研究生: |
黃靜瑩 Ching-Ying Huang |
---|---|
論文名稱: |
大氣電漿束對類鑽碳膜之表面處理與分析 DLC surface treatments by atmospheric pressure plasma jet |
指導教授: |
寇崇善
Chwung-Shan Kou |
口試委員: | |
學位類別: |
碩士 Master |
系所名稱: |
理學院 - 物理學系 Department of Physics |
論文出版年: | 2006 |
畢業學年度: | 94 |
語文別: | 中文 |
論文頁數: | 59 |
中文關鍵詞: | 大氣電漿束 、類鑽碳膜 、表面能 |
外文關鍵詞: | APPJ, DLC, surface energy |
相關次數: | 點閱:3 下載:0 |
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本研究目的係利用低溫、均勻的大氣電漿束處理類鑽碳膜,並研究其表面能的改變。本實驗中,先使用13.56 MHz之電容式射頻電漿源,功率100 W、壓力10 mTorr、沉積時間15 min、氣體H2:CH4=1:1,成長類鑽碳膜,再以大氣電漿束,以固定60度角的方式,通入氣體Ar或He,改變不同的功率與流量,處理DLC試片,經由量測接觸角,來了解表面能的變化。同時使用化學能量分析電子術(ESCA)、Langmuir probe、與光學放射頻譜分析儀(OES)量測系統,來分析造成表面能改變的因素。
經大氣電漿束處理後的類鑽碳膜,接觸角會下降,表面能的極性項會大幅增加,而非極性項會稍稍下降。因為經大氣電漿束處理,會打斷DLC表面的聚合物長鍊鍵結,造成表面能非極性項的值降低,同時,大氣電漿束會激發游離大氣中的O2與N2形成氧的活化粒子,對基板表面蝕刻,而與表面的碳原子形成極性鍵結,造成較強的極性。當功率增加,氧的活化粒子變多,表面的C-O鍵結增加;當流量增加,大氣電漿束噴口前端的壓力減小,有更多大氣中的O2與N2靠近噴口前端,因此更多C-O鍵結於類鑽碳膜的表面形成,造成表面能的極性項隨流量增加而增加。
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