為了探討汞齊在金薄膜上生成的情形，本研究利用穿透式電子顯微鏡做汞齊晶體結構鑑定與形貌分析。試片的製備為將金薄膜暴露在汞蒸氣中，藉由在室溫下改變其曝汞時間，以及隔水加熱法改變其溫度，兩種條件中進行。實驗數據分別與數據庫及波長散佈譜做比對，分析結果指出於實驗條件下，汞齊顆粒分佈相當不均勻，與理論計算的吸附率相比結果差距甚遠，並且這些顆粒經由繞射圖形鑑定證實結構為 Au3Hg。此外，在本論文中也發展出固態汞源蒸鍍方法，成功的將汞鍍於欲鍍金膜上。

In this study, in order to investigate the amalgamation on the thin gold films, the crystal structure and morphology analysis of gold amalgams were studied with transmission electron microscopy. Specimens were prepared by exposing thin gold films under mecury vapour environment in room temperature and in hot water bath. Experimental data were compared with database. The distribution of amalgam particles on thin gold films was found to be non-uniform, and the adsorption rate deviated from theoretical calculation. Moreover, Au3Hg were verified by analysing diffraction patterns from those amalgam particles. Besides, the successful evaporation of mercury by amalgam method is developed in this study as well.

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