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研究生: 田仲達
Tian, Jhong-Da
論文名稱: 利用自我對準微接合技術製作矽鍺異質接面波導光偵測器
A novel process using self-aligned microbonding technique to make Ge/Si heterojunction PIN waveguide photodetectors
指導教授: 李明昌
Lee, Ming-Chang
口試委員: 那允中
劉致為
學位類別: 碩士
Master
系所名稱: 電機資訊學院 - 光電工程研究所
Institute of Photonics Technologies
論文出版年: 2012
畢業學年度: 101
語文別: 中文
論文頁數: 99
中文關鍵詞: 鍺矽異質結構光偵測器
外文關鍵詞: Ge/Si
相關次數: 點閱:3下載:0
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  • 近年來,矽鍺整合技術應用於電子元件或是光學元件上漸漸受到矚目,舉例來說,利用鍺材料載子遷移率高的特色做主動調變器,或鍺紅外光偵測器,文獻上都已成功做出且有不錯的特性表現。但基於兩種材料本質上4%的晶格常數差異,使矽鍺整合有一定難度。一般常用方法如直接磊晶鍺於矽基板上,但此法需要較特殊的製程處理和儀器,且磊晶後的鍺需要高溫長時間的退火,才能達到元件所需高品質單晶鍺,此高熱預算會降低元件表現,且增加與積體電路整合困難度。另一種達成鍺矽異質結構的方法為晶圓接合法,可直接將鍺晶圓和矽晶圓對接,不需高溫的鍵結,但缺點為太浪費材料,且接合時,晶圓表面輪廓不易控制,此問題將造成元件良率下降。
    回顧文獻,使用液相磊晶法可保證所長鍺為高品質單晶,但此法需將鍺先包覆於一非晶材料坩鍋中,高溫退火使鍺成為單晶,而鍺和矽基板被坩鍋絕緣層所阻擋。在本論文中,提出新穎的方法,利用自我對準微接合技術直接將液相磊晶後的鍺材料和矽基板鍵結,不需高溫長時間退火,且接合範圍小,改善大範圍晶圓接合問題,並實際完成鍺矽異質接面PIN波導型光偵測器,所量測的暗電流密度、光反應、操作速度皆有高水準表現。


    Ge/Si integration receives a lot of attention for both electronic and photonic devices. For example, Ge/Si-based high-mobility transistors and high-speed photodetectors have been demonstrated with superior performances. However, pure Ge grown on Si is critical due to the lattice mismatch (4%) between Si and Ge. Direct epitaxial growth of Ge on Si usually requires special process techniques and tools. In addition, Ge epitaxial growth often requires a high-temperature process condition for an extended period of time to achieve high crystal quality. Nevertheless, the resultant thermal budget could degrade the device properties and complicate the integration with ICs. Another approach for Ge/Si hetero-integration is a direct wafer or die bonding of Ge onto Si wafers. However, removing the bonded substrates could be a waste of material. Furthermore, bonding surface topography often affects the bonding yield very much.
    Previously, rapid melt growth (RMG) of Ge on insulator showed a promising way for the integration of high-quality Ge with ICs. However, through this process, a Ge/Si heterojunction can’t be made since the Ge layer has to be separated from the Si surface by a dielectric. In this paper, a novel process using a self-aligned microbonding technique to directly make the RMG Ge strips contacted on SOI waveguides. A microbonded Ge/Si PIN waveguide photodetector is demonstrated with good performance in dark current, operation bandwidth, and responsivity.

    摘要 I Abstract II 致謝 III 目錄 IV 第一章 緒論 1 1.1 前言 1 1.2 研究動機與目的 3 1.3 論文架構 4 第二章 關於鍺光偵測器問題討論 5 2.1 光偵測器介紹 5 2.2 矽鍺異質結構整合所遇困難 7 2.3 磊晶法與晶圓接合法鍺光偵測器文獻回顧 10 2.4 液相磊晶+自我對準微接合技術概念 12 第三章 元件及製程理論背景 14 3.1 鍺材料應用於紅外光通訊元件 14 3.2 PIN光子偵測器原理 16 3.2.1 基本運作原理 16 3.2.2 照光吸收機制 17 3.2.3 特性參數 17 3.3 快速熱熔再結晶法原理 20 3.3.1 液相磊晶理論與機制 21 3.4 微接合技術理論 25 3.4.1 表面張力 26 3.4.2 表面張力使懸樑附著於基板 28 第四章 元件模擬與設計 33 4.1 鍺矽PIN與NIP二極體架構 33 4.2 鎳化矽電極設計 35 4.3 RSoft模擬鍺吸收光效率 39 第五章 元件製程 42 5.1 元件製作流程圖 42 5.2 元件製作流程表 48 5.3 元件製作流程詳細說明 56 第六章 元件量測結果與討論 71 6.1 元件電子顯微鏡與穿透式電子顯微鏡拍攝 71 6.2 電性量測與比較 81 6.3 光響應度架設與量測 88 6.4 高頻架設與量測 92 第七章 結論與未來展望 95 7.1 結論 95 7.2 未來展望 96 參考文獻 97

