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研究生: 游舜名
論文名稱: 自組裝單分子膜輔助SU8-2035負型光阻與玻璃基材間黏著力提升的設計與測試
Adhesion Improvement between SU8-2035 Resist and Glass Substrate by Self-Assembly Monolayers (SAMs)
指導教授: 曾繁根
Fan-Gang Tseng
錢景常
Ching-Chang Chieng
口試委員:
學位類別: 碩士
Master
系所名稱: 原子科學院 - 工程與系統科學系
Department of Engineering and System Science
論文出版年: 2005
畢業學年度: 93
語文別: 中文
論文頁數: 90
中文關鍵詞: 黏著力自組裝單分子膜表面刮痕測試
外文關鍵詞: SU8, Adhesion, Self-Assembly Monolayers, Scratch Tests
相關次數: 點閱:3下載:0
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  • 本研究宗旨在於發展利用自組裝單分子膜來增進SU-82035負型光阻與玻璃基材之間的黏著力,以期能達成能抵抗物理性或化學性的破壞,擴大SU-8 2035在微機電系統中應用的空間,提升微機電系統元件製程良率的目標。高分子材料與基材表面的黏著力向來是應用上的一大問題,因此如何有效的改善,並穩定的控制表面特性來達到控制黏著力的目的,便成了很重要的課題。自組裝單分子的特色是,製程簡單、製程後表面特性穩定、時效長、不易被破壞等優點,近年來已被廣泛的研究。
    本研究提出,成功的利用自組裝單分子膜來增進SU-8 2035與玻璃基材之間的黏著力,並且比較利用表面粗糙度、電漿處理、化學蝕刻等方式來提升SU-8 2035與玻璃基材間的黏著力,發現自組裝單分子膜所得到的黏著力提升的效果要大於其他方式所得,並且再透過對自組裝單分子膜進行退火處理,使其重新排列整理後,效果更益明顯,提高黏著力達4倍有餘,由此可知自組裝單分子膜的優劣影響黏著力甚巨,因此要更提升黏著力,則必須再對自組裝單分子做更詳細的研究,此外如何提高SU-8 2035與基材之間鍵結反應的效率,亦是相當重要的關鍵之一。本研究量測基於表面微刮痕測試(micro-scratch tests),能於定性上提供黏著力優劣的比較,再結合原子力顯微鏡和表面動態分析儀,對自組裝單分子膜進行特性研究,並實際運用自組裝單分子膜於SU-8製作微小結構之測試與觀察。


    目錄 Ⅰ 圖目錄 Ⅲ 表目錄 Ⅶ 一、 緒論 1 二、 表面黏著 5 2.1 黏著力原理 5 2.1.1 機械性介面固定 6 2.1.2 擴散理論 7 2.1.3 吸附理論 8 2.2 文獻回顧與探討 17 2.3 SU-8 2035 之內應力 28 三、 自組裝單分子膜 29 3.1 組成原理 29 3.2 文獻回顧與探討 33 3.2.1 自組裝單分子膜(SAMs)的種類 33 3.2.2 自組裝單分子膜(SAMs)之結構 33 3.2.3 矽烷類自組裝單分子膜之鍵結形式 35 3.2.4 矽烷分子與基材表面鍵結之反應機構 36 3.2.5 矽烷類自組裝單分子膜之成膜理論 39 3.2.6 影響矽烷類自組裝單分子膜反應之因素 40 3.2.7 長短碳鏈矽烷對自組裝單分子膜品質之影響 41 四、 黏著力量測(表面刮痕測試) 44 4.1 量測原理 46 4.2 文獻回顧與探討 49 五、 實驗原理與製程 53 5.1 實驗原理 53 5.2 實驗製程 55 六、 實驗結果與討論 59 6.1 表面粗糙度,反應式離子蝕刻(二氧化矽蝕刻以及 氧電漿)與氧化物濕式蝕刻進行表面活化 59 6.2自組裝單分子膜處理以及不同的製程條件 61 6.3 自組裝單分子膜(APTS and GPTS)的比較 67 6.4 自組裝單分子膜處理研究與後續熱處理的比較 68 6.5 黏著力功的計算與比較 75 6.6 黃光微影極限測試 77 七、 結論 86 參考文獻 87

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