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研究生: 楊佳偉
論文名稱: 添加微粒對預調式塗佈視窗之影響
指導教授: 劉大佼
口試委員:
學位類別: 碩士
Master
系所名稱: 工學院 - 化學工程學系
Department of Chemical Engineering
論文出版年: 2006
畢業學年度: 94
語文別: 中文
論文頁數: 94
中文關鍵詞: 塗佈微粒
相關次數: 點閱:3下載:0
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  • 在過去塗佈研究中多半是以高分子溶液進行研究,對含有微粒的懸浮液的塗佈技術研究甚少,目前在工業界中有愈來愈多含有微粒的懸浮液的塗佈產品,如背噴光擴散燈箱片(light diffusing backlit film)、抗炫膜(Anti-glare film)、鋰電池(Lithium battery)、燃料電池(fuel cell)和偏光膜等。本研究利用聚乙烯醇 (PVA)和甘油當作基本流體,該流體除了是水溶性、無毒,易於實驗進行的優點外,更重要的是它已經被廣泛的應用在工業材料上,同時本研究利用數種不同微粒如二氧化鈦加入聚乙烯醇和PMMA加入甘油,形成分散良好的懸浮液,並針對加入微粒後的流體所呈現的物性與塗佈行為進行研究。
    由我們的實驗,可得知不論是二氧化鈦加入聚乙烯醇系統的狹縫式塗佈或是PMMA加入甘油系統的淋幕式塗佈,微粒的添加均有助於塗佈視窗變大,我們藉由添加不同的粒徑和不同的濃度的粉體當作變因,觀察出對於塗佈視窗有著不同的差異。改變酸鹼環境下,由於懸浮液系統吸附量的改變,也會對懸浮液的穩定性造成影響。
    而上述研究的主題,對於將來運用在一些工業上的產品,均有參考價值,也是我們本次研究最主要的動機和目的。


    目錄 謝誌 II 摘要 III 目錄 IV 圖目錄 VI 表目錄 VIII 壹、緒論 1 1-1工業上常用的塗佈方式 2 1-2狹縫式塗佈 5 1-3淋幕式塗佈 8 貳、文獻回顧 10 2-1 狹縫式塗佈工程(slot coating) 10 2-2 淋幕式塗佈工程(curtain coating) 12 2-3 流體與微粒之間的關係 15 參、實驗方法 17 3-1 分析儀器 17 3-2 藥品 25 3-3 實驗步驟 31 3-4 測量方法之建立 39 3-5 吸附量測量 42 肆、研究方法 44 4-1 聚乙烯醇添加無機粉體二氧化鈦系統 44 4-2甘油添加有機粉體PMMA系統 45 伍、結果與討論 46 5-1 聚乙烯醇添加無機粉體二氧化鈦對狹縫式塗佈的影響 46 5-1-1添加二氧化鈦粉體對塗佈視窗的影響 46 5-1-2表面張力效應 49 5-1-3黏度效應 51 5-1-4 酸鹼值對塗佈視窗的影響 54 5-1-5 不同酸鹼度之下的流變行為 56 5-1-6 不同酸鹼度之下吸附量的測量 58 5-1-7 Zeta potential實驗 60 5-1-8 二氧化鈦懸浮液pH=8和pH=9之塗佈視窗實驗 62 5-2甘油添加有機粉體PMMA對淋幕式塗佈的影響 64 5-2-1 PMMA粒徑對甘油塗佈視窗的影響 64 5-2-2 PMMA濃度對甘油塗佈視窗的影響 68 5-2-3 流體物性分析 72 5-2-4 預測模型(最適化黏度和最適化粒徑) 77 5-3 比較聚乙烯醇系統與甘油系統之塗佈缺陷 80 5-3-1 聚乙烯醇系統之狹縫式塗佈常見缺陷 80 5-3-2 甘油系統之淋幕式塗佈常見缺陷 84 5-4 結果與討論 89 陸、參考文獻 91

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