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研究生: 謝濬宇
Hsieh, Chun-Yu
論文名稱: 類燭光有機發光二極體
Candle Light-Style Organic Light Emitting Diode
指導教授: 周卓煇
Jou, Jwo-Huei
口試委員: 許千樹
周卓煇
吳茂昆
岑尚仁
學位類別: 碩士
Master
系所名稱: 工學院 - 材料科學工程學系
Materials Science and Engineering
論文出版年: 2013
畢業學年度: 101
語文別: 中文
論文頁數: 118
中文關鍵詞: 有機發光二極體燭光低色溫
相關次數: 點閱:3下載:0
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  • 為了回應醫界的呼籲:入夜若需點燈,應該避免使用藍或白光,我們因此利用有機發光二極體(Organic light emitting diode, OLED)照明技術,設計、製作一個非常節能又生理友善、像燭光的夜用光源;此一類燭光OLED,色溫可低至1,900 K,演色性(Color rendering index, CRI)可達93,其能量效率是蠟燭的300倍,至少高於白熾燈泡兩倍;此外,此一擬燭光OLED元件的亮度光譜,與蠟燭的亮度光譜,有80 %的相似性;此元件能有超高演色性與低色溫,乃緣自使用紅、黃、綠及藍光四個低色溫黑體輻射互補性的發光染料;而此四個發光染料,乃分別摻混於兩個發光層中,其間搭配一個奈米載子調制層;此一載子調制層的功能,乃在調配注入的載子,以使四個光色,都能順利產出,以獲得最高的演色性;由於良好的載子分佈,也使得元件的效率增加;更重要的是,此乃以電力驅動的燭光光輝,有潛力取代燃燒碳氫、耗能、且會產生溫室氣體的蠟燭。


    摘要 I 英文摘要 II 致謝 III 目錄 V 圖目錄 VIII 表目錄 X 壹、緒論 1 貳、文獻回顧 4 2-1 有機發光二極體的歷史 4 2-2 有機發光二極體的發光原理 31 2-3 能量傳遞機制 38 2-4 光取出效率 44 2-5 有機發光二極體之材料發展 46 2-5-1 電洞注入材料 47 2-5-2 電洞傳輸材料 47 2-5-3 電子傳輸材料 48 2-5-4 電子注入材料 48 2-5-5 陰極材料 49 參、實驗方法 50 3-1 使用材料 50 3-2 元件電路設計 57 3-3 基板清洗 59 3-4 旋轉塗佈製成 60 3-5 熱蒸鍍製成 62 3-6成膜鍍率測定 63 3-7 元件光電特性量測 64 3-8 發光效率計算 65 肆、結果與討論 66 4-1 燭光特性 66 4-1-1燭光光譜 66 4-1-2燭火色溫分布 67 4-2 類燭光OLED之燭光光譜相似度 68 4-3 類燭光OLED 71 4-3-1類燭光OLED-與常見光源比較 71 4-3-2類燭光OLED-光源氛圍 73 4-3-3燭光光譜相似性計算 76 4-3-4元件架構 78 4-4元件結構探討 80 4-4-1元件分析 80 4-4-2發光層厚度最佳化 85 4-4-3載子調制層與濃度影響 88 4-4-4成果比較 89 伍、結論 92 陸、參考資料 93 附錄、個人著作目錄 116 (A)期刊研討會論文 116 (B)研討會論文 117 (C)專利 118  

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