研究生: |
黃瀞瑤 Huang, Ching-Yao |
---|---|
論文名稱: |
對高分子塗膜在乾燥過程中捲曲行為之探討 |
指導教授: |
劉大佼
Liu, Ta-Jo |
口試委員: | |
學位類別: |
碩士 Master |
系所名稱: |
工學院 - 化學工程學系 Department of Chemical Engineering |
論文出版年: | 2009 |
畢業學年度: | 97 |
語文別: | 中文 |
論文頁數: | 75 |
中文關鍵詞: | 捲曲 、高分子 |
外文關鍵詞: | curl, curling |
相關次數: | 點閱:1 下載:0 |
分享至: |
查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報 |
塗膜在乾燥過程中,常會有捲曲現象的產生,而造成捲曲現象的主要原因是因為在乾燥過程中塗料因為乾燥時體積的收縮產生的應力所致。應力的產生不單單由一個變因或一個物性決定,往往是很多因素在製程條件的改變下所造成的應力形成與應力釋放間決定了應力的大小。
會造成應力的形成與釋放是因為有厚度、黏度、反應時間種種原因。本實驗探討兩種應用相當廣的塗料聚亞醯胺(polyimide,PI)與聚乙烯醇(polyvinyl alcohol,PVA)在不同製程條件下例如:溫度、厚度、環境溼度、基材厚度等等不同因素下對於塗膜乾燥捲曲的影響,進而去找出影響捲曲最敏感的條件。此外並以製成條件來推論出可能的捲曲高度,如此一來就可以避開捲曲對其他性質的影響。在理論方面探討了在塗膜時塗料因為體積收縮產生了應力並可以從製程條件去推出應力形成 ,在另一方面,加上可以從應力去推出捲曲高度的理論 ,兩者相配合 即可從製程條件直接推算出捲曲高度。
附錄B.參考文獻
[1] Morris .Barry A., “Reducing Curl in Multilayer Blown Film :Experimental Results, Model Development, and Application to A Cereal Liner Film ”, Journal Of Plastic Film and Sheeting , Vol. 19, pp.31-54(2003)
[2] Alsoy.S and Duda, J.L , “Drying of Solvent Coated Polymer Films”, Drying Technology, Vol.16, pp.15-44 (1998).
[3]H.Lei,J.A,Payne,A.V.Mccormick,L.F.Francis,W.W.gerberichi,L.e.Scriven,’’Steess Development in Drying Coatings’’,Inc.J Appl Polym Sci 81 PP.1000-1013(2001)
[4] Penwell ,R.C. and Chow ,T.S. ”Minimizing Curl Induced Upon Drying Layered Solvent Coated Films”,Polymer Engineering And Science,April,Vol.25,No.6 pp367-373(1985)
[5] Vrentas,J.S . and Duda,J.L. , “Diffusion in Polymer-Solvent Systems II. A Predictive Theory for the Dependence of Diffusion Coefficients on Temperature, Concentration, and Molecular Weight”, J. Polym. Sci., Part B: Polym. Phs., Vol.15, 403-416 (1977).
[6] Hong, S.U., “Prediction of Polymer/Solvent Diffusion Behavior Using Free-Volume Theory”, Ind. Eng. Chem., Res., Vol.34, 2536-2544 (1995).
[7] Bird, R.B., Steward, W.E. and Lightfoot, E.N., “Transport Phenomena”, Wiley & Sons, New York( 1960)
[8] Rivlin, R.S. and Saunders, D.W., “Large Elastic Deformations of Isotropic Materials, VII, Experiments on the Deformation of Rubber”, Phi. T. Roy. A, 243, 251-288 (1951).
[9] Yapel, R.A., “The Physical Model of Drying of Coated Films”, M.S. Thesis, University of Minnesota, Minneapolis, USA, 1988.
[10]陳惠姿, "Novel Positive-working Aqueous Base MicroeDevelopable
Photosensitive Poly(imide-benzoxazole) for Microelectronic
Applications",成功大學碩士論文 ,(2004)
[11]陳柏儒,”光學膜製程中所產生雙折射現象之定量分析”,清華大學博士論文,(2009)
[12] Hong, S.U., “Prediction of Polymer/Solvent Diffusion Behavior Using Free-Volume Theory”, Ind. Eng. Chem., Res., 34, 2536-2544 (1995).
[13] Park, K.S. and Kim, D., “Determination of Diffusion and Mass Tansfer Coefficients during Drying of Solvent-Absorbed Polymer Films”, Polym. J., 32, 415-421 (2000).
[14] Tam,S.Y., “Stress Effects in Drying Coatings”, Ph.D. Thesis. Univ. Minnesota (1997).
[15] Lei,H., Francis L.F., Gerberich W.W. and Scriven L.E., “Stress development in drying fibers and spheres”, J. Appl. Polym. Sci., 90, 3934 (2003).
[17] Narukawa ,Y. and Scriven,L.E., “Drying, Stress Development and Deformation in Solvent-Cast Film”, 12th ISCST Conference, 86 (2004).
[18] Greener, J., Lei, H., Elman J. and Chen, J., “Optical Properties of Solvent-Cast Polarizer Films for Liquid Crystal Display: A Viscoelastic Modeling Framework”, SID Digest, 756-759 (2005).
[19] Timoshenko,S.P. and Gere,J.M., “Theory of Elastic Stability”, McGraw-Hill, New York( 1961).
[20]Croll,S.G., “The Origin of Residual Internal Stress in Solvent-Cast Thermoplastic Coatings”, J. Appl. Polym. Sci., 23, 847-858 (1990).
[21] Crank J., “The Mathematics of Diffusion”, 2nd ed. Oxford, New York, (1975).
[22]周宏隆,” 聚乙烯醇黏土複合材料之物理化學性質與結構分析”,中山大學博士論文,(1999)
[23] 陳泰宏,” 應用實驗設計法探討PI膜液晶配向製程之研究”,清華大學碩士論文,(2005)