過去十年來，本實驗室著重的研究項目為有機發光二極體以及不對稱催化與合成反應，皆有不錯的成果。最近幾年，近期本實驗室希望結合有機發光二極體以及不對稱催化之經驗進行新研究系統開發。
本次研究中我們以鈀金屬鹽類與我們開發的氮雜二苯環庚烯酮衍生之磺醯胺手性配體生成新型鈀 (II) 錯合物，並另用此手性錯合物作為催化劑，在氬氣與 50 ºC 下以無水甲苯為溶劑，二(三甲基矽基)醯胺 (N,O-Bis(trimethylsilyl)acetamide, BSA) 為鹼，進行 Trost 不對稱烯丙位烷化反應 (Trost asymmetric allylic alkylation, AAA)。產率介於 46%–93%，鏡像選擇性介於 30%–55%。並以分子模擬推測產物之手性中心構型形成過程。

Over the past decade, the research projects in this laboratory have been focused on organic light-emitting diodes and asymmetric catalysis and synthesis reactions. In recent years, we hope to develop new research systems based on the integrated experience of organic light-emitting diodes and asymmetric catalysis.
In this study, we generated new palladium (II) complexes from the palladium metal salts and the azadiphenyl cycloheptenone-derived chiral sulfinamide ligands we developed, and used the chiral complexes as a catalyst, Trost asymmetrical allylation was eamined with anhydrous toluene as a solvent and N,O-Bis(trimethylsilyl)acetamide (BSA) as a base under argon at 50 ºC. Asymmetric allylic alkylation (AAA) led to the products with yields between 46%–93% and enantioselectivity between 30%–55%.Molecular simulation was carried out to gain some insight into the origin of enantioselectivity.

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