    [1] Xiaochen Sun, “Ge-on-Si Light-Emitting Materials and Devices for Silicon Photonics,” B.S. Physics, Peking University, (2004)
    [2] T. Yin, M. M. Morse, G. Sarid, Y. Chetrit, D. Rubin and M. J. Paniccia, “31 GHz Ge n-i-p waveguide photodetectors on Silicon-on-Insulator substrate” Opt. Express 15, 13965–13971 (2007)
    [3] M. Morse, O. Dosunmu, G. Sarid and Y. Chetrit, “Performance of Ge-on-Si p-i-n Photodetectors for Standard Receiver Modules,” IEEE Photon. Technol. Lett. 18, 2442–2444 (2006).
    [4] Xi Luo, “Transistor-Based Ge/SOI Photodetector for Integrated Silicon Photonics,” Electrical Engineering and Computer Sciences University of California at Berkeley, (2011) .
    [5] H. Kanbe, M. Hirose, T. Ito, and M. Taniwaki, “Crystallographic Properties of Ge/Si Heterojunctions Fabricated by Wet Wafer Bonding,”39,1248(2010) .
    [6] H. Kanbe, M. Miyaji, and T. Ito, “Ge/Si heterojunction Photodiodes Fabricated by Low Temperature Wafer Bonding,”Appl. Phys. Exp. 1, 072301
    [7] Yaocheng Liu, Michael D. Deal, and James D. Plummer, “High-quality single-crystal Ge on insulator by liquid-phase epitaxy on Si substrates,” APPLIED PHYSICS LETTERS, vol. 84, (2004)
    [8] 黃鐘億,“具有低溫成長氮化鎵/氮化鋁插入層之氮化鎵光偵測器光電特性比較之研究,”國立成功大學光電科學與工程研究所(民國96年)
    [9] Edward D,“Handbook of optical Constants of solids,” Academic press NY, Palik(1985)
    [10] Shu-Lu Chen, “Design and process for three-dimensional heterogeneous integration,” (2010)
    [11] 吳庭孝,“利用快速熱熔再結晶法製作金半金結構之面收型鍺紅外光光子偵測器於矽基板上,”國立清華大學光電工程研究所(民國101年)
    [12] C. H. Mastrangelo, C. H. Hsu, “Mechanical Stability and Adhesion of Microstructures Under Capillary Forces-Part I: Basic Theory,” Journal of Microelectro mechanical systems, vol. 2, no. I ,(1993)
    [13] J. Osmond, G. Isella, D. Chrastina, R. Kaufmann, M. Acciarri, and H. von Kanel, “Ultralow dark current Ge/Si(100) photodiodes with low thermal budget,” Appl. Phys. Lett. 94(20), 201106 (2009).
    [14] W.W. Wu, S.L. Cheng, S.W. Lee, L.J. Chen, “Enhanced growth of low-resistivity NiSi on epitaxial Si0.7Ge0.3 0n (001)Si with a sacrificial amorphous Si interlayer,” , J. Vac. Sci. Technol. B 21 (2003)
    [15] C. O. Chui, K. Gopalakrishnan, P. B. Griffin, J. D. Plummer, and K. C. Saraswat, “Activation and diffusion studies of ion-implanted p and n dopants in germanium,” Appl. Phys. Lett. 83(16), 3275–3277 (2003).
    [16] C. H. Mastrangelo, et al., “A sample experimental technique for the measurement of the work of adhesion of microstructures,” (1992)
    [17] J. D. Hwang, et al., “Effects of a a-Si:H layer on reducing the dark current of 1310nm metal-germanium-metal photodetectors, ” Thin Solid Films 519 (2011)
    [18] K. Prabhakaran, F. Maeda, Y. Watanabe, T. Ogino, “ Distinctly different thermal decomposition pathways of ultrathin oxide layer on Ge and Si surfaces, ”Applied Physics Letters 76 (2000) 2244–2246
    [19] Rongqing Hui, Maurice OSullivan, “Fiber Optic Measurement Techniques,”
    [20] Marius Grundmann, “ The physics of semiconductors an introduction including devices and nanophysics, ”Institute of experiment physic II, university of Leipzig(2006)

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