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研究生： 朱永祺
Chu, Yung Chi
論文名稱： 玻璃轉換溫度以下奈米碳管/環氧樹脂介面增強阻尼性質:可程式化電控高強度阻尼
Carbon nanotube-epoxy interface improved damping below glass transition temperature：programmable controlled high strength damper
指導教授： 徐文光
Hsu, Wen Kuang
口試委員: 郭信良
Kuo, Hsin Liang
呂昇益
Lu, Sheng Yi
許景棟
Hsu, Ching Tung
溫華強
Wen, Hua Chiang
學位類別： 博士
Doctor
系所名稱： 工學院 - 材料科學工程學系
Materials Science and Engineering
論文出版年： 2016
畢業學年度： 104
語文別： 英文
論文頁數： 82
中文關鍵詞： 奈米碳管 、複合材料 、分子動力學
外文關鍵詞： carbon nanotubes, composites, molecular dynamics
相關次數： 點閱：4  下載：0 
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    • 由奈米碳管、環氧樹脂與玻璃纖維組成的可程式化電控相轉變之高強度複合材料。可藉由加入奈米碳管以控制在玻璃轉換溫度時的吸收能量能力，藉由施加電壓將剛性複合材料變更為阻尼器與橡膠，達到快速吸震效果。並在加入玻璃纖維作為強化材料後，測試其阻尼特性以及玻璃轉換溫度改變。阻尼係數經量測為0.1，並可在約6秒內達到最大吸震能力。本文探討加入奈米碳管後，環氧樹脂與奈米碳管間的介面效應，並藉由實際模擬測試探討實際應用方向。人造衛星及太陽能板因機械構造產生的自然震動或是飛機與風力發電葉片因亂流與風阻產生的間歇性震動等均可使用此複合才達到快速吸震。亦可應用於房屋與橋梁之防震，藉由此材料破壞共振頻率，降低損失與意外發生機率。

    Composites made from fibers and epoxy display a low viscous drag and are barely used as mechanical damper at room temperature. Incorporation of carbon nanotubes into epoxy promotes interfaces that govern damping mechanism in the vicinity of glass transition temperature. Damping character remains unchanged as glass fibers are also present in composites and damping coefficient is measured to be 0.1.

    Contents 摘要 Abstract II 致謝 III Contents IV Chapter 1 introduction 1 1-1 Carbon nanotubes 1 1-1-1 Introduction of carbon nanotubes 1 1-1-2 Structure of carbon nanotubes 2 1-1-3 Electronic properties of Carbon Nanotubes 7 1-1-4 Mechanical property of carbon nanotubes 13 1-1-5 Syntheses of Carbon Nanotubes 14 1-2 Epoxy 17 1-2-1 Introduction of Epoxy 17 1-2-2 The classification of epoxy 21 1-3 Introduction of glass fiber 23 1-4 Introduction of Ultimate tensile strength (UTS) test 25 1-5 introduction of Dynamic mechanical analysis (DMA) test 29 1-6 Ab initio DFT calculation 33 1-7 Characterization instrument 34 Chapter 2 38 Motivation 38 2-1 Introduction of the damper 38 2-2 Innovative damper 40 Chapter 3 41 Experimental section 41 3-1 Synthesis of MWCNTs 41 3-2 Production of MWCNTs /Epoxy /GFs composites 43 Chapter 4 45 Results and Discussion 45 4-1 Characterization of MWCNTs 45 4.2 Characterization of Carbon Nanotubes-Epoxy Composites 48 4.3 Electrically Controlled Glass Transition 55 4.4 CNTs/GFs Reinforced Epoxy Composites 58 4.5 Origin of damping and rubbery phase 61 4-6 Simulation 67 4-7 Use of composites as passive dampers 69 Chapter 5 71 Conclusion 71 Chapter 6 Reference 72

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