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研究生: 陳婷婷
Chen, Ting-Ting
論文名稱: 以氧氣電漿蝕刻的鑽石奈米管之場發特性研究
Field emission characteristics of B-doped Diamond Nanotube Fabricated by Oxygen Plasma Etching
指導教授: 黃振昌
口試委員:
學位類別: 碩士
Master
系所名稱: 工學院 - 材料科學工程學系
Materials Science and Engineering
論文出版年: 2010
畢業學年度: 98
語文別: 中文
論文頁數: 69
中文關鍵詞: 鑽石氬氣電漿
相關次數: 點閱:4下載:0
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  • 中文摘要
    本研究係在多晶鑽石表面和微米級多晶鑽石薄膜上蝕刻出奈米級鑽石針尖結構研發其場發射特性。本研究利用微波電漿輔助化學沉積的氧氣電漿來蝕刻拋光及未拋光的P-型多晶硼參雜鑽石膜,製作出鑽石奈米管林,電源供應器為射頻(RF)電源供應器輸入100W的能量,進行物理性蝕刻,再利用微波電漿輔助化學沉積的氬氣電漿改質處理,去量測不同處理時間下,奈米鑽石管的場發射特性。
    實驗結果顯示,氬氣電漿處理四分鐘後的拋光鑽石膜及未拋光鑽石膜所蝕刻而成的奈米鑽石管林,皆展現優良的場發特性,拋光的試片所蝕刻出來的奈米鑽石管林可將啟動電場降至4.4(V/um)且電流密度維持在15-20 mA/cm2 at8.1V/um,未拋光部分經氬氣處理4mins下的場發特性,具有低啟動電場(5V/um)及高電流密度(7.6 mA/cm2 at 8.6 V/um )的特性,利用場發射電子顯微鏡(FE-SEM)觀看經過處理後的鑽石奈米管林的形貌,隨著處理時間的增長,奈米鑽石管端的形貌無明顯差異,而鑽石品質卻隨著處理時間增長而下降。
    研究顯示,經過氬氣電漿處理的奈米鑽石管,不僅降低啟動電場,也明顯的增加電流密度,由此推論場發射特性的提升和氬氣電漿處理造成的形貌及SP3鍵結破壞及所產生的缺陷是相關的。


    中文摘要……………… I Abstract……………………. ……Ⅱ 總目錄……………………. …Ⅲ 圖表目錄…………………… Ⅴ 第一章 緒論……………… 1 1-1 研究動機……………………. …1 1-2 論文架構 2 第二章 文獻回顧 …..3 2- 1平面顯示器簡介 …………………..3 2-2常見之場發射材料的製程與研究 4 2-2.1.1金屬 2-2.1.a鉬金屬(Mo) 2-2.1.b鎢金屬(W) 2-2.1.2非金屬 2-2.1.2a矽基(Silicon Base 2-2.1.2b碳基(Carbon Base) 2-2.1.2c氧化鋅(Zinc Oxide)奈米線 2-2.1.2d氮化物(carbon nanotube)奈米線 2-3鑽石性質及應用……………………………………….7 2-3.1 鑽石的結構、特性及應用 2-3.2 一維奈米結構的鑽石之相關研究 2-3.2.1反應性離子蝕刻(RIE) 2-3.2.2電漿輔助式化學氣相沉積(PECVD) 2-3.2.3一維奈米結構的鑽石之場發性質 第三章 實驗系統與分析技術簡介 25 3-1 電漿蝕刻實驗設備…………….. 25 3-1.1 氣體供應系統 3-1.2真空腔體 3-1.3 抽氣裝置 3-1.4 電源供應系統 3-2 場發測量測設備………………. 26 3-2.1 場發射原理 3-2.2 場發射機台介紹 3-3 分析技術簡介…………………. 28 3-3.1 場發射掃描式電子顯微鏡(FESEM) 3-3.2 X光繞射分析儀(XRD) 3-3.3 拉曼光譜分析儀(Raman Scattering Spectrometer) 3-3.4 霍爾效應分析儀(Hall Effect Measurement System) 第四章 實驗原理與流程 34 4-1 實驗原理……………. 34 4-2 實驗流程……………… 34 第五章 實驗結果與討論 36 5-1多晶鑽石薄膜試片的品質與特性 36 5-2 以氧氣電漿蝕刻而成的鑽石奈米管 37 5-2.1 SEM分析 5-2.2 Raman光譜分析 5-2.3 TEM分析 5-3鑽石奈米管的場發量測分析與討論 41 5-3.1 場發射機台基座 5-3.2寬能隙材料的物理性質對場發射的影響 5-3.3鑽石奈米管的場發特性分析 5-3.4提升場發特性的機制 第六章 結論…………….. 62 參考文獻…………………. 64

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