過濾效果。鑒於他人已發表的研究，我們知道薄膜的表面改質會在不同的情況下對水中離子產生單純吸附、斥力、吸引力三種影響，我們用在不同pH值改質的膜在不同pH值的含鈷溶液下做過濾，藉以了解他的通量、去除率。爾後我們使用Poiseuille Equation獲得各種不同pH值的含鈷溶液其黏滯度，藉以觀察電誘發的黏滯度對通量及去除率的影響。我們也使用BET及LA-ICP-MS的深度剖析來觀察改質後的孔徑大小及薄膜過濾之後鈷離子在膜上的吸附情形，最後我們研究綜合以上情形去了解電誘發的黏滯度及孔徑的大小與通量、去除率、黏滯度彼此之間的關係。

Ultrafiltration membrane can’t filtrate particles of ion level, but after modification it can reach the ability of rejection as high as the nanofiltration membrane. In view of the research publish by others I know there are three kind of effect will occur and had action to the ion in the solution when modifying membrane in different situation, respectively absorption, attractive force and repulsion. I use membrane modified in different pH and use different pH solution which has Co2+ to conduct our experiments by realizing the permeate flux and rejection. Later, I adopt Poiseuille Equation to gain the viscosities of different pH solution including Co2+ and furthermore to observe the effect of permeate flux and rejection caused by electroviscous with this equation. I also conduct BET and LA-ICP-MS depth profile to understand the pore size and the Co2+ absorption situation of membrane surface after filtration. Overall, our research base on the above to establish the relationships between electroviscous, pore size and permeate flux, rejection, viscosity.

中文摘要        i
Abstract        ii
謝誌        iii
Content              iv
Table Index      vi
Figure Index    vii
Chapter  1    Introduction    1
Chapter  2    Literature Review    4
1    Membrane Technology    4
1.1    Classification of Membranes    4
1.2    Materials of Membranes    5
2    Operation Mode    8
Figure 2.2    Mechanism of cross-flow filtration.    9
3    Theory of Solute Transport in Porous Media: Poiseuille Equation    10
4    Electrokinetic Effect: Gibbs-Donnan Effect    11
5    Zeta potential    13
6    Brunauer, Emmett and Teller (BET) Theory    15
7    Principle and Application of LA-ICP-MS    18
7.1.    Mapping Images by Using LA-ICP-MS    18
7.2.    Depth Profile Analysis of LA-ICP-MS    20
Chapter  3    Experiment    24
1    Chemical Reagents and Materials    24
2    Instruments    25
2.1    Scanning Electron Microscopy (SEM)    25
2.2    Inductively Coupled Plasma-Mass Spectrometer (ICP-MS)    26
2.3    LA-ICP-MS    28
2.4    pH Meter    30
3    Experimental Procedures    33
3.1    Preparation of Hematite Suspensions and Co2+ Stock Solution    33
3.2    Membrane Modification    33
3.3    Performance Evaluation under the Cross Flow Mode    33
3.4    Approximation in Poiseuille Equation    34
Chapter  4    Results and Discussions    36
1    Permeate Flux and Rejection by Modified Membranes    36
1.1    Permeation Flux and Rejection at pH4    36
1.2    Permeation Flux and Rejection at pH 7    39
1.3    Permeation Flux and Rejection at pH10    42
2    Pore Size and Pore Volume Determination    45
3    Zeta Potential and Viscosity of Hematite Suspensions    47
4    Surface Texture of Modified Membranes    50
5    Quantitative Interpretation of Permeate Fluxes by Modified Membranes    52
5.1    Permeation Flux Collected at pH4    52
5.2    Permeation Flux Collected at pH 7    54
5.3    Permeation Flux Collected at pH 10    56
6    Calculated Viscosity under Different Conditions    58
7    Depth Profile Analysis of Modified Membranes    59
Chapter  5    Conclusions and Future Work    65
1    Conclusions    65
2    Future Work    67
References    68




                                

